Synthesis of Bis‐1,2,4‐triazines via Telescoped Condensation of [1,10]‐Phenanthroline‐2,9‐dicarbonitrile with Aromatic 1,2‐Dicarbonyls

Tai, Serene; Williams, Neil J.; Carrick, Jesse D.

doi:10.1002/jhet.2295

Title: Synthesis of Bis‐1,2,4‐triazines via Telescoped Condensation of [1,10]‐Phenanthroline‐2,9‐dicarbonitrile with Aromatic 1,2‐Dicarbonyls

Journal Article · Wed Jan 21 00:00:00 EST 2015 · Journal of Heterocyclic Chemistry

DOI:https://doi.org/10.1002/jhet.2295· OSTI ID:1400685

Tai, Serene ^[1]; Williams, Neil J. ^[2]; Carrick, Jesse D. ^[1]

Department of Chemistry Tennessee Technological University 55 University Drive Cookeville Tennessee 38505‐0001
Oak Ridge National Laboratory Oak Ridge Tennessee 37831

Efficient separation of minor actinides from spent nuclear fuel remains a formidable challenge. As part of ongoing efforts to identify effective ligands for separation of toxic radionuclides, a series of bis‐1,2,4‐triazines, three novel, have been prepared from [1,10]‐phenanthroline‐2,9‐dicarbonitrile in two‐telescoped steps without additives, complicated workups, prolonged reaction times, or additional purification.

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Sponsoring Organization:: USDOE

OSTI ID:: 1400685

Journal Information:: Journal of Heterocyclic Chemistry, Journal Name: Journal of Heterocyclic Chemistry Vol. 53 Journal Issue: 1; ISSN 0022-152X

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 11 works

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References (18)

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