Two-Dimensional Titanium Carbide (MXene) as Surface-Enhanced Raman Scattering Substrate

Sarycheva, Asia; Makaryan, Taron; Maleski, Kathleen; Satheeshkumar, Elumalai; Melikyan, Armen; Minassian, Hayk; Yoshimura, Masahiro; Gogotsi, Yury G.

doi:10.1021/acs.jpcc.7b08180

Title: Two-Dimensional Titanium Carbide (MXene) as Surface-Enhanced Raman Scattering Substrate

Journal Article · Tue Aug 22 00:00:00 EDT 2017 · Journal of Physical Chemistry. C

DOI:https://doi.org/10.1021/acs.jpcc.7b08180· OSTI ID:1399222

^[1]; Makaryan, Taron ^[1];

^[1];

^[2]; Melikyan, Armen ^[3]; Minassian, Hayk ^[4]; Yoshimura, Masahiro ^[5];

^[1]

Drexel Univ., Philadelphia, PA (United States)
National Cheng Kung Univ., Tainan (Taiwan); National Institute of Technology-Trichy, Tamil Nadu (India)
Russian-Armenian (Slavonic) State Univ., Yerevan (Armenia)
A. Alikhanian National Science Lab., Yerevan (Armenia)
National Cheng Kung Univ., Tainan (Taiwan)

Here, noble metal (gold or silver) nanoparticles or patterned films are typically used as substrates for surface-enhanced Raman spectroscopy (SERS). Two-dimensional (2D) carbides and nitrides (MXenes) exhibit unique electronic and optical properties, including metallic conductivity and plasmon resonance in the visible or near-infrared range, making them promising candidates for a wide variety of applications. Herein, we show that 2D titanium carbide, Ti₃C₂T_x, enhances Raman signal from organic dyes on a substrate and in solution. As a proof of concept, MXene SERS substrates were manufactured by spray-coating and used to detect several common dyes, with calculated enhancement factors reaching ~10⁶. Titanium carbide MXene demonstrates SERS effect in aqueous colloidal solutions, suggesting the potential for biomedical or environmental applications, where MXene can selectively enhance positively charged molecules.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States); Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC05-00OR22725

OSTI ID:: 1399222

Journal Information:: Journal of Physical Chemistry. C, Vol. 121, Issue 36; ISSN 1932-7447

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 214 works

Citation information provided by
Web of Science

References (28)

Probing the Structure of Single-Molecule Surface-Enhanced Raman Scattering Hot Spots Camden, Jon P.; Dieringer, Jon A.; Wang, Yingmin Journal of the American Chemical Society, Vol. 130, Issue 38, p. 12616-12617 https://doi.org/10.1021/ja8051427	journal	September 2008
Single Molecule Detection Using Surface-Enhanced Raman Scattering (SERS) Kneipp, Katrin; Wang, Yang; Kneipp, Harald Physical Review Letters, Vol. 78, Issue 9, p. 1667-1670 https://doi.org/10.1103/PhysRevLett.78.1667	journal	March 1997
Surface-Enhanced Raman Spectroscopy and Nanogeometry: The Plasmonic Origin of SERS Lee, Seung Joon; Guan, Zhiqiang; Xu, Hongxing The Journal of Physical Chemistry C, Vol. 111, Issue 49 https://doi.org/10.1021/jp077422g	journal	December 2007
Potential of Surface Enhanced Raman Spectroscopy (SERS) in Therapeutic Drug Monitoring (TDM). A Critical Review Jaworska, Aleksandra; Fornasaro, Stefano; Sergo, Valter Biosensors, Vol. 6, Issue 3 https://doi.org/10.3390/bios6030047	journal	September 2016
Interrogating Cells, Tissues, and Live Animals with New Generations of Surface-Enhanced Raman Scattering Probes and Labels Kneipp, Janina ACS Nano, Vol. 11, Issue 2 https://doi.org/10.1021/acsnano.7b00152	journal	February 2017
Surface-Enhanced Raman Spectroscopy-Active Substrates: Adapting the Shape of Plasmonic Nanoparticles for Different Biological Applications Vitol, Elina A.; Friedman, Gary; Gogotsi, Yury Journal of Nanoscience and Nanotechnology, Vol. 14, Issue 4 https://doi.org/10.1166/jnn.2014.8610	journal	April 2014
One-dimensional nanoprobes for single-cell studies Gao, Yang; Longenbach, Travis; Vitol, Elina A. Nanomedicine, Vol. 9, Issue 1 https://doi.org/10.2217/nnm.13.196	journal	January 2014
Surface-Enhanced Raman Spectroscopy: Concepts and Chemical Applications Schlücker, Sebastian Angewandte Chemie International Edition, Vol. 53, Issue 19 https://doi.org/10.1002/anie.201205748	journal	April 2014
Prospects for plasmonic hot spots in single molecule SERS towards the chemical imaging of live cells Radziuk, Darya; Moehwald, Helmuth Physical Chemistry Chemical Physics, Vol. 17, Issue 33 https://doi.org/10.1039/C4CP04946B	journal	January 2015
High-performance SERS substrates: Advances and challenges Sharma, Bhavya; Fernanda Cardinal, M.; Kleinman, Samuel L. MRS Bulletin, Vol. 38, Issue 8 https://doi.org/10.1557/mrs.2013.161	journal	August 2013
The effect of field gradient on SERS Aikens, Christine M.; Madison, Lindsey R.; Schatz, George C. Nature Photonics, Vol. 7, Issue 7 https://doi.org/10.1038/nphoton.2013.153	journal	June 2013
Ultrasensitive molecular sensor using N-doped graphene through enhanced Raman scattering Feng, Simin; dos Santos, Maria Cristina; Carvalho, Bruno R. Science Advances, Vol. 2, Issue 7 https://doi.org/10.1126/sciadv.1600322	journal	July 2016
Raman Enhancement Effect on Two-Dimensional Layered Materials: Graphene, h-BN and MoS ₂ Ling, Xi; Fang, Wenjing; Lee, Yi-Hsien Nano Letters, Vol. 14, Issue 6 https://doi.org/10.1021/nl404610c	journal	April 2014
NMR reveals the surface functionalisation of Ti ₃ C ₂ MXene Hope, Michael A.; Forse, Alexander C.; Griffith, Kent J. Physical Chemistry Chemical Physics, Vol. 18, Issue 7 https://doi.org/10.1039/C6CP00330C	journal	January 2016
Novel amperometric glucose biosensor based on MXene nanocomposite Rakhi, R. B.; Nayak, Pranati; Xia, Chuan Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep36422	journal	November 2016
Antibacterial Activity of Ti ₃ C ₂ T _x MXene Rasool, Kashif; Helal, Mohamed; Ali, Adnan ACS Nano, Vol. 10, Issue 3 https://doi.org/10.1021/acsnano.6b00181	journal	February 2016
Charge- and Size-Selective Ion Sieving Through Ti ₃ C ₂ T _x MXene Membranes Ren, Chang E.; Hatzell, Kelsey B.; Alhabeb, Mohamed The Journal of Physical Chemistry Letters, Vol. 6, Issue 20 https://doi.org/10.1021/acs.jpclett.5b01895	journal	September 2015
Electromagnetic interference shielding with 2D transition metal carbides (MXenes) Shahzad, F.; Alhabeb, M.; Hatter, C. B. Science, Vol. 353, Issue 6304 https://doi.org/10.1126/science.aag2421	journal	September 2016
2D metal carbides and nitrides (MXenes) for energy storage Anasori, Babak; Lukatskaya, Maria R.; Gogotsi, Yury Nature Reviews Materials, Vol. 2, Issue 2 https://doi.org/10.1038/natrevmats.2016.98	journal	January 2017
Spectroscopic evidence in the visible-ultraviolet energy range of surface functionalization sites in the multilayer ${Ti}_{3} C_{2}$ MXene Magne, Damien; Mauchamp, Vincent; Célérier, Stéphane Physical Review B, Vol. 91, Issue 20 https://doi.org/10.1103/PhysRevB.91.201409	journal	May 2015
One-step Solution Processing of Ag, Au and Pd@MXene Hybrids for SERS Satheeshkumar, Elumalai; Makaryan, Taron; Melikyan, Armen Scientific Reports, Vol. 6, Issue 1 https://doi.org/10.1038/srep32049	journal	August 2016
Examining the Performance of Refractory Conductive Ceramics as Plasmonic Materials: A Theoretical Approach Kumar, Mukesh; Umezawa, Naoto; Ishii, Satoshi ACS Photonics, Vol. 3, Issue 1 https://doi.org/10.1021/acsphotonics.5b00409	journal	December 2015
Effect of Synthesis on Quality, Electronic Properties and Environmental Stability of Individual Monolayer Ti ₃ C ₂ MXene Flakes Lipatov, Alexey; Alhabeb, Mohamed; Lukatskaya, Maria R. Advanced Electronic Materials, Vol. 2, Issue 12 https://doi.org/10.1002/aelm.201600255	journal	November 2016
Vibrational properties of Ti ₃ C ₂ and Ti ₃ C ₂ T ₂ (T = O, F, OH) monosheets by first-principles calculations: a comparative study Hu, Tao; Wang, Jiemin; Zhang, Hui Physical Chemistry Chemical Physics, Vol. 17, Issue 15 https://doi.org/10.1039/C4CP05666C	journal	January 2015
Adsorption study of 4-MBA on TiO ₂ nanoparticles by surface-enhanced Raman spectroscopy: Adsorption study of 4-MBA on TiO ₂ nanoparticles by SERS Yang, Libin; Jiang, Xin; Ruan, Weidong Journal of Raman Spectroscopy, Vol. 40, Issue 12 https://doi.org/10.1002/jrs.2358	journal	July 2009
Dye adsorption and decomposition on two-dimensional titanium carbide in aqueous media Mashtalir, O.; Cook, K. M.; Mochalin, V. N. J. Mater. Chem. A, Vol. 2, Issue 35 https://doi.org/10.1039/C4TA02638A	journal	January 2014
Highly Conductive Optical Quality Solution-Processed Films of 2D Titanium Carbide Dillon, Andrew D.; Ghidiu, Michael J.; Krick, Alex L. Advanced Functional Materials, Vol. 26, Issue 23 https://doi.org/10.1002/adfm.201600357	journal	April 2016
High-Throughput Survey of Ordering Configurations in MXene Alloys Across Compositions and Temperatures Tan, Teck Leong; Jin, Hong Mei; Sullivan, Michael B. ACS Nano, Vol. 11, Issue 5 https://doi.org/10.1021/acsnano.6b08227	journal	March 2017

Cited By (22)

Recent developments in emerging two-dimensional materials and their applications Khan, Karim; Tareen, Ayesha Khan; Aslam, Muhammad Journal of Materials Chemistry C, Vol. 8, Issue 2 https://doi.org/10.1039/c9tc04187g	journal	January 2020
A composite film prepared from titanium carbide Ti3C2Tx (MXene) and gold nanoparticles for voltammetric determination of uric acid and folic acid Elumalai, Satheeshkumar; Mani, Veerappan; Jeromiyas, Nithiya Microchimica Acta, Vol. 187, Issue 1 https://doi.org/10.1007/s00604-019-4018-0	journal	December 2019
Reversible Crumpling of 2D Titanium Carbide (MXene) Nanocoatings for Stretchable Electromagnetic Shielding and Wearable Wireless Communication Li, Yang; Tian, Xi; Gao, Si‐Ping Advanced Functional Materials, Vol. 30, Issue 5 https://doi.org/10.1002/adfm.201907451	journal	November 2019
MZI‐Based All‐Optical Modulator Using MXene Ti ₃ C ₂ T _x (T = F, O, or OH) Deposited Microfiber Wu, Qing; Chen, Si; Wang, Yunzheng Advanced Materials Technologies, Vol. 4, Issue 4 https://doi.org/10.1002/admt.201800532	journal	January 2019
Oxidation-resistant titanium carbide MXene films Lee, Yonghee; Kim, Seon Joon; Kim, Yong-Jae Journal of Materials Chemistry A, Vol. 8, Issue 2 https://doi.org/10.1039/c9ta07036b	journal	January 2020
Electronic and Optical Properties of 2D Transition Metal Carbides and Nitrides (MXenes) Hantanasirisakul, Kanit; Gogotsi, Yury Advanced Materials, Vol. 30, Issue 52 https://doi.org/10.1002/adma.201804779	journal	November 2018
Recent Advances in 2D Inorganic Nanomaterials for SERS Sensing Karthick Kannan, Padmanathan; Shankar, Prabakaran; Blackman, Chris Advanced Materials, Vol. 31, Issue 34 https://doi.org/10.1002/adma.201803432	journal	February 2019
Enhanced Thermal Conductivity of Epoxy Composites Filled with 2D Transition Metal Carbides (MXenes) with Ultralow Loading Kang, Ruiyang; Zhang, Zhenyu; Guo, Liangchao Scientific Reports, Vol. 9, Issue 1 https://doi.org/10.1038/s41598-019-45664-4	journal	June 2019
Hierarchical Cobalt Borate/MXenes Hybrid with Extraordinary Electrocatalytic Performance in Oxygen Evolution Reaction Liu, Jiapeng; Chen, Tao; Juan, Peng ChemSusChem, Vol. 11, Issue 21 https://doi.org/10.1002/cssc.201802098	journal	October 2018
Synthesis of two-dimensional Ti ₃ C ₂ T _x /Au nanosheets with SERS performance Yue, Ming; Li, Fang; Lu, Nianhang Applied Optics, Vol. 58, Issue 30 https://doi.org/10.1364/ao.58.008290	journal	January 2019
Biomimetic MXene Textures with Enhanced Light‐to‐Heat Conversion for Solar Steam Generation and Wearable Thermal Management Li, Kerui; Chang, Ting‐Hsiang; Li, Zhipeng Advanced Energy Materials, Vol. 9, Issue 34 https://doi.org/10.1002/aenm.201901687	journal	July 2019
Preparation of Self-Assembled Composite Films Constructed by Chemically-Modified MXene and Dyes with Surface-Enhanced Raman Scattering Characterization Chen, Kaiyue; Yan, Xiaoya; Li, Junkai Nanomaterials, Vol. 9, Issue 2 https://doi.org/10.3390/nano9020284	journal	February 2019
Novel Scale-Like Structures of Graphite/TiC/Ti ₃ C ₂ Hybrids for Electromagnetic Absorption Li, Mian; Han, Meikang; Zhou, Jie Advanced Electronic Materials, Vol. 4, Issue 5 https://doi.org/10.1002/aelm.201700617	journal	April 2018
Applications of Conventional Vibrational Spectroscopic Methods for Batteries Beyond Li-Ion Deng, Yuanfu; Dong, Shengyang; Li, Zhifei Small Methods, Vol. 2, Issue 8 https://doi.org/10.1002/smtd.201700332	journal	March 2018
Two-dimensional transition metal carbides and nitrides (MXenes) for biomedical applications Huang, Kai; Li, Zhongjun; Lin, Jing Chemical Society Reviews, Vol. 47, Issue 14 https://doi.org/10.1039/c7cs00838d	journal	January 2018
Highly sensitive fluorescent sensing for intracellular glutathione based on Ti3C2 quantum dots Xu, Xiumei; Zhang, Haijiao; Diao, Quan Journal of Materials Science: Materials in Electronics, Vol. 31, Issue 1 https://doi.org/10.1007/s10854-019-02682-2	journal	December 2019
Electromagnetic simulation of MXene-based plasmonic metamaterials with enhanced optical absorption Jakšić, Zoran; Obradov, Marko; Tanasković, Dragan Optical and Quantum Electronics, Vol. 52, Issue 2 https://doi.org/10.1007/s11082-020-2227-8	journal	January 2020
Preparation and characterization of Ti3C2Tx with SERS properties Xie, XiaoJing; Zhu, YuMei; Li, Fang Science China Technological Sciences, Vol. 62, Issue 7 https://doi.org/10.1007/s11431-018-9359-4	journal	January 2019
Promoting Role of MXene Nanosheets in Biomedical Sciences: Therapeutic and Biosensing Innovations Soleymaniha, Mohammadreza; Shahbazi, Mohammad-Ali; Rafieerad, Ali Reza Advanced Healthcare Materials, Vol. 8, Issue 1 https://doi.org/10.1002/adhm.201801137	journal	October 2018
Saturable Absorption in 2D Ti ₃ C ₂ MXene Thin Films for Passive Photonic Diodes Dong, Yongchang; Chertopalov, Sergii; Maleski, Kathleen Advanced Materials, Vol. 30, Issue 10 https://doi.org/10.1002/adma.201705714	journal	January 2018
Titanium-carbide MXenes for work function and interface engineering in perovskite solar cells Agresti, A.; Pazniak, A.; Pescetelli, S. Nature Materials, Vol. 18, Issue 11 https://doi.org/10.1038/s41563-019-0478-1	journal	September 2019
2D Titanium Carbide/Reduced Graphene Oxide Heterostructures for Supercapacitor Applications Navarro-Suárez, Adriana M.; Maleski, Kathleen; Makaryan, Taron Batteries & Supercaps, Vol. 1, Issue 1 https://doi.org/10.1002/batt.201800014	journal	April 2018

Similar Records

Trace Chemical Detection Using Intercalated MXenes as a Signal Enhancing Substrate in Optical Probes

Conference · Wed Jul 01 00:00:00 EDT 2020 · OSTI ID:1399222

Allen-Perry, Kemryn; Autrey, Daniel; Lascola, Robert

Guidelines for Synthesis and Processing of Two-Dimensional [2D] Titanium Carbide (Ti₃C₂T_x MXene)

Journal Article · Fri Aug 25 00:00:00 EDT 2017 · Chemistry of Materials · OSTI ID:1399222

Alhabeb, Mohamed; Maleski, Kathleen; Anasori, Babak; +4 more

Raman Spectroscopy Analysis of the Structure and Surface Chemistry of Ti3C2Tx MXene

Journal Article · Tue Apr 07 00:00:00 EDT 2020 · Chemistry of Materials · OSTI ID:1399222

Sarycheva, Asia; Gogotsi, Yury

Related Subjects

36 MATERIALS SCIENCE
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Title: Two-Dimensional Titanium Carbide (MXene) as Surface-Enhanced Raman Scattering Substrate

Citation Formats

References (28)

Cited By (22)

Similar Records

Related Subjects