Modulated Synthesis of Metal‐Organic Frameworks through Tuning of the Initial Oxidation State of the Metal

Bosch, Mathieu; Sun, Xing; Yuan, Shuai; Chen, Ying‐Pin; Wang, Qi; Wang, Xuan; Zhou, Hong‐Cai

doi:10.1002/ejic.201600211

Title: Modulated Synthesis of Metal‐Organic Frameworks through Tuning of the Initial Oxidation State of the Metal

Journal Article · Fri Jun 10 00:00:00 EDT 2016 · European Journal of Inorganic Chemistry

DOI:https://doi.org/10.1002/ejic.201600211· OSTI ID:1400769

^[1]; Sun, Xing ^[2]; Yuan, Shuai ^[1]; Chen, Ying‐Pin ^[2]; Wang, Qi ^[1]; Wang, Xuan ^[1];

^[3]

Department of Chemistry Texas A&,M University 77842‐3012 College Station Texas USA
Department of Material Science and Engineering Texas A&,M University 77842‐3012 College Station Texas USA
Department of Chemistry Texas A&,M University 77842‐3012 College Station Texas USA, Department of Material Science and Engineering Texas A&,M University 77842‐3012 College Station Texas USA

Modulated solvothermal synthesis and other alterations of synthetic conditions have been used to control metal‐organic framework (MOF) crystallinity, porosity, and other properties. However, so far these changes have mostly been limited to changes in solvent, pH, or modulating acid type or concentration. In this work, we introduce a new method for the tuning of MOF synthesis: modulation through alteration of the metal source's initial oxidation state. By choosing a metal source that should be reduced or oxidized at high temperature in the solvent, metal concentration can be started at zero for initially insoluble starting materials and then increased as the metal reacts with the solvent, slowing and altering crystallization compared to standard MOF solvothermal synthesis. This concept is demonstrated through the synthesis of PCN‐47, PCN‐48, and PCN‐49, MOFs with distinct structures and porosities synthesized from the same metal and ligand with the metal initially in different oxidation states.

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Sponsoring Organization:: USDOE

Grant/Contract Number:: DE‐SC0001015; DE‐AR0000249; DE‐EE‐0007049; DE‐AC02‐06CH11357

OSTI ID:: 1400769

Journal Information:: European Journal of Inorganic Chemistry, Journal Name: European Journal of Inorganic Chemistry Vol. 2016 Journal Issue: 27; ISSN 1434-1948

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 12 works

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