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Title: An intrinsic dual-emitting gold thiolate coordination polymer, [Au(+I)(p-SPhCO 2 H)] n , for ratiometric temperature sensing

Journal Article · · Journal of Materials Chemistry. C
DOI:https://doi.org/10.1039/C7TC03605A· OSTI ID:1399124
 [1];  [1];  [2];  [3];  [3];  [3]; ORCiD logo [4];  [5];  [5];  [5]; ORCiD logo [6]; ORCiD logo [1]
  1. Univ Lyon; Université Claude Bernard Lyon 1; Institut de Recherches sur la Catalyse et l'Environnement de Lyon (IRCELYON); Villeurbanne; France
  2. Université de Versailles Saint-Quentin-en Yvelines; Université Paris-Saclay; Institut Lavoisier de Versailles (ILV); Versailles; France
  3. Univ Lyon; Université Claude Bernard Lyon 1; Institut Lumière Matière (ILM); Villeurbanne; France
  4. Departamento de Química; Universidad de La Rioja; Centro de Investigación en Síntesis Química (CISQ); Complejo Científico-Tecnológico; Logroño
  5. Dalhousie University; Department of Chemistry; Halifax; Canada
  6. Univ Lyon; Université Claude Bernard Lyon 1; Laboratoire des Multimatériaux et Interfaces (LMI); Villeurbanne; France

Lamellar gold(i)-carboxythiophenolate exhibits intrinsic dual emission and a high sensitivity as a ratiometric thermometer.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States). Advanced Photon Source (APS)
Sponsoring Organization:
DOE - BASIC ENERGY SCIENCESFOREIGN
OSTI ID:
1399124
Journal Information:
Journal of Materials Chemistry. C, Vol. 5, Issue 38; ISSN 2050-7526
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
ENGLISH

References (31)

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Different emissive properties in dithiolate gold(i) complexes as a function of the presence of phenylene spacers journal January 2014
Dual-Emitting Nanoscale Temperature Sensors journal March 2013
Dynamic single-crystal diffraction studies using synchrotron radiation journal October 2014
Light-Emitting Self-Assembled Materials Based on d 8 and d 10 Transition Metal Complexes journal July 2015
Supramolecular assembly of molecular gold(I) compounds: An evaluation of the competition and complementarity between aurophilic (Au⋯Au) and conventional hydrogen bonding interactions journal September 2014
A Luminescent Metal-Organic Framework Thermometer with Intrinsic Dual Emission from Organic Lumophores journal February 2016
Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities journal September 2016
Aurophilic interactions as a subject of current research: an up-date journal January 2012
A Highly Soluble Luminescent Decanuclear Gold(I) Complex with a Propeller-Shaped Structure journal May 2000
Excited-state structure by time-resolved X-ray diffraction journal February 2002
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Organic Triplet Excited States of Gold(I) Complexes with Oligo( o - or m -phenyleneethynylene) Ligands: Conjunction of Steady-State and Time-Resolved Spectroscopic Studies on Exciton Delocalization and Emission Pathways journal September 2011
Restricted Photochemistry in the Molecular Solid State: Structural Changes on Photoexcitation of Cu(I) Phenanthroline Metal-to-Ligand Charge Transfer (MLCT) Complexes by Time-Resolved Diffraction journal March 2012
Instantaneous measurement of two-dimensional temperature distributions by means of two-color planar laser induced fluorescence (PLIF) journal December 2004
Luminescent probes and sensors for temperature journal January 2013
A comprehensive classification and nomenclature of carboxyl–carboxyl(ate) supramolecular motifs and related catemers: implications for biomolecular systems journal March 2015
Controllable synthesis of Zn/Cd( ii ) coordination polymers: dual-emissive luminescent properties, and tailoring emission tendency under varying excitation energies journal January 2016
Tuning the Extended Structure and Electronic Properties of Gold(I) Thienyl Pyrazolates journal June 2014
Chameleon Luminophore for Sensing Temperatures: Control of Metal-to-Metal and Energy Back Transfer in Lanthanide Coordination Polymers journal May 2013
A luminescent double helical gold( i )–thiophenolate coordination polymer obtained by hydrothermal synthesis or by thermal solid-state amorphous-to-crystalline isomerization journal January 2015
Luminescence Studies of Gold(I) Thiolate Complexes journal December 1995
Metal–organic frameworks for luminescence thermometry journal January 2015
Dual-Emission Luminescence of Magnesium Coordination Polymers Based on Mixed Organic Ligands journal December 2015
A dye encapsulated terbium-based metal–organic framework for ratiometric temperature sensing journal January 2016
Shedding light on an ultra-bright photoluminescent lamellar gold thiolate coordination polymer [Au(p-SPhCO 2 Me)] n journal January 2016
Structure of a Thiol Monolayer-Protected Gold Nanoparticle at 1.1 A Resolution journal October 2007
Crystal Structure of the Antiarthritic Drug Gold Thiomalate (Myochrysine):  A Double-Helical Geometry in the Solid State journal September 1998
Visible-Light Excited Luminescent Thermometer Based on Single Lanthanide Organic Frameworks journal October 2016
A Reversible Polymorphic Phase Change Which Affects the Luminescence and Aurophilic Interactions in the Gold(I) Cluster Complex, [μ 3 -S(AuCNC 7 H 13 ) 3 ](SbF 6 ) journal August 2005

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