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Title: Incorporating Rich Mesoporosity into a Ceria-Based Catalyst via Mechanochemistry

Abstract

Ceria-based materials possessing mesoporous structures afford higher activity than the corresponding bulk materials in CO oxidation and other catalytic applications, because of the wide pore channel and high surface area. The development of a direct, template-free, and scalable technology for directing porosity inside ceriabased materials is highly welcome. Here in this paper, a family of mesoporous transition-metaldoped ceria catalysts with specific surface areas up to 122 m 2 g -1 is constructed by mechanochemical grinding. No templates, additives, or solvents are needed in this process, while the mechanochemistry-mediated restructuring and the decomposing of the organic group led to plentiful mesopores. Interestingly, the copper species are evenly dispersed in the ceria matrix at the atomic scale, as observed in high resolution scanning transmission electron microscopy in high angle annular dark field. The copper-doped ceria materials show good activity in the CO oxidation.

Authors:
 [1]; ORCiD logo [2]; ORCiD logo [3];  [1]; ORCiD logo [1]; ORCiD logo [2]; ORCiD logo [4]
  1. East China Univ. of Science and Technology, Shanghai (China). Key Lab. for Advanced Materials and Research Inst. of Industrial Catalysis
  2. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Materials Science & Technology Division
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Shanghai Jiao Tong Univ. (China). School of Chemistry and Chemical Engineering
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Chemical Sciences Division; Univ. of Tennessee, Knoxville, TN (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Key Basic Research Program of China; National Science Foundation (NSF)
OSTI Identifier:
1399408
Grant/Contract Number:  
AC05-00OR22725; AC02-05CH11231; ACI-1053575
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Chemistry of Materials
Additional Journal Information:
Journal Volume: 29; Journal Issue: 17; Journal ID: ISSN 0897-4756
Publisher:
American Chemical Society (ACS)
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Zhan, Wangcheng, Yang, Shize, Zhang, Pengfei, Guo, Yanglong, Lu, Guanzhong, Chisholm, Matthew F., and Dai, Sheng. Incorporating Rich Mesoporosity into a Ceria-Based Catalyst via Mechanochemistry. United States: N. p., 2017. Web. doi:10.1021/acs.chemmater.7b02206.
Zhan, Wangcheng, Yang, Shize, Zhang, Pengfei, Guo, Yanglong, Lu, Guanzhong, Chisholm, Matthew F., & Dai, Sheng. Incorporating Rich Mesoporosity into a Ceria-Based Catalyst via Mechanochemistry. United States. doi:10.1021/acs.chemmater.7b02206.
Zhan, Wangcheng, Yang, Shize, Zhang, Pengfei, Guo, Yanglong, Lu, Guanzhong, Chisholm, Matthew F., and Dai, Sheng. Tue . "Incorporating Rich Mesoporosity into a Ceria-Based Catalyst via Mechanochemistry". United States. doi:10.1021/acs.chemmater.7b02206. https://www.osti.gov/servlets/purl/1399408.
@article{osti_1399408,
title = {Incorporating Rich Mesoporosity into a Ceria-Based Catalyst via Mechanochemistry},
author = {Zhan, Wangcheng and Yang, Shize and Zhang, Pengfei and Guo, Yanglong and Lu, Guanzhong and Chisholm, Matthew F. and Dai, Sheng},
abstractNote = {Ceria-based materials possessing mesoporous structures afford higher activity than the corresponding bulk materials in CO oxidation and other catalytic applications, because of the wide pore channel and high surface area. The development of a direct, template-free, and scalable technology for directing porosity inside ceriabased materials is highly welcome. Here in this paper, a family of mesoporous transition-metaldoped ceria catalysts with specific surface areas up to 122 m2 g-1 is constructed by mechanochemical grinding. No templates, additives, or solvents are needed in this process, while the mechanochemistry-mediated restructuring and the decomposing of the organic group led to plentiful mesopores. Interestingly, the copper species are evenly dispersed in the ceria matrix at the atomic scale, as observed in high resolution scanning transmission electron microscopy in high angle annular dark field. The copper-doped ceria materials show good activity in the CO oxidation.},
doi = {10.1021/acs.chemmater.7b02206},
journal = {Chemistry of Materials},
number = 17,
volume = 29,
place = {United States},
year = {Tue Aug 15 00:00:00 EDT 2017},
month = {Tue Aug 15 00:00:00 EDT 2017}
}

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