Rapid Guest Exchange and Ultra‐Low Surface Tension Solvents Optimize Metal–Organic Framework Activation

Ma, Jialiu; Kalenak, Andre P.; Wong‐Foy, Antek G.; Matzger, Adam J.

doi:10.1002/anie.201709187

Title: Rapid Guest Exchange and Ultra‐Low Surface Tension Solvents Optimize Metal–Organic Framework Activation

Journal Article · Fri Oct 20 00:00:00 EDT 2017 · Angewandte Chemie (International Edition)

DOI:https://doi.org/10.1002/anie.201709187· OSTI ID:1400421

^[1]; Kalenak, Andre P. ^[1];

^[1];

^[1]

Department of Chemistry University of Michigan 930 N. University Ave Ann Arbor MI 48109 USA

Abstract Exploratory research into the critical steps in metal–organic framework (MOF) activation involving solvent exchange and solvent evacuation are reported. It is discovered that solvent exchange kinetics are extremely fast, and minutes rather days are appropriate for solvent exchange in many MOFs. It is also demonstrated that choice of a very low surface tension solvent is critical in successfully activating challenging MOFs. MOFs that have failed to be activated previously can achieve predicted surface areas provided that lower surface tension solvents, such as n‐hexane and perfluoropentane, are applied. The insights herein aid in the efficient activation of MOFs in both laboratory and industrial settings and provide best practices for avoiding structural collapse.

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Sponsoring Organization:: USDOE

OSTI ID:: 1400421

Journal Information:: Angewandte Chemie (International Edition), Journal Name: Angewandte Chemie (International Edition) Vol. 56 Journal Issue: 46; ISSN 1433-7851

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 86 works

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