A Honeycomb-Layered Oxide Cathode for Sodium-Ion Batteries with Suppressed P3-O1 Phase Transition

You, Ya; Kim, Sang Ok; Manthiram, Arumugam

doi:10.1002/aenm.201601698

Title: A Honeycomb-Layered Oxide Cathode for Sodium-Ion Batteries with Suppressed P3-O1 Phase Transition

Journal Article · Wed Nov 16 00:00:00 EST 2016 · Advanced Energy Materials

DOI:https://doi.org/10.1002/aenm.201601698· OSTI ID:1533068

You, Ya ^[1]; Kim, Sang Ok ^[1]; Manthiram, Arumugam ^[1]

University of Texas, Austin, TX (United States)

Mg–substituted Na₃Ni_2–xMg_xSbO₆ cathode materials are synthesized via a scalable high–temperature solid–state method to improve the cyclability of the honeycomb–layered oxide cathode in sodium–ion batteries. Here, the partial substitution of Ni²⁺ by Mg²⁺ in the transition–metal layer suppresses the electrochemically unfavorable P3–O1 transition and enlarges the lattice parameters to bring improved performance with respect to capacity retention, Coulombic efficiency, and Na (de)intercalation kinetics.

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Research Organization:: Univ. of Texas, Austin, TX (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES). Materials Sciences & Engineering Division; USDOE

Grant/Contract Number:: SC0005397

OSTI ID:: 1533068

Alternate ID(s):: OSTI ID: 1400587

Journal Information:: Advanced Energy Materials, Vol. 7, Issue 5; ISSN 1614-6832

Publisher:: WileyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 99 works

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Title: A Honeycomb-Layered Oxide Cathode for Sodium-Ion Batteries with Suppressed P3-O1 Phase Transition

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