Fluoropolymer‐Stabilized Chromophore–Catalyst Assemblies in Aqueous Buffer Solutions for Water‐Oxidation Catalysis
- Department of Chemistry University of North Carolina at Chapel Hill CB 3290, Chapel Hill North Carolina 27599 USA
- Department of Chemistry Daegu University Gyeongsan 712-714 Republic of Korea
Abstract Here, the application of the fluorinated polymer [Dupont AF, a copolymer of 4,5‐difluoro‐2,2‐bis(trifluoromethyl)‐1,3‐dioxole and tetrafluoroethylene] is described in stabilizing phosphonate‐derivatized molecular assemblies on oxide electrodes. In the procedure, the polymer was dip‐coated onto the surfaces of oxide electrodes with pre‐bound, phosphonate‐derivatized chromophores and assemblies, including assemblies for water oxidation. The results of the experiments showed a high degree of stabilization by the added polymer and a demonstration of its use in stabilizing surface‐bound assemblies for water‐oxidation catalysis.
- Sponsoring Organization:
- USDOE
- Grant/Contract Number:
- SC0001011
- OSTI ID:
- 1401539
- Journal Information:
- ChemSusChem, Journal Name: ChemSusChem Vol. 10 Journal Issue: 11; ISSN 1864-5631
- Publisher:
- Wiley Blackwell (John Wiley & Sons)Copyright Statement
- Country of Publication:
- Germany
- Language:
- English
Cited by: 13 works
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