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Title: Heat-Treatment of Defective UiO-66 from Modulated Synthesis: Adsorption and Stability Studies

Abstract

Defect engineering in metal–organic frameworks (MOFs) is an emerging strategy that can be used to control physical or chemical characteristics of MOFs, including adsorption behavior and textural, mechanical, and conductive properties. Understanding the impact of defects on textural properties and chemical stability of MOFs is imperative to the development of MOFs with tunable defect sites. In this work, systematic adsorption measurements were performed with three adsorbate molecules (SO 2, benzene, and cyclohexane) to investigate changes in the pore size of defective UiO-66. Compared to the parent UiO-66, the defective UiO-66 shows significant changes in adsorption capacities among the selected adsorbate molecules, demonstrating that pore size is significantly enlarged by the missing cluster defects. BET surface area analysis and DFT calculations were also performed to interrogate the chemical stability of the defective MOFs after exposure to water and acidic environments. This work shows that pore size can be tuned as a function of defect concentration. Further, it is shown that the structural incorporation of trifluoroacetate groups in defective UiO-66 leads to an increase in average pore size without sacrificing chemical stability toward water and acidic species. The results of this work advance the understanding of textural properties and chemical stability ofmore » defect-engineered MOFs and also suggest a preparation method for synthesizing defective but stable MOFs.« less

Authors:
ORCiD logo [1];  [1];  [1];  [1];  [1]; ORCiD logo [1]; ORCiD logo [1]; ORCiD logo [1]
  1. Georgia Inst. of Technology, Atlanta, GA (United States). School of Chemical and Biomolecular Engineering
Publication Date:
Research Org.:
Georgia Tech Research Corporation, Atlanta, GA (United States); Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
Contributing Org.:
Center for “Understanding and Control of Acid Gas-Induced Evolution of Materials for Energy”
OSTI Identifier:
1399606
Alternate Identifier(s):
OSTI ID: 1413283
Grant/Contract Number:  
SC0012577
Resource Type:
Journal Article: Published Article
Journal Name:
Journal of Physical Chemistry. C
Additional Journal Information:
Journal Volume: 121; Journal Issue: 42; Journal ID: ISSN 1932-7447
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Jiao, Yang, Liu, Yang, Zhu, Guanghui, Hungerford, Julian T., Bhattacharyya, Souryadeep, Lively, Ryan P., Sholl, David S., and Walton, Krista S. Heat-Treatment of Defective UiO-66 from Modulated Synthesis: Adsorption and Stability Studies. United States: N. p., 2017. Web. doi:10.1021/acs.jpcc.7b07772.
Jiao, Yang, Liu, Yang, Zhu, Guanghui, Hungerford, Julian T., Bhattacharyya, Souryadeep, Lively, Ryan P., Sholl, David S., & Walton, Krista S. Heat-Treatment of Defective UiO-66 from Modulated Synthesis: Adsorption and Stability Studies. United States. doi:10.1021/acs.jpcc.7b07772.
Jiao, Yang, Liu, Yang, Zhu, Guanghui, Hungerford, Julian T., Bhattacharyya, Souryadeep, Lively, Ryan P., Sholl, David S., and Walton, Krista S. Thu . "Heat-Treatment of Defective UiO-66 from Modulated Synthesis: Adsorption and Stability Studies". United States. doi:10.1021/acs.jpcc.7b07772.
@article{osti_1399606,
title = {Heat-Treatment of Defective UiO-66 from Modulated Synthesis: Adsorption and Stability Studies},
author = {Jiao, Yang and Liu, Yang and Zhu, Guanghui and Hungerford, Julian T. and Bhattacharyya, Souryadeep and Lively, Ryan P. and Sholl, David S. and Walton, Krista S.},
abstractNote = {Defect engineering in metal–organic frameworks (MOFs) is an emerging strategy that can be used to control physical or chemical characteristics of MOFs, including adsorption behavior and textural, mechanical, and conductive properties. Understanding the impact of defects on textural properties and chemical stability of MOFs is imperative to the development of MOFs with tunable defect sites. In this work, systematic adsorption measurements were performed with three adsorbate molecules (SO2, benzene, and cyclohexane) to investigate changes in the pore size of defective UiO-66. Compared to the parent UiO-66, the defective UiO-66 shows significant changes in adsorption capacities among the selected adsorbate molecules, demonstrating that pore size is significantly enlarged by the missing cluster defects. BET surface area analysis and DFT calculations were also performed to interrogate the chemical stability of the defective MOFs after exposure to water and acidic environments. This work shows that pore size can be tuned as a function of defect concentration. Further, it is shown that the structural incorporation of trifluoroacetate groups in defective UiO-66 leads to an increase in average pore size without sacrificing chemical stability toward water and acidic species. The results of this work advance the understanding of textural properties and chemical stability of defect-engineered MOFs and also suggest a preparation method for synthesizing defective but stable MOFs.},
doi = {10.1021/acs.jpcc.7b07772},
journal = {Journal of Physical Chemistry. C},
number = 42,
volume = 121,
place = {United States},
year = {Thu Sep 21 00:00:00 EDT 2017},
month = {Thu Sep 21 00:00:00 EDT 2017}
}

Journal Article:
Free Publicly Available Full Text
Publisher's Version of Record at 10.1021/acs.jpcc.7b07772

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Cited by: 4 works
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