Exploring the Promotion of Synthons of Choice: Halogen Bonding in Molecular Lanthanide Complexes Characterized via X-ray Diffraction, Luminescence Spectroscopy, and Magnetic Measurements
Abstract
Promotion of a synthon of choice for the non‐covalent assembly of lanthanide tectons represents both a noteworthy challenge and opportunity within Ln III hybrid materials. We have developed a system, wherein some control can be exercised over supramolecular assembly and, as part of continued efforts to improve this process we have generated a family of ten new lanthanide ( Ln = Sm 3+ – Lu 3+ ) 2,4,6‐trichlorobenzoic acid‐1,10‐phenanthroline molecular complexes. Delineation of criteria for promoting assembly via halogen based interactions was introduced previously and is refined herein based on the characterization of complexes 1 – 10 via single‐crystal X‐ray diffraction. Direct comparison of means of supramolecular assembly for 1 – 10 with isostructural Ln ‐ p ‐chlorobenzoic acid‐1,10‐phenanthroline analogues verifies that increasing the number of halogen atoms at the periphery of a tecton is one route that increases the frequency of halogen bonding interactions. Additionally, solid‐state visible and near‐IR photoluminescence and luminescent lifetime data were collected for complexes 1 (Sm 3+ ), 2 (Eu 3+ ), 4 (Tb 3+ ), 5 (Dy 3+ ), 6 (Ho 3+ ), 7 (Er 3+ ), and 9 (Yb 3+ ) and characteristic emission was observed for all complexes except 6 . Further,more »
- Authors:
-
- George Washington Univ., Washington, DC (United States). Dept. of Chemistry
- Cardiff Univ., Wales (United Kingdom). School of Chemistry
- Univ. of Ottawa, Ottawa, ON (Canada). Dept. of Chemistry and Biomolecular Sciences
- Publication Date:
- Research Org.:
- Energy Frontier Research Centers (EFRC) (United States). Materials Science of Actinides (MSA)
- Sponsoring Org.:
- USDOE Office of Science (SC), Basic Energy Sciences (BES)
- OSTI Identifier:
- 1470041
- Alternate Identifier(s):
- OSTI ID: 1399274
- Grant/Contract Number:
- SC0001089
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Zeitschrift fuer Anorganische und Allgemeine Chemie
- Additional Journal Information:
- Journal Volume: 643; Journal Issue: 23; Related Information: MSA partners with University of Notre Dame (lead); University of California, Davis; Florida State University; George Washington University; University of Michigan; University of Minnesota; Oak Ridge National Laboratory; Oregon state University; Rensselaer Polytechnic Institute; Savannah River National Laboratory; Journal ID: ISSN 0044-2313
- Publisher:
- Wiley
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 36 MATERIALS SCIENCE; nuclear (including radiation effects); materials and chemistry by design; synthesis (novel materials), synthesis (self-assembly)
Citation Formats
Carter, Korey P., Pope, Simon J. A., Kalaj, Mark, Holmberg, Rebecca J., Murugesu, Muralee, and Cahill, Christopher L. Exploring the Promotion of Synthons of Choice: Halogen Bonding in Molecular Lanthanide Complexes Characterized via X-ray Diffraction, Luminescence Spectroscopy, and Magnetic Measurements. United States: N. p., 2017.
Web. doi:10.1002/zaac.201700341.
Carter, Korey P., Pope, Simon J. A., Kalaj, Mark, Holmberg, Rebecca J., Murugesu, Muralee, & Cahill, Christopher L. Exploring the Promotion of Synthons of Choice: Halogen Bonding in Molecular Lanthanide Complexes Characterized via X-ray Diffraction, Luminescence Spectroscopy, and Magnetic Measurements. United States. https://doi.org/10.1002/zaac.201700341
Carter, Korey P., Pope, Simon J. A., Kalaj, Mark, Holmberg, Rebecca J., Murugesu, Muralee, and Cahill, Christopher L. 2017.
"Exploring the Promotion of Synthons of Choice: Halogen Bonding in Molecular Lanthanide Complexes Characterized via X-ray Diffraction, Luminescence Spectroscopy, and Magnetic Measurements". United States. https://doi.org/10.1002/zaac.201700341. https://www.osti.gov/servlets/purl/1470041.
@article{osti_1470041,
title = {Exploring the Promotion of Synthons of Choice: Halogen Bonding in Molecular Lanthanide Complexes Characterized via X-ray Diffraction, Luminescence Spectroscopy, and Magnetic Measurements},
author = {Carter, Korey P. and Pope, Simon J. A. and Kalaj, Mark and Holmberg, Rebecca J. and Murugesu, Muralee and Cahill, Christopher L.},
abstractNote = {Promotion of a synthon of choice for the non‐covalent assembly of lanthanide tectons represents both a noteworthy challenge and opportunity within Ln III hybrid materials. We have developed a system, wherein some control can be exercised over supramolecular assembly and, as part of continued efforts to improve this process we have generated a family of ten new lanthanide ( Ln = Sm 3+ – Lu 3+ ) 2,4,6‐trichlorobenzoic acid‐1,10‐phenanthroline molecular complexes. Delineation of criteria for promoting assembly via halogen based interactions was introduced previously and is refined herein based on the characterization of complexes 1 – 10 via single‐crystal X‐ray diffraction. Direct comparison of means of supramolecular assembly for 1 – 10 with isostructural Ln ‐ p ‐chlorobenzoic acid‐1,10‐phenanthroline analogues verifies that increasing the number of halogen atoms at the periphery of a tecton is one route that increases the frequency of halogen bonding interactions. Additionally, solid‐state visible and near‐IR photoluminescence and luminescent lifetime data were collected for complexes 1 (Sm 3+ ), 2 (Eu 3+ ), 4 (Tb 3+ ), 5 (Dy 3+ ), 6 (Ho 3+ ), 7 (Er 3+ ), and 9 (Yb 3+ ) and characteristic emission was observed for all complexes except 6 . Further, direct current magnetic susceptibility measurements were carried out for complexes 5 (Dy 3+ ) and 7 (Er 3+ ), and two slow magnetic relaxation processes were characterized using alternating current magnetic susceptibility measurements for 5 .},
doi = {10.1002/zaac.201700341},
url = {https://www.osti.gov/biblio/1470041},
journal = {Zeitschrift fuer Anorganische und Allgemeine Chemie},
issn = {0044-2313},
number = 23,
volume = 643,
place = {United States},
year = {Fri Sep 29 00:00:00 EDT 2017},
month = {Fri Sep 29 00:00:00 EDT 2017}
}
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