skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Characterization of defects in copper antimony disulfide

Journal Article · · Journal of Materials Chemistry. A
DOI:https://doi.org/10.1039/C7TA07012H· OSTI ID:1399356

Copper antimony disulfide (CuSbS2) has several excellent bulk optoelectronic properties for photovoltaic absorber applications. Here, we report on the defect properties in CuSbS2thin film materials and photovoltaic devices studied using several experimental methods supported by theoretical calculations.

Research Organization:
National Renewable Energy Lab. (NREL), Golden, CO (United States)
Sponsoring Organization:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Renewable Power Office. Solar Energy Technologies Office
Grant/Contract Number:
AC36-08GO28308
OSTI ID:
1399356
Report Number(s):
NREL/JA-5K00-70120; JMCAET
Journal Information:
Journal of Materials Chemistry. A, Vol. 5, Issue 41; ISSN 2050-7488
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 24 works
Citation information provided by
Web of Science

References (36)

Generalized Gradient Approximation Made Simple journal October 1996
Band-structure, optical properties, and defect physics of the photovoltaic semiconductor SnS journal January 2012
Effects of Disorder on Carrier Transport in Cu 2 SnS 3 journal October 2015
Free-to-bound recombination in near stoichiometric Cu 2 ZnSnS 4 single crystals journal July 2012
Projector augmented-wave method journal December 1994
Microphotoluminescence study of Cu2ZnSnS4 polycrystals journal January 2013
Photoluminescence and electrical study of fluctuating potentials in Cu 2 ZnSnS 4 -based thin films journal July 2011
Defect Tolerant Semiconductors for Solar Energy Conversion journal March 2014
Thin film solar cell based on CuSbS2 absorber fabricated from an electrochemically deposited metal stack journal January 2014
Determination of defect distributions from admittance measurements and application to Cu(In,Ga)Se 2 based heterojunctions journal October 1996
Luminescence of Cu 2 ZnSnS 4 polycrystals described by the fluctuating potential model journal June 2013
Effects of Thermochemical Treatment on CuSbS 2 Photovoltaic Absorber Quality and Solar Cell Reproducibility journal August 2016
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set journal October 1996
From ultrasoft pseudopotentials to the projector augmented-wave method journal January 1999
Self-regulated growth and tunable properties of CuSbS2 solar absorbers journal January 2015
Donor–acceptor pair recombination in gallium sulfide journal December 2000
Ab initio molecular-dynamics simulation of the liquid-metal–amorphous-semiconductor transition in germanium journal May 1994
First-principles calculations for point defects in solids journal March 2014
Electron-energy-loss spectra and the structural stability of nickel oxide: An LSDA+U study journal January 1998
Donor-acceptor pair recombination luminescence from monoclinic Cu 2 SnS 3 thin film journal July 2015
Assessment of correction methods for the band-gap problem and for finite-size effects in supercell defect calculations: Case studies for ZnO and GaAs journal December 2008
Photoluminescence properties of polycrystalline AgGaTe2 journal August 2006
Luminescence properties of defects in GaN journal March 2005
Temperature dependence of pair band luminescence in GaP journal March 1965
Does the low-temperature Arrhenius plot of the photoluminescence intensity in CdTe point towards an erroneous activation energy? journal February 1997
CuSbS 2 as a Promising Earth-Abundant Photovoltaic Absorber Material: A Combined Theoretical and Experimental Study journal May 2014
Theoretical Prediction and Experimental Realization of New Stable Inorganic Materials Using the Inverse Design Approach journal June 2013
Required material properties for high-efficiency CIGS modules conference August 2009
CuSbSe 2 photovoltaic devices with 3% efficiency journal July 2015
Optimization of CBD CdS process in high-efficiency Cu(In,Ga)Se2-based solar cells journal February 2002
A review of defects and disorder in multinary tetrahedrally bonded semiconductors journal November 2016
Preparation, formation mechanism and photoelectric properties of well-aligned CuSbS2 nanowires journal November 2015
Photoluminescence investigation of Cu 2 ZnSnS 4 thin film solar cells journal May 2015
Deep Level Transient Fourier Spectroscopy (DLTFS)—A technique for the analysis of deep level properties journal December 1988
Defect levels in Cu 2 ZnSn(S x Se 1−x ) 4 solar cells probed by current-mode deep level transient spectroscopy journal May 2014
Geometry, Electronic Structure, and Bonding in CuMCh 2 (M = Sb, Bi; Ch = S, Se): Alternative Solar Cell Absorber Materials? journal March 2012

Cited By (8)

Simulation studies on photovoltaic response of ultrathin CuSb(S/Se) 2 ternary compound semiconductors absorber‐based single junction solar cells journal April 2020
High open-circuit voltage CuSbS 2 solar cells achieved through the formation of epitaxial growth of CdS/CuSbS 2 hetero-interface by post-annealing treatment journal July 2018
Review of Recent Progress in Antimony Chalcogenide‐Based Solar Cells: Materials and Devices journal March 2019
Spray pyrolysis deposited CuSbS2 absorber layers for thin-film solar cells journal November 2019
Multimodal characterization of solution-processed Cu 3 SbS 4 absorbers for thin film solar cells journal January 2018
Research Update: Emerging chalcostibite absorbers for thin-film solar cells journal August 2018
Band gap temperature-dependence and exciton-like state in copper antimony sulphide, CuSbS 2 journal August 2018
Observation of photoluminescence edge emission in CuSbSe 2 absorber material for photovoltaic applications journal August 2019