Iron K-edge X-ray absorption near-edge structure spectroscopy of aerodynamically levitated silicate melts and glasses

Alderman, O. L. G.; Wilding, M. C.; Tamalonis, A.; Sendelbach, S.; Heald, S. M.; Benmore, C. J.; Johnson, C. E.; Johnson, J. A.; Hah, H. -Y.; Weber, J. K. R.

doi:10.1016/j.chemgeo.2017.01.020

Title: Iron K-edge X-ray absorption near-edge structure spectroscopy of aerodynamically levitated silicate melts and glasses

Journal Article · Thu Jan 26 00:00:00 EST 2017 · Chemical Geology

DOI:https://doi.org/10.1016/j.chemgeo.2017.01.020· OSTI ID:1372470

Alderman, O. L. G. ^[1]; Wilding, M. C. ^[2]; Tamalonis, A. ^[3]; Sendelbach, S. ^[3]; Heald, S. M. ^[4]; Benmore, C. J. ^[4]; Johnson, C. E. ^[5]; Johnson, J. A. ^[5]; Hah, H. -Y. ^[5]; Weber, J. K. R. ^[1]

Materials Development, Inc., Arlington Heights, IL (United States); Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. College London, London (United Kingdom)
Materials Development, Inc., Arlington Heights, IL (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Univ. of Tennessee Space Institute, Tullahoma, TN (United States)

Here, the local structure about Fe(II) and Fe(III) in silicate melts was investigated in-situ using iron K-edge X-ray absorption near-edge structure (XANES) spectroscopy. An aerodynamic levitation and laser heating system was used to allow access to high temperatures without contamination, and was combined with a chamber and gas mixing system to allow the iron oxidation state, Fe³⁺/ΣFe, to be varied by systematic control of the atmospheric oxygen fugacity. Eleven alkali-free, mostly iron-rich and depolymerized base compositions were chosen for the experiments, including pure oxide FeO, olivines (Fe,Mg)₂SiO₄, pyroxenes (Fe,Mg)SiO₃, calcic FeO-CaSiO₃, and a calcium aluminosilicate composition, where total iron content is denoted by FeO for convenience. Melt temperatures varied between 1410 and 2160 K and oxygen fugacities between FMQ – 2.3(3) to FMQ + 9.1(3) log units (uncertainties in parentheses) relative to the fayalite-magnetite-β-quartz (FMQ) buffer.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: University of Tennessee, Space Institute (UTSI); USDOE Office of Science (SC), Small Business Innovation Research (SBIR) and Small Business Technology Transfer (STTR), Small Business Innovative Research Grant Program; USDOE

Grant/Contract Number:: AC02-06CH11357; SBIR DE-SC0007564

OSTI ID:: 1372470

Alternate ID(s):: OSTI ID: 1398053

Journal Information:: Chemical Geology, Vol. 453, Issue C; ISSN 0009-2541

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 32 works

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Activity coefficients for FeS and NiS in monosulfide liquid and NiSi sub 1/2 O sub 2 in olivine from sulfide-silicate equilibria

Journal Article · Sat Apr 01 00:00:00 EST 1989 · Geochimica et Cosmochimica Acta; (USA) · OSTI ID:1372470

Fleet, M E

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58 GEOSCIENCES
36 MATERIALS SCIENCE
silicate
melt
glass
iron
XANES
redox

Title: Iron K-edge X-ray absorption near-edge structure spectroscopy of aerodynamically levitated silicate melts and glasses

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