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Title: Porous Organic Polymers for Post-Combustion Carbon Capture

Journal Article · · Advanced Materials

One of the most pressing environmental concerns of our age is the escalating level of atmospheric CO2. Intensive efforts have been made to investigate advanced porous materials, especially porous organic polymers (POPs), as one type of the most promising candidates for carbon capture due to their extremely high porosity, structural diversity, and physicochemical stability. This review provides a critical and in-depth analysis of recent POP research as it pertains to carbon capture. The definitions and terminologies commonly used to evaluate the performance of POPs for carbon capture, including CO2 capacity, enthalpy, selectivity, and regeneration strategies, are summarized. A detailed correlation study between the structural and chemical features of POPs and their adsorption capacities is discussed, mainly focusing on the physical interactions and chemical reactions. Lastly, a concise outlook for utilizing POPs for carbon capture is discussed, noting areas in which further work is needed to develop the next-generation POPs for practical applications

Research Organization:
Texas A & M Univ., College Station, TX (United States)
Sponsoring Organization:
USDOE Office of Fossil Energy (FE); USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
FE0026472; SC0001015; A-0030
OSTI ID:
1525348
Alternate ID(s):
OSTI ID: 1398119
Journal Information:
Advanced Materials, Vol. 29, Issue 37; ISSN 0935-9648
Publisher:
WileyCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 268 works
Citation information provided by
Web of Science

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A theoretical analysis of the energy consumption of post-combustion CO2 capture processes by temperature swing adsorption using solid sorbents journal May 2013
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Synthesis and Characterization of Porous Benzimidazole-Linked Polymers and Their Performance in Small Gas Storage and Selective Uptake journal April 2012
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[3+3] Imine and β-ketoenamine tethered fluorescent covalent-organic frameworks for CO 2 uptake and nitroaromatic sensing journal January 2015
Enhanced Hydrolytic Stability of Self-Assembling Alkylated Two-Dimensional Covalent Organic Frameworks journal September 2011
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Fluorinated microporous organic polymers: design and applications in CO 2 adsorption and conversion journal January 2014
Adsorption of Gases in Multimolecular Layers journal February 1938
Pyrene-directed growth of nanoporous benzimidazole-linked nanofibers and their application to selective CO2 capture and separation journal January 2012
Review of solutions to global warming, air pollution, and energy security journal January 2009
The energy penalty of post-combustion CO2 capture & storage and its implications for retrofitting the U.S. installed base journal January 2009
A triazine-based covalent organic polymer for efficient CO 2 adsorption journal January 2015
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Targeted Synthesis of a Porous Aromatic Framework with High Stability and Exceptionally High Surface Area journal November 2009
A Belt-Shaped, Blue Luminescent, and Semiconducting Covalent Organic Framework journal April 2009
3D Microporous Base-Functionalized Covalent Organic Frameworks for Size-Selective Catalysis journal February 2014
Polyamine-Tethered Porous Polymer Networks for Carbon Dioxide Capture from Flue Gas journal June 2012
A Belt-Shaped, Blue Luminescent, and Semiconducting Covalent Organic Framework journal November 2008
Conjugated Microporous Poly(aryleneethynylene) Networks journal February 2008
Towards Polymer-Based Hydrogen Storage Materials: Engineering Ultramicroporous Cavities within Polymers of Intrinsic Microporosity journal March 2006
Radical Covalent Organic Frameworks: A General Strategy to Immobilize Open-Accessible Polyradicals for High-Performance Capacitive Energy Storage journal April 2015
Charge Dynamics in A Donor-Acceptor Covalent Organic Framework with Periodically Ordered Bicontinuous Heterojunctions journal January 2013
Two-Dimensional Covalent Organic Frameworks for Carbon Dioxide Capture through Channel-Wall Functionalization journal January 2015
The oxycoal process with cryogenic oxygen supply text January 2009
Conjugated Microporous Poly(aryleneethynylene) Networks journal February 2008
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Ionic‐Liquid‐Modified Click‐Based Porous Organic Polymers for Controlling Capture and Catalytic Conversion of CO 2 journal December 2019
Stability of amine-functionalized CO 2 adsorbents: a multifaceted puzzle journal January 2019
Interfacial assembled preparation of porous carbon composites for selective CO 2 capture at elevated temperatures journal January 2019
Peptide nanotube for carbon dioxide chemisorption with regeneration properties and water compatibility journal January 2019
Porous Organic Polymers for Polysulfide Trapping in Lithium-Sulfur Batteries journal April 2018
A Porous Organic Poly(triphenylimidazole) Decorated with Palladium Nanoparticles for the Cyanation of Aryl Iodides journal August 2018
Tunable Surface Area, Porosity, and Function in Conjugated Microporous Polymers journal July 2019
Epoxy-Functionalized Porous Organic Polymers via the Diels-Alder Cycloaddition Reaction for Atmospheric Water Capture journal February 2018
Effect of Building Block Transformation in Covalent Triazine‐Based Frameworks for Enhanced CO 2 Uptake and Metal‐Free Heterogeneous Catalysis journal December 2019
Enhanced carbon dioxide capture in an indole-based microporous organic polymer via synergistic effects of indoles and their adjacent carbonyl groups journal January 2018
Porous Cationic Covalent Triazine‐Based Frameworks as Platforms for Efficient CO 2 and Iodine Capture journal August 2019
Effect of Building Block Transformation in Covalent Triazine‐Based Frameworks for Enhanced CO 2 Uptake and Metal‐Free Heterogeneous Catalysis journal December 2019
Hexamethylcucurbit[3,3]uril-Based Porous Supramolecular Assemblies and Their Adsorption Properties journal August 2018
Pristine and Carboxyl-Functionalized Tetraphenylethylene-Based Ladder Networks for Gas Separation and Volatile Organic Vapor Adsorption journal November 2018
Mechanochemical synthesis of pillar[5]quinone derived multi-microporous organic polymers for radioactive organic iodide capture and storage. journalarticle January 2020
Selective Adsorption-Based Separation of Flue Gas and Natural Gas in Zirconium Metal-Organic Frameworks Nanocrystals journal May 2019

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