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Title: Comparing the 2,2'-Biphenylenedithiophosphinate Binding of Americium with Neodymium and Europium

Journal Article · · Angewandte Chemie (International Edition)
 [1];  [2];  [3];  [1];  [3]; ORCiD logo [1];  [1];  [1];  [4];  [1];  [5]
  1. Los Alamos National Lab. (LANL), Los Alamos, NM (United States)
  2. Los Alamos National Lab. (LANL), Los Alamos, NM (United States); Univ. of Illinois, Urbana-Champaign, IL (United States)
  3. Univ. of Illinois, Urbana-Champaign, IL (United States)
  4. Lawrence Berkeley National Lab. (LBNL), Berkeley, CA (United States)
  5. Los Alamos National Lab. (LANL), Los Alamos, NM (United States); California State Polytechnic Univ., Pomona, CA (United States)
+ Show Author Affiliations

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Los Alamos National Laboratory (LANL), Los Alamos, NM (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Nuclear Physics (NP); USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division; USDOE National Nuclear Security Administration (NNSA); USDOE Office of Nuclear Energy (NE), Fuel Cycle Technologies (NE-5); National Science Foundation (NSF)
Grant/Contract Number:
AC02-05CH11231; AC52-06NA25396
OSTI ID:
1435060
Alternate ID(s):
OSTI ID: 1401877; OSTI ID: 1441291
Report Number(s):
LA-UR-16-24625; ark:/13030/qt3zq898qx; TRN: US1803074
Journal Information:
Angewandte Chemie (International Edition), Vol. 55, Issue 41; ISSN 1433-7851
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 27 works
Citation information provided by
Web of Science

References (57)

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Synthesis and Characterization of f -Element Iodate Architectures with Variable Dimensionality, α- and β-Am(IO 3 ) 3 journal March 2006
Curium(III) Borate Shows Coordination Environments of Both Plutonium(III) and Americium(III) Borates journal January 2012
Characterization of extraction complexes of Am(III) with dialkyldithiophosphinic acids by extended X-ray absorption fine structure spectroscopy journal February 2002
Hydrothermal synthesis, structural, Raman, and luminescence studies of Am[M(CN)2]3·3H2O and Nd[M(CN)2]3·3H2O (M=Ag, Au): Bimetallic coordination polymers containing both trans-plutonium and transition metal elements journal November 2007
Complexation and Extraction of Trivalent Actinides and Lanthanides by Triazinylpyridine N -Donor Ligands journal October 2012
[An(H2O)9](CF3SO3)3 (An=U-Cm, Cf): Exploring Their Stability, Structural Chemistry, and Magnetic Behavior by Experiment and Theory journal August 2010
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Differentiating between Trivalent Lanthanides and Actinides journal June 2012
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Complexation and Separation of Lanthanides(III) and Actinides(III) by Heterocyclic N-Donors in Solutions journal October 2008
Coordination Modes of Americium in the Am 2 (C 2 O 4 ) 3 (H 2 O) 6 ·4H 2 O Oxalate: Synthesis, Crystal Structure, Spectroscopic Characterizations and Comparison in the M 2 (C 2 O 4 ) 3 (H 2 O) 6 · n H 2 O (M = Ln, An) Series journal December 2015
Curium(III) Borate Shows Coordination Environments of Both Plutonium(III) and Americium(III) Borates journal January 2012
The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution journal January 2007
Emergence of californium as the second transitional element in the actinide series journal April 2015
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Bonding Changes in Plutonium(III) and Americium(III) Borates journal August 2011
Interpretation of europium(III) spectra journal July 2015
Thermodynamic Study of the Complexation of Trivalent Actinide and Lanthanide Cations by ADPTZ, a Tridentate N-Donor Ligand journal March 2005
Preferential extraction of lanthanides over trivalent actinides by monoacidic organophosphates from carboxylic acids and from mixtures of carboxylic and aminopolyacetic acids journal January 1968
Extraction of Am(III) and Eu(III) from Nitrate Solution with Purified Cyanex 301 journal January 1996
Synthesis, Structure, and Spectroscopic Properties of Am(IO 3 ) 3 and the Photoluminescence Behavior of Cm(IO 3 ) 3 journal August 2005
Some misconceptions concerning the electronic spectra of tri-positive europium and cerium journal January 2013
Refinement of the crystal structure of AmCl 3 journal November 1970
[An(H2O)9](CF3SO3)3 (An=U-Cm, Cf): Exploring Their Stability, Structural Chemistry, and Magnetic Behavior by Experiment and Theory journal June 2010
Thermodynamic properties of lanthanide and actinide ions in avueous solution journal July 1986
The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution journal January 2007
Sulfur K-edge X-ray Absorption Spectroscopy and Time-Dependent Density Functional Theory of Dithiophosphinate Extractants: Minor Actinide Selectivity and Electronic Structure Correlations journal August 2012
The coordination chemistry of trivalent lanthanides (Ce, Nd, Sm, Eu, Gd, Dy, Yb) with diphenyldithiophosphinate anions journal January 2014
Hydrothermal synthesis, structure, Raman spectroscopy, and self-irradiation studies of 248Cm(IO3)3 journal December 2004
Plutonium(IV) Sequestration: Structural and Thermodynamic Evaluation of the Extraordinarily Stable Cerium(IV) Hydroxypyridinonate Complexes1 journal September 2000
Rational Design of Sequestering Agents for Plutonium and Other Actinides journal November 2003
6-(3,5-Dimethyl-1 H -pyrazol-1-yl)-2,2′-bipyridine as Ligand for Actinide(III)/Lanthanide(III) Separation journal October 2010
Recent achievements in the development of partitioning processes of minor actinides from nuclear wastes obtained in the frame of the NEWPART European programme (1996–1999) journal April 2002
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Effects of Large Halides on the Structures of Lanthanide(III) and Plutonium(III) Borates journal April 2012
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Preparation and structures of homoleptic Pu(iii) and U(iii) acetonitrile salts journal January 2003
Absorption Spectrum of Americium Tricyclopentadienide journal July 1969
Relationships Between Structure and Spectroscopic Properties of Nd 3+ Ethylene­diaminetetramethylenephosphonates and Ethylenediaminetetraacetates journal May 2013
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Rational Design of Sequestering Agents for Plutonium and Other Actinides journal February 2004
The Structures and Optical Spectra of Hydrated Transplutonium Ions in the Solid State and in Solution. journal April 2007
Direct solid-phase synthesis of molecular heterooligonuclear lanthanoid-complexes journal March 2020
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Recent achievements in the development of partitioning processses of minor actinides from nuclear wastes obtained in the frame of the NEWPART European Programme (1996–1999) conference January 2000

Cited By (11)

Actinide-Pnictide (An−Pn) Bonds Spanning Non-Metal, Metalloid, and Metal Combinations (An=U, Th; Pn=P, As, Sb, Bi) journal December 2017
Picomolar Traces of Americium(III) Introduce Drastic Changes in the Structural Chemistry of Terbium(III): A Break in the “Gadolinium Break” journal August 2017
Origin of Selectivity of a Triazinyl Ligand for Americium(III) over Neodymium(III) journal February 2019
The lanthanide complexes of 2,2′-bipyridyl-6,6′-dicarboxylic dimethylanilides: the influence of a secondary coordination sphere on the stability, structure, luminescence and f-element extraction journal January 2018
An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements journal September 2019
Probing a variation of the inverse-trans-influence in americium and lanthanide tribromide tris(tricyclohexylphosphine oxide) complexes journal January 2020
Soft-donor dipicolinamide derivatives for selective actinide( iii )/lanthanide( iii ) separation: the role of S- vs. O-donor sites journal January 2019
[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex journal July 2019
Actinide-Pnictide (An−Pn) Bonds Spanning Non-Metal, Metalloid, and Metal Combinations (An=U, Th; Pn=P, As, Sb, Bi) journal December 2017
[Am(C 5 Me 4 H) 3 ]: An Organometallic Americium Complex journal July 2019
An Americium‐Containing Metal–Organic Framework: A Platform for Studying Transplutonium Elements journal November 2019

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Related Subjects

38 RADIATION CHEMISTRY, RADIOCHEMISTRY, AND NUCLEAR CHEMISTRY
actinides
americium
lanthanides
radiochemistry
X-ray diffraction
Inorganic and Physical Chemistry