Solvent-Free Self-Assembly to the Synthesis of Nitrogen-Doped Ordered Mesoporous Polymers for Highly Selective Capture and Conversion of CO2

Liu, Fujian; Huang, Kuan; Wu, Qin; Dai, Sheng

doi:10.1002/adma.201700445

Title: Solvent-Free Self-Assembly to the Synthesis of Nitrogen-Doped Ordered Mesoporous Polymers for Highly Selective Capture and Conversion of CO₂

Journal Article · Wed May 10 00:00:00 EDT 2017 · Advanced Materials

DOI:https://doi.org/10.1002/adma.201700445· OSTI ID:1388885

Liu, Fujian ^[1]; Huang, Kuan ^[2]; Wu, Qin ^[3];

^[4]

Shaoxing Univ. (China). College of Chemistry and Chemical Engineering; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Nanchang Univ. (China). School of Resources Environmental and Chemical Engineering, Key Laboratory of Poyang Lake Environment and Resource Utilization of Ministry of Education; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Shaoxing Univ. (China). College of Chemistry and Chemical Engineering
Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry; Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division

A solvent‐free induced self‐assembly technology for the synthesis of nitrogen‐doped ordered mesoporous polymers (N‐OMPs) is developed, which is realized by mixing polymer precursors with block copolymer templates, curing at 140–180 °C, and calcination to remove the templates. This synthetic strategy represents a significant advancement in the preparation of functional porous polymers through a fast and scalable yet environmentally friendly route, since no solvents or catalysts are used. The synthesized N‐OMPs and their derived catalysts are found to exhibit competitive CO ₂ capacities (0.67–0.91 mmol g ⁻¹ at 25 °C and 0.15 bar), extraordinary CO ₂ /N ₂ selectivities (98–205 at 25 °C), and excellent activities for catalyzing conversion of CO ₂ into cyclic carbonate (conversion >95% at 100 °C and 1.2 MPa for 1.5 h). The solvent‐free technology developed in this work can also be extended to the synthesis of N‐OMP/SiO ₂ nanocomposites, mesoporous SiO ₂ , crystalline mesoporous TiO ₂ , and TiPO, demonstrating its wide applicability in porous material synthesis.

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Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC0012577; DE‐SC0012577

OSTI ID:: 1388885

Alternate ID(s):: OSTI ID: 1401794

Journal Information:: Advanced Materials, Vol. 29, Issue 27; Related Information: UNCAGE-ME partners with Georgia Institute of Technology (lead); Lehigh University; Oak Ridge National Laboratory; University of Alabama; University of Florida; University of Wisconsin; Washington University in St. Louis; ISSN 0935-9648

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 175 works

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Mechanochemically synthesized MgAl layered double hydroxide nanosheets for efficient catalytic removal of carbonyl sulfide and H 2 S Mi, Jinxing; Chen, Xiaoping; Zhang, Qiuyun Chemical Communications, Vol. 55, Issue 63 https://doi.org/10.1039/c9cc03637g	journal	January 2019
Hierarchical porous metallized poly-melamine-formaldehyde (PMF) as a low-cost and high-efficiency catalyst for cyclic carbonate synthesis from CO ₂ and epoxides Yin, Jian; Zhang, Tianqi; Schulman, Emily Journal of Materials Chemistry A, Vol. 6, Issue 18 https://doi.org/10.1039/c8ta00625c	journal	January 2018
Chemical activation of mesoporous carbon with ultrahigh pore volume for highly supported adsorption of CO2 Hu, Siping; Li, Chun; Wan, De Journal of Porous Materials, Vol. 25, Issue 6 https://doi.org/10.1007/s10934-018-0582-7	journal	February 2018
Synthetic, spectral, structural and catalytic activity of infinite 3-D and 2-D copper( ii ) coordination polymers for substrate size-dependent catalysis for CO 2 conversion Bhaskaran, Bhaskaran; Trivedi, Manoj; Yadav, Anita K. Dalton Transactions, Vol. 48, Issue 27 https://doi.org/10.1039/c9dt01457h	journal	January 2019
Unveiling anomalous CO ₂ -to-N ₂ selectivity of graphene oxide Lee, Ji Hoon; Lee, Hyeon Jeong; Choi, Jang Wook Physical Chemistry Chemical Physics, Vol. 19, Issue 34 https://doi.org/10.1039/c7cp04318j	journal	January 2017
Self-assembly of 3D porous architectures from energetic nanoparticles for enhanced energetic performances Wang, Jun; Zhang, Long; Guo, Xiangli CrystEngComm, Vol. 20, Issue 41 https://doi.org/10.1039/c8ce01243a	journal	January 2018
Naphthalene Based Amide‐Imine Derivative and its Dinuclear Vanadium Complex: Structures, Atmospheric CO 2 Fixation and Theoretical Support Ta, Sabyasachi; Ghosh, Milan; Molla, Rostam Ali ChemistrySelect, Vol. 4, Issue 35 https://doi.org/10.1002/slct.201901327	journal	September 2019
Fabrication of Nanoreaction Clusters with Dual-Functionalized Protein Cage Nanobuilding Blocks Choi, Hyukjun; Choi, Bongseo; Kim, Gwang Joong Small, Vol. 14, Issue 35 https://doi.org/10.1002/smll.201801488	journal	July 2018
Nitrogen-decorated, porous carbons derived from waste cow manure as efficient catalysts for the selective capture and conversion of CO ₂ Kong, Weiping; Liu, Jing RSC Advances, Vol. 9, Issue 9 https://doi.org/10.1039/c8ra10497b	journal	January 2019
A Mechanochemical‐Assisted Synthesis of Boron, Nitrogen Co‐Doped Porous Carbons as Metal‐Free Catalysts Zhao, Li‐Yuan; Dong, Xiao‐Ling; Chen, Jun‐Yue Chemistry – A European Journal, Vol. 26, Issue 9 https://doi.org/10.1002/chem.201904381	journal	January 2020
Heterogeneity of polyoxometalates by confining within ordered mesopores: toward efficient oxidation of benzene to phenol Leng, Yan; Jiang, Yuchen; Peng, Honggeng Catalysis Science & Technology, Vol. 9, Issue 9 https://doi.org/10.1039/c9cy00288j	journal	January 2019
Ultrahigh Surface Area N‐Doped Hierarchically Porous Carbon for Enhanced CO ₂ Capture and Electrochemical Energy Storage Wang, Shuai; Qin, Jieqiong; Zhao, Yujuan ChemSusChem, Vol. 12, Issue 15 https://doi.org/10.1002/cssc.201901137	journal	June 2019
Cycloaddition of CO ₂ with epoxides and esterification reactions using the porous redox catalyst Co-POM@MIL-101(Cr) Marandi, Afsaneh; Bahadori, Mehrnaz; Tangestaninejad, Shahram New Journal of Chemistry, Vol. 43, Issue 39 https://doi.org/10.1039/c9nj02607j	journal	January 2019
Natural rubber latex foam with particulate fillers for carbon dioxide adsorption and regeneration Panploo, Krittaya; Chalermsinsuwan, Benjapon; Poompradub, Sirilux RSC Advances, Vol. 9, Issue 50 https://doi.org/10.1039/c9ra06000f	journal	January 2019
A convenient approach directly from triglycerides toward the producing of thia-wax esters as bio- and chemical raw materials Yıldırım, Ayhan; Kıraylar, Kaan; Öztürk, Serkan Research on Chemical Intermediates, Vol. 46, Issue 1 https://doi.org/10.1007/s11164-019-03944-8	journal	August 2019
Prediction of Carbon Dioxide Adsorption via Deep Learning Zhang, Zihao; Schott, Jennifer A.; Liu, Miaomiao Angewandte Chemie, Vol. 131, Issue 1 https://doi.org/10.1002/ange.201812363	journal	December 2018
Post-modified porphyrin imine gels with improved chemical stability and efficient heterogeneous activity in CO ₂ transformation Liao, Peisen; Cai, Guangmei; Shi, Jianying New Journal of Chemistry, Vol. 43, Issue 25 https://doi.org/10.1039/c9nj00570f	journal	January 2019
Microporous organic hydroxyl-functionalized polybenzotriazole for encouraging CO ₂ capture and separation Yin, Qiang; Lu, Chunlin; Zhang, Shuai RSC Advances, Vol. 9, Issue 39 https://doi.org/10.1039/c9ra03741a	journal	January 2019
Cation–π induced lithium-doped conjugated microporous polymer with remarkable hydrogen storage performance Yang, Li; Ma, Yuanchi; Xu, Yewei Chemical Communications, Vol. 55, Issue 75 https://doi.org/10.1039/c9cc04174e	journal	January 2019
Interfacial Engineering of Supported Liquid Membranes by Vapor Cross-Linking for Enhanced Separation of Carbon Dioxide Kong, Li-Yun; Shan, Wei-Da; Han, Sheng-Li ChemSusChem, Vol. 11, Issue 1 https://doi.org/10.1002/cssc.201701851	journal	November 2017
Nitrogen-Enriched Carbon/CNT Composites Based on Schiff-Base Networks: Ultrahigh N Content and Enhanced Lithium Storage Properties Xiao, Zhichang; Song, Qi; Guo, Ruiying Small, Vol. 14, Issue 12 https://doi.org/10.1002/smll.201703569	journal	February 2018
Facile fabrication of a heterogeneous Co-modified pyridinecarboxaldehyde-polyethylenimine catalyst for efficient CO ₂ conversion under mild conditions Liu, Chao; Yang, Li; Zhang, Jiaxu Inorganic Chemistry Frontiers, Vol. 7, Issue 5 https://doi.org/10.1039/c9qi01401b	journal	January 2020

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36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
catalysis (heterogeneous)
defects
membrane
carbon capture
materials and chemistry by design
synthesis (novel materials)
synthesis (self-assembly)
synthesis (scalable processing)
CO2 capture and conversion
molecular sieves
nitrogen functionality
ordered mesoporosity
solvent-free synthesis

Title: Solvent-Free Self-Assembly to the Synthesis of Nitrogen-Doped Ordered Mesoporous Polymers for Highly Selective Capture and Conversion of CO2

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Title: Solvent-Free Self-Assembly to the Synthesis of Nitrogen-Doped Ordered Mesoporous Polymers for Highly Selective Capture and Conversion of CO₂