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Title: Cooperative Noncovalent Interactions Induce Ion Pair Separation in Diphenylsilanides

Journal Article · · Chemistry - A European Journal
 [1];  [1];  [1];  [1];  [1]; ORCiD logo [1]
  1. Department of Chemistry Johns Hopkins University 3400 N. Charles St Baltimore MD 21218 USA
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Abstract This crystallographic and computational study describes an unusual potassium silanide structure. A contact ion pair is expected in the solid state between potassium and silicon, yet the potassium cation binds an aromatic ring and the anionic silanide interacts with CH bonds on neighboring crown ether molecules. These structure‐bonding phenomena are attributed to strong soft–soft interactions.

Sponsoring Organization:
USDOE
OSTI ID:
1399800
Journal Information:
Chemistry - A European Journal, Journal Name: Chemistry - A European Journal Vol. 23 Journal Issue: 62; ISSN 0947-6539
Publisher:
Wiley Blackwell (John Wiley & Sons)Copyright Statement
Country of Publication:
Germany
Language:
English
Citation Metrics:
Cited by: 11 works
Citation information provided by
Web of Science

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