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Title: Sequential infiltration synthesis for advanced lithography

Patent ·
OSTI ID:1398972

A plasma etch resist material modified by an inorganic protective component via sequential infiltration synthesis (SIS) and methods of preparing the modified resist material. The modified resist material is characterized by an improved resistance to a plasma etching or related process relative to the unmodified resist material, thereby allowing formation of patterned features into a substrate material, which may be high-aspect ratio features. The SIS process forms the protective component within the bulk resist material through a plurality of alternating exposures to gas phase precursors which infiltrate the resist material. The plasma etch resist material may be initially patterned using photolithography, electron-beam lithography or a block copolymer self-assembly process.

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE
DOE Contract Number:
AC02-06CH11357
Assignee:
UCHICAGO ARGONNE, LLC
Patent Number(s):
9,786,511
Application Number:
14/645,162
OSTI ID:
1398972
Resource Relation:
Patent File Date: 2015 Mar 11
Country of Publication:
United States
Language:
English

References (33)

Photolithography process with gas-phase pretreatment patent December 2000
Method of forming high aspect ratio apertures patent January 2007
Complementary replacement of material patent July 2008
Method for making a chemical contrast pattern using block copolymers and sequential infiltration synthesis patent December 2014
Methods of laser processing photoresist in a gaseous environment patent March 2015
Method for line density multiplication using block copolymers and sequential infiltration synthesis patent August 2016
Ordered nanoscale domains by infiltration of block copolymers patent November 2016
Plasma processing method patent-application May 2005
Method for manufacturing porous structure and method for forming pattern patent-application October 2006
TRILAYER RESIST SCHEME FOR GATE ETCHING APPLICATIONS patent-application April 2009
Method of Controlling Orientation of Domains in Block Copolymer Films patent-application July 2009
Methods Of Utilizing Block Copolymer To Form Patterns patent-application April 2010
METHOD OF MANUFACTURING SEMICONDUCTOR DEVICE patent-application September 2010
Method for Forming a Block Copolymer Pattern patent-application August 2011
Ordered Nanoscale Domains by Infiltration of Block Copolymers patent-application February 2012
SEQUENTIAL INFILTRATION SYNTHESIS FOR ADVANCED LITHOGRAPHY patent-application September 2012
SELECTIVE ATOMIC LAYER DEPOSITION OF PASSIVATION LAYERS FOR SILICON-BASED PHOTOVOLTAIC DEVICES patent-application June 2013
An experimentally validated analytical model for gate line-edge roughness (LER) effects on technology scaling journal June 2001
High sensitive negative silylation process for 193nm lithography journal June 2000
Optimized surface silylation of chemically amplified epoxidized photoresists for micromachining applications journal April 2010
Mobility analysis of surface roughness scattering in FinFET devices journal August 2011
Hierarchical self-assembly of metal nanostructures on diblock copolymer scaffolds journal December 2001
Optical Characterization and Process Control of Top Surface Imaging journal January 1999
Reduction of line edge roughness in the top surface imaging process
  • Mori, Shigeyasu; Morisawa, Taku; Matsuzawa, Nobuyuki
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 16, Issue 6, Article No. 3739 https://doi.org/10.1116/1.590409
journal November 1998
A Route to Nanoscopic Materials via Sequential Infiltration Synthesis on Block Copolymer Templates journal May 2011
Nanoscopic Patterned Materials with Tunable Dimensions via Atomic Layer Deposition on Block Copolymers journal September 2010
Hollow Inorganic Nanospheres and Nanotubes with Tunable Wall Thicknesses by Atomic Layer Deposition on Self-Assembled Polymeric Templates journal January 2007
Approaches to deep ultraviolet photolithography utilizing acid hardened resin photoresist systems
  • Thackeray, James W.; Orsula, George W.; Bohland, John F.
  • Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 7, Issue 6, Article No. 1620 https://doi.org/10.1116/1.584502
journal November 1989
Enhanced Block Copolymer Lithography Using Sequential Infiltration Synthesis journal July 2011
Enhanced Lithographic Imaging Layer Meets Semiconductor Manufacturing Specification a Decade Early journal April 2012
Etch properties of resists modified by sequential infiltration synthesis
  • Tseng, Yu-Chih; Peng, Qing; Ocola, Leonidas E.
  • Journal of Vacuum Science & Technology B, Nanotechnology and Microelectronics: Materials, Processing, Measurement, and Phenomena, Vol. 29, Issue 6, Article No. 06FG01 https://doi.org/10.1116/1.3640758
journal November 2011
Nanoscopic Morphologies in Block Copolymer Nanorods as Templates for Atomic-Layer Deposition of Semiconductors journal April 2009
Statistical Modeling and Simulation of Threshold Variation Under Random Dopant Fluctuations and Line-Edge Roughness journal June 2011