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Title: Sealing glass-ceramics with near-linear thermal strain, part III: Stress modeling of strain and strain rate matched glass-ceramic to metal seals

Journal Article · · Journal of the American Ceramic Society
DOI:https://doi.org/10.1111/jace.14821· OSTI ID:1399893
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  1. Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)

Thermal mechanical stresses of glass-ceramic to stainless steel (GCtSS) seals are analyzed using finite element modeling over a temperature cycle from a set temperature (Tset) 500°C to -55°C, and then back to 600°C. There are two glass-ceramics that have an identical coefficient of thermal expansion (CTE) at ~16 ppm/°C but have very different linearity of thermal strains, designated as near-linear NL16 and step-like SL16, and were formed from the same parent glass using different crystallization processes. Stress modeling reveals much higher plastic strain in the stainless steel using SL16 glass-ceramic when the GCtSS seal cools from Tset. Upon heating tensile stresses start to develop at the GC-SS interface before the temperature reaches Tset. On the other hand, the much lower plastic deformation in stainless steel accumulated during cooling using NL16 glass-ceramic allows for radially compressive stress at the GC-SS interface to remain present when the seal is heated back to Tset. Finally, the qualitative stress comparison suggests that with a better match of thermal strain rate to that of stainless steel, the NL16 glass-ceramic not only improves the hermeticity of the GCtSS seals, but would also improve the reliability of the seals exposed to high-temperature and/or high-pressure abnormal environments.

Research Organization:
Sandia National Lab. (SNL-NM), Albuquerque, NM (United States)
Sponsoring Organization:
USDOE National Nuclear Security Administration (NNSA)
Grant/Contract Number:
AC04-94AL85000
OSTI ID:
1399893
Alternate ID(s):
OSTI ID: 1373821
Report Number(s):
SAND2016-10169J; 648180
Journal Information:
Journal of the American Ceramic Society, Vol. 100, Issue 8; ISSN 0002-7820
Publisher:
American Ceramic SocietyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 10 works
Citation information provided by
Web of Science

References (7)

Crystallization of a Glass-Ceramic by Epitaxial Growth journal September 1984
Design of High Thermal Expansion Glass-Ceramics Through Microstructural Control book January 1987
Sealing Glass‐Ceramics with Near Linear Thermal Strain, Part I: Process Development and Phase Identification journal June 2016
Crystallization Kinetics of a Complex Lithium Silicate Glass-Ceramic journal August 1987
Preparation, properties and chemistry of glass- and glass-ceramic-to-metal seals and coatings journal January 1993
Sealing Glass‐Ceramics with Near‐Linear Thermal Strain, Part II : Sequence of Crystallization and Phase Stability journal August 2016
Small Strain Plasticity Behavior of 304L Stainless Steel in Glass-to-Metal Seal Applications book July 2014

Cited By (1)

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