Current understanding of structure-processing-property relationships in BaTiO3-Bi(M)O3 dielectrics

Beuerlein, Michaela A.; Kumar, Nitish; Usher, Tedi -Marie; Brown-Shaklee, Harlan James; Raengthon, Natthaphon; Reaney, Ian M.; Cann, David P.; Jones, Jacob L.; Brennecka, Geoff L.

doi:10.1111/jace.14472

Title: Current understanding of structure-processing-property relationships in BaTiO₃-Bi(M)O₃ dielectrics

Journal Article · Thu Sep 01 00:00:00 EDT 2016 · Journal of the American Ceramic Society

DOI:https://doi.org/10.1111/jace.14472· OSTI ID:1342707

Beuerlein, Michaela A. ^[1]; Kumar, Nitish ^[2]; Usher, Tedi -Marie ^[3]; Brown-Shaklee, Harlan James ^[4]; Raengthon, Natthaphon ^[5]; Reaney, Ian M. ^[6]; Cann, David P. ^[2]; Jones, Jacob L. ^[3]; Brennecka, Geoff L. ^[1]

Colorado School of Mines, Golden, CO (United States)
Oregon State Univ., Corvallis, OR (United States)
North Carolina State Univ., Raleigh, NC (United States)
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Chulalongkorn Univ., Bangkok (Thailand)
Univ. of Sheffield, Sheffield (United Kingdom)

As part of a continued push for high permittivity dielectrics suitable for use at elevated operating temperatures and/or large electric fields, modifications of BaTiO ₃ with Bi( M )O ₃ , where M represents a net‐trivalent B ‐site occupied by one or more species, have received a great deal of recent attention. Materials in this composition family exhibit weakly coupled relaxor behavior that is not only remarkably stable at high temperatures and under large electric fields, but is also quite similar across various identities of M . Moderate levels of Bi content (as much as 50 mol%) appear to be crucial to the stability of the dielectric response. In addition, the presence of significant Bi reduces the processing temperatures required for densification and increases the required oxygen content in processing atmospheres relative to traditional X7R‐type BaTiO ₃ ‐based dielectrics. Although detailed understanding of the structure–processing–property relationships in this class of materials is still in its infancy, this article reviews the current state of understanding of the mechanisms underlying the high and stable values of both relative permittivity and resistivity that are characteristic of BaTiO ₃ ‐Bi( M )O ₃ dielectrics as well as the processing challenges and opportunities associated with these materials.

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Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)

Sponsoring Organization:: USDOE Office of Electricity (OE)

Grant/Contract Number:: AC05-00OR22725; DE‐AC02‐06CH11357; DE‐AC52‐06NA25396

OSTI ID:: 1342707

Alternate ID(s):: OSTI ID: 1401236

Journal Information:: Journal of the American Ceramic Society, Vol. 99, Issue 9; ISSN 0002-7820

Publisher:: American Ceramic SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 90 works

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Crystal Structure of Metastable Perovskite Bi(Mg1/2Ti1/2)O3: Bi-Based Structural Analogue of Antiferroelectric PbZrO3. Khalyavin, Dmitry D.; Salak, Andrei N.; Vyshatko, Nikolai P. ChemInform, Vol. 38, Issue 2 https://doi.org/10.1002/chin.200702020	journal	January 2007
Bi2ZnTiO6: A Lead-Free Closed-Shell Polar Perovskite with a Calculated Ionic Polarization of 150 μC cm-2. Suchomel, Matthew R.; Fogg, Andrew M.; Allix, Mathieu ChemInform, Vol. 38, Issue 2 https://doi.org/10.1002/chin.200702019	journal	January 2007
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Phase-field modeling of the coupled domain structure and dielectric breakdown evolution in a ferroelectric single crystal Cai, Ziming; Zhu, Chaoqiong; Wang, Xiaohui Physical Chemistry Chemical Physics, Vol. 21, Issue 29 https://doi.org/10.1039/c9cp02860a	journal	January 2019
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Local and average structures of BaTiO3-Bi(Zn1/2Ti1/2)O3 Usher, Tedi-Marie; Iamsasri, Thanakorn; Forrester, Jennifer S. Journal of Applied Physics, Vol. 120, Issue 18 https://doi.org/10.1063/1.4967222	journal	November 2016
Effects of glass additives on microstructure, dielectric and ferroelectric properties of BaTiO ₃ –BiYbO ₃ based ceramics Chen, Gang; Fan, Tao; Zhang, Shilong Materials Research Express, Vol. 6, Issue 8 https://doi.org/10.1088/2053-1591/ab22f5	journal	May 2019
Influence of A-site nonstoichiometry on the electrical properties of BT-BMT Muhammad, Raz; Khesro, Amir Journal of the American Ceramic Society, Vol. 100, Issue 3 https://doi.org/10.1111/jace.14684	journal	December 2016
Defect mechanisms in BaTiO ₃ ‐Bi M O ₃ ceramics Kumar, Nitish; Patterson, Eric A.; Frömling, Till Journal of the American Ceramic Society, Vol. 101, Issue 6 https://doi.org/10.1111/jace.15403	journal	January 2018
Bi _0.5 K _0.5 TiO ₃ –CaTiO ₃ ceramics: Appearance of the pseudocubic structure and ferroelectric‐relaxor transition characters Wei, Yongxing; Zhang, Ning; Jin, Changqing Journal of the American Ceramic Society, Vol. 102, Issue 6 https://doi.org/10.1111/jace.16244	journal	December 2018
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Crystal structure and temperature dependence of permittivity in barium aluminate based solid solutions Li, Jie; Lan, Xue‐Kai; Du, Kang Journal of the American Ceramic Society, Vol. 102, Issue 12 https://doi.org/10.1111/jace.16673	journal	June 2019
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Ultrahigh Energy Storage Properties in (Sr0.7Bi0.2)TiO3-Bi(Mg0.5Zr0.5)O3 Lead-Free Ceramics and Potential for High-Temperature Capacitors Kong, Xi; Yang, Letao; Cheng, Zhenxiang Materials, Vol. 13, Issue 1 https://doi.org/10.3390/ma13010180	journal	January 2020

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Title: Current understanding of structure-processing-property relationships in BaTiO₃-Bi(M)O₃ dielectrics