Gold Nanoparticles on Polymer‐Wrapped Carbon Nanotubes: An Efficient and Selective Catalyst for the Electroreduction of CO 2

Jhong, Huei‐Ru “Molly”; Tornow, Claire E.; Kim, Chaerin; Verma, Sumit; Oberst, Justin L.; Anderson, Paul S.; Gewirth, Andrew A.; Fujigaya, Tsuyohiko; Nakashima, Naotoshi; Kenis, Paul J. A.

doi:10.1002/cphc.201700815

Title: Gold Nanoparticles on Polymer‐Wrapped Carbon Nanotubes: An Efficient and Selective Catalyst for the Electroreduction of CO ₂

Journal Article · Tue Oct 17 00:00:00 EDT 2017 · ChemPhysChem

DOI:https://doi.org/10.1002/cphc.201700815· OSTI ID:1399798

Jhong, Huei‐Ru “Molly” ^[1]; Tornow, Claire E. ^[2]; Kim, Chaerin ^[3]; Verma, Sumit ^[1]; Oberst, Justin L. ^[2]; Anderson, Paul S. ^[2]; Gewirth, Andrew A. ^[1]; Fujigaya, Tsuyohiko ^[3]; Nakashima, Naotoshi ^[3];

^[1]

Department of Chemistry and Chemical &, Biomolecular Engineering University of Illinois at Urbana Champaign 600 South Mathews Avenue Urbana IL 61801 USA, International Institute for Carbon Neutral Energy Research (WPI-I2CNER) Kyushu University 744 Moto-oka Nishi-ku Fukuoka 819-0395 Japan
Department of Chemistry and Chemical &, Biomolecular Engineering University of Illinois at Urbana Champaign 600 South Mathews Avenue Urbana IL 61801 USA
International Institute for Carbon Neutral Energy Research (WPI-I2CNER) Kyushu University 744 Moto-oka Nishi-ku Fukuoka 819-0395 Japan, Department of Applied Chemistry Kyushu University 744 Moto-oka Nishi-ku Fukuoka 819-0395 Japan

Abstract Multiple approaches will be needed to reduce the atmospheric CO ₂ levels, which have been linked to the undesirable effects of global climate change. The electroreduction of CO ₂ driven by renewable energy is one approach to reduce CO ₂ emissions while producing chemical building blocks, but current electrocatalysts exhibit low activity and selectivity. Here, we report the structural and electrochemical characterization of a promising catalyst for the electroreduction of CO ₂ to CO: Au nanoparticles supported on polymer‐wrapped multiwall carbon nanotubes. This catalyst exhibits high selectivity for CO over H ₂ : 80–92 % CO, as well as high activity: partial current density for CO as high as 160 mA cm ⁻² . The observed high activity, originating from a high electrochemically active surface area (23 m ² g ⁻¹ Au), in combination with the low loading (0.17 mg cm ⁻² ) of the highly dispersed Au nanoparticles underscores the promise of this catalyst for efficient electroreduction of CO ₂ .

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Sponsoring Organization:: USDOE

Grant/Contract Number:: FG02005ER46260, DE-SC0004453

OSTI ID:: 1399798

Journal Information:: ChemPhysChem, Journal Name: ChemPhysChem Vol. 18 Journal Issue: 22; ISSN 1439-4235

Publisher:: Wiley Blackwell (John Wiley & Sons)Copyright Statement

Country of Publication:: Germany

Language:: English

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Cited by: 48 works

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References (38)

Electrochemical conversion of CO2 to useful chemicals: current status, remaining challenges, and future opportunities Jhong, Huei-Ru “Molly”; Ma, Sichao; Kenis, Paul JA Current Opinion in Chemical Engineering, Vol. 2, Issue 2 https://doi.org/10.1016/j.coche.2013.03.005	journal	May 2013
Diesel Production from Fischer−Tropsch: The Past, the Present, and New Concepts Leckel, Dieter Energy & Fuels, Vol. 23, Issue 5 https://doi.org/10.1021/ef900064c	journal	May 2009
The Fischer–Tropsch process: 1950–2000 Dry, Mark E. Catalysis Today, Vol. 71, Issue 3-4 https://doi.org/10.1016/S0920-5861(01)00453-9	journal	January 2002
Efficient Electrochemical Flow System with Improved Anode for the Conversion of CO₂ to CO Ma, S.; Luo, R.; Moniri, S. Journal of the Electrochemical Society, Vol. 161, Issue 10, p. F1124-F1131 https://doi.org/10.1149/2.1201410jes	journal	January 2014
Design of an Assembly of Poly(benzimidazole), Carbon Nanotubes, and Pt Nanoparticles for a Fuel-Cell Electrocatalyst with an Ideal Interfacial Nanostructure Okamoto, Minoru; Fujigaya, Tsuyohiko; Nakashima, Naotoshi Small, Vol. 5, Issue 6 https://doi.org/10.1002/smll.200801742	journal	March 2009
Tuning of Silver Catalyst Mesostructure Promotes Selective Carbon Dioxide Conversion into Fuels Yoon, Youngmin; Hall, Anthony Shoji; Surendranath, Yogesh Angewandte Chemie, Vol. 128, Issue 49 https://doi.org/10.1002/ange.201607942	journal	November 2016
Exceptional Size-Dependent Activity Enhancement in the Electroreduction of CO ₂ over Au Nanoparticles Mistry, Hemma; Reske, Rulle; Zeng, Zhenhua Journal of the American Chemical Society, Vol. 136, Issue 47 https://doi.org/10.1021/ja508879j	journal	November 2014
Influence of dilute feed and pH on electrochemical reduction of CO₂ to CO on Ag in a continuous flow electrolyzer Kim, Byoungsu; Ma, Sichao; Molly Jhong, Huei-Ru Electrochimica Acta, Vol. 166, p. 271-276 https://doi.org/10.1016/j.electacta.2015.03.064	journal	June 2015
Support materials for PEMFC and DMFC electrocatalysts—A review Sharma, Surbhi; Pollet, Bruno G. Journal of Power Sources, Vol. 208 https://doi.org/10.1016/j.jpowsour.2012.02.011	journal	June 2012
Electrocatalytic process of CO selectivity in electrochemical reduction of CO₂ at metal electrodes in aqueous media Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio Electrochimica Acta, Vol. 39, Issue 11-12, p. 1833-1839 https://doi.org/10.1016/0013-4686(94)85172-7	journal	August 1994
Towards sustainable fuels and chemicals through the electrochemical reduction of CO ₂ : lessons from water electrolysis Martín, Antonio J.; Larrazábal, Gastón O.; Pérez-Ramírez, Javier Green Chemistry, Vol. 17, Issue 12 https://doi.org/10.1039/C5GC01893E	journal	January 2015
A selective and efficient electrocatalyst for carbon dioxide reduction Lu, Qi; Rosen, Jonathan; Zhou, Yang Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4242	journal	January 2014
Design of an assembly of pyridine-containing polybenzimidazole, carbon nanotubes and Pt nanoparticles for a fuel cell electrocatalyst with a high electrochemically active surface area Fujigaya, Tsuyohiko; Okamoto, Minoru; Nakashima, Naotoshi Carbon, Vol. 47, Issue 14 https://doi.org/10.1016/j.carbon.2009.07.038	journal	November 2009
Fuel Cell Electrocatalyst Using Polybenzimidazole-Modified Carbon Nanotubes As Support Materials Fujigaya, Tsuyohiko; Nakashima, Naotoshi Advanced Materials, Vol. 25, Issue 12 https://doi.org/10.1002/adma.201204461	journal	February 2013
Real surface area measurements in electrochemistry Trasatti, S.; Petrii, O. A. Pure and Applied Chemistry, Vol. 63, Issue 5 https://doi.org/10.1351/pac199163050711	journal	January 1991
Preparation and characterisation of platinum- and gold-coated copper, iron, cobalt and nickel deposits on glassy carbon substrates Papadimitriou, S.; Tegou, A.; Pavlidou, E. Electrochimica Acta, Vol. 53, Issue 22 https://doi.org/10.1016/j.electacta.2008.04.015	journal	September 2008
Tuning of Silver Catalyst Mesostructure Promotes Selective Carbon Dioxide Conversion into Fuels Yoon, Youngmin; Hall, Anthony Shoji; Surendranath, Yogesh Angewandte Chemie International Edition, Vol. 55, Issue 49 https://doi.org/10.1002/anie.201607942	journal	November 2016
Operation of a Pressurized System for Continuous Reduction of CO ₂ Dufek, Eric J.; Lister, Tedd E.; Stone, Simon G. Journal of The Electrochemical Society, Vol. 159, Issue 9 https://doi.org/10.1149/2.011209jes	journal	January 2012
Monodisperse Au Nanoparticles for Selective Electrocatalytic Reduction of CO ₂ to CO Zhu, Wenlei; Michalsky, Ronald; Metin, Önder Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja409445p	journal	October 2013
Activity Descriptors for CO ₂ Electroreduction to Methane on Transition-Metal Catalysts Peterson, Andrew A.; Nørskov, Jens K. The Journal of Physical Chemistry Letters, Vol. 3, Issue 2 https://doi.org/10.1021/jz201461p	journal	January 2012
The Effects of Catalyst Layer Deposition Methodology on Electrode Performance Jhong, Huei-Ru “Molly”; Brushett, Fikile R.; Kenis, Paul J. A. Advanced Energy Materials, Vol. 3, Issue 5 https://doi.org/10.1002/aenm.201200759	journal	February 2013
A Gross-Margin Model for Defining Technoeconomic Benchmarks in the Electroreduction of CO ₂ Verma, Sumit; Kim, Byoungsu; Jhong, Huei-Ru “Molly” ChemSusChem, Vol. 9, Issue 15 https://doi.org/10.1002/cssc.201600394	journal	June 2016
Future CO ₂ Emissions and Climate Change from Existing Energy Infrastructure Davis, Steven J.; Caldeira, Ken; Matthews, H. Damon Science, Vol. 329, Issue 5997 https://doi.org/10.1126/science.1188566	journal	September 2010
New trends in the development of heterogeneous catalysts for electrochemical CO 2 reduction Kumar, Bijandra; Brian, Joseph P.; Atla, Veerendra Catalysis Today, Vol. 270 https://doi.org/10.1016/j.cattod.2016.02.006	journal	July 2016
Effect of Cations on the Electrochemical Conversion of CO₂ to CO Thorson, M. R.; Siil, K. I.; Kenis, P. J. A. Journal of the Electrochemical Society, Vol. 160, Issue 1, p. F69-F74 https://doi.org/10.1149/2.052301jes	journal	November 2012
Bottom-up design of carbon nanotube-based electrocatalysts and their application in high temperature operating polymer electrolyte fuel cells Matsumoto, Kazuya; Fujigaya, Tsuyohiko; Sasaki, Kazunari J. Mater. Chem., Vol. 21, Issue 4 https://doi.org/10.1039/C0JM02744H	journal	January 2011
Quantum Description of the Plasmon Resonances of a Nanoparticle Dimer Zuloaga, Jorge; Prodan, Emil; Nordlander, Peter Nano Letters, Vol. 9, Issue 2 https://doi.org/10.1021/nl803811g	journal	February 2009
Stabilization Wedges: Solving the Climate Problem for the Next 50 Years with Current Technologies Pacala, S. Science, Vol. 305, Issue 5686 https://doi.org/10.1126/science.1100103	journal	August 2004
Greenhouse Gas Emissions, Energy Efficiency, and Cost of Synthetic Fuel Production Using Electrochemical CO ₂ Conversion and the Fischer–Tropsch Process Li, Xuping; Anderson, Paul; Jhong, Huei-Ru Molly Energy & Fuels, Vol. 30, Issue 7 https://doi.org/10.1021/acs.energyfuels.6b00665	journal	June 2016
Electrocatalytic activity of carbon-supported Pt–Au nanoparticles for methanol electro-oxidation Park, In-Su; Lee, Kug-Seung; Jung, Dae-Sik Electrochimica Acta, Vol. 52, Issue 18 https://doi.org/10.1016/j.electacta.2006.12.068	journal	May 2007
Prospects of CO₂ Utilization via Direct Heterogeneous Electrochemical Reduction Whipple, Devin T.; Kenis, Paul J. A. The Journal of Physical Chemistry Letters, Vol. 1, Issue 24, p. 3451-3458 https://doi.org/10.1021/jz1012627	journal	December 2010
Aqueous CO ₂ Reduction at Very Low Overpotential on Oxide-Derived Au Nanoparticles Chen, Yihong; Li, Christina W.; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 134, Issue 49 https://doi.org/10.1021/ja309317u	journal	November 2012
A comprehensive review on PEM water electrolysis Carmo, Marcelo; Fritz, David L.; Mergel, Jürgen International Journal of Hydrogen Energy, Vol. 38, Issue 12, p. 4901-4934 https://doi.org/10.1016/j.ijhydene.2013.01.151	journal	April 2013
The effect of electrolyte composition on the electroreduction of CO ₂ to CO on Ag based gas diffusion electrodes Verma, Sumit; Lu, Xun; Ma, Sichao Physical Chemistry Chemical Physics, Vol. 18, Issue 10 https://doi.org/10.1039/C5CP05665A	journal	January 2016
Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO ₂ Fixation Appel, Aaron M.; Bercaw, John E.; Bocarsly, Andrew B. Chemical Reviews, Vol. 113, Issue 8 https://doi.org/10.1021/cr300463y	journal	June 2013
Rethinking wedges Davis, Steven J.; Cao, Long; Caldeira, Ken Environmental Research Letters, Vol. 8, Issue 1 https://doi.org/10.1088/1748-9326/8/1/011001	journal	January 2013
Bench-scale electrochemical system for generation of CO and syn-gas Dufek, Eric J.; Lister, Tedd E.; McIlwain, Michael E. Journal of Applied Electrochemistry, Vol. 41, Issue 6 https://doi.org/10.1007/s10800-011-0271-6	journal	March 2011
Microfluidic Reactor for the Electrochemical Reduction of Carbon Dioxide: The Effect of pH Whipple, Devin T.; Finke, Eryn C.; Kenis, Paul J. A. Electrochemical and Solid-State Letters, Vol. 13, Issue 9 https://doi.org/10.1149/1.3456590	journal	January 2010

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Title: Gold Nanoparticles on Polymer‐Wrapped Carbon Nanotubes: An Efficient and Selective Catalyst for the Electroreduction of CO ₂