Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]
Abstract
In situ high energy X-ray diffraction (HEXRD) and in situ X-ray absorption near edge spectroscopy (XANES) were carried out to understand the soild state synthesis of NaxMnO2, with particular interest on the synthesis of P2 type Na2/3MnO2. It was found that there were multi intermediate phases formed before NaMnO2 appeared at about 600 °C. And the final product after cooling process is a combination of O'3 NaMnO2 with P2 Na2/3MnO2. A P2 type Na2/3MnO2 was synthesized at reduced temperature (600 °C). The influence of Na2CO3 impurity on the electrochemical performance of P2 Na2/3MnO2 was thoroughly investigated in our work. It was found that the content of Na2CO3 can be reduced by optimizing Na2CO3/MnCO3 ratio during the solid state reaction or other post treatment such as washing with water. Lastly, we expected our results could provide a good guide for future development of high performance cathode materials for sodium-ion batteries.
- Authors:
-
- Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Rochester, Rochester, NY (United States)
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Univ. of Rochester, Rochester, NY (United States)
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
- OSTI Identifier:
- 1369033
- Alternate Identifier(s):
- OSTI ID: 1397470
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Journal of Power Sources
- Additional Journal Information:
- Journal Volume: 341; Journal Issue: C; Journal ID: ISSN 0378-7753
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE; in situ XANES; P2 type Na2/3MnO2; in situ HEXRD; ion battery; sodium deficiency; solid-state synthesis
Citation Formats
Ma, Tianyuan, Xu, Gui -Liang, Zeng, Xiaoqiao, Li, Yan, Ren, Yang, Sun, Chengjun, Heald, Steve M., Jorne, Jacob, Amine, Khalil, and Chen, Zonghai. Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]. United States: N. p., 2016.
Web. doi:10.1016/j.jpowsour.2016.11.022.
Ma, Tianyuan, Xu, Gui -Liang, Zeng, Xiaoqiao, Li, Yan, Ren, Yang, Sun, Chengjun, Heald, Steve M., Jorne, Jacob, Amine, Khalil, & Chen, Zonghai. Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]. United States. https://doi.org/10.1016/j.jpowsour.2016.11.022
Ma, Tianyuan, Xu, Gui -Liang, Zeng, Xiaoqiao, Li, Yan, Ren, Yang, Sun, Chengjun, Heald, Steve M., Jorne, Jacob, Amine, Khalil, and Chen, Zonghai. 2016.
"Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]". United States. https://doi.org/10.1016/j.jpowsour.2016.11.022. https://www.osti.gov/servlets/purl/1369033.
@article{osti_1369033,
title = {Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]},
author = {Ma, Tianyuan and Xu, Gui -Liang and Zeng, Xiaoqiao and Li, Yan and Ren, Yang and Sun, Chengjun and Heald, Steve M. and Jorne, Jacob and Amine, Khalil and Chen, Zonghai},
abstractNote = {In situ high energy X-ray diffraction (HEXRD) and in situ X-ray absorption near edge spectroscopy (XANES) were carried out to understand the soild state synthesis of NaxMnO2, with particular interest on the synthesis of P2 type Na2/3MnO2. It was found that there were multi intermediate phases formed before NaMnO2 appeared at about 600 °C. And the final product after cooling process is a combination of O'3 NaMnO2 with P2 Na2/3MnO2. A P2 type Na2/3MnO2 was synthesized at reduced temperature (600 °C). The influence of Na2CO3 impurity on the electrochemical performance of P2 Na2/3MnO2 was thoroughly investigated in our work. It was found that the content of Na2CO3 can be reduced by optimizing Na2CO3/MnCO3 ratio during the solid state reaction or other post treatment such as washing with water. Lastly, we expected our results could provide a good guide for future development of high performance cathode materials for sodium-ion batteries.},
doi = {10.1016/j.jpowsour.2016.11.022},
url = {https://www.osti.gov/biblio/1369033},
journal = {Journal of Power Sources},
issn = {0378-7753},
number = C,
volume = 341,
place = {United States},
year = {Wed Dec 07 00:00:00 EST 2016},
month = {Wed Dec 07 00:00:00 EST 2016}
}
Web of Science
Works referenced in this record:
Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012
- Kim, Sung-Wook; Seo, Dong-Hwa; Ma, Xiaohua
- Advanced Energy Materials, Vol. 2, Issue 7, p. 710-721
Sodium-Ion Batteries
journal, May 2012
- Slater, Michael D.; Kim, Donghan; Lee, Eungje
- Advanced Functional Materials, Vol. 23, Issue 8, p. 947-958
Structural classification and properties of the layered oxides
journal, January 1980
- Delmas, C.; Fouassier, C.; Hagenmuller, P.
- Physica B+C, Vol. 99, Issue 1-4
An advanced cathode for Na-ion batteries with high rate and excellent structural stability
journal, January 2013
- Lee, Dae Hoe; Xu, Jing; Meng, Ying Shirley
- Physical Chemistry Chemical Physics, Vol. 15, Issue 9
Synthesis and electrochemical behaviors of layered Na0.67[Mn0.65Co0.2Ni0.15]O2 microflakes as a stable cathode material for sodium-ion batteries
journal, January 2013
- Yuan, Dingding; He, Wei; Pei, Feng
- Journal of Materials Chemistry A, Vol. 1, Issue 12
Layered Na[Ni1/3Fe1/3Mn1/3]O2 cathodes for Na-ion battery application
journal, January 2012
- Kim, Donghan; Lee, Eungje; Slater, Michael
- Electrochemistry Communications, Vol. 18
Na 0.67 Mn 1−x Mg x O 2 (0 ≤ x ≤ 0.2): a high capacity cathode for sodium-ion batteries
journal, January 2014
- Billaud, Juliette; Singh, Gurpreet; Armstrong, A. Robert
- Energy Environ. Sci., Vol. 7, Issue 4
P2-type Na 0.66 Ni 0.33–x Zn x Mn 0.67 O 2 as new high-voltage cathode materials for sodium-ion batteries
journal, May 2015
- Wu, Xuehang; Guo, Jianghuai; Wang, Dawei
- Journal of Power Sources, Vol. 281
High-Performance P2-Type Na 2/3 (Mn 1/2 Fe 1/4 Co 1/4 )O 2 Cathode Material with Superior Rate Capability for Na-Ion Batteries
journal, September 2015
- Liu, Lei; Li, Xin; Bo, Shou-Hang
- Advanced Energy Materials, Vol. 5, Issue 22
Sur quelques nouvelles phases de formule NaxMnO2 (x ⩽ 1)
journal, February 1971
- Parant, Jean-Paul; Olazcuaga, Roger; Devalette, Michel
- Journal of Solid State Chemistry, Vol. 3, Issue 1
Sodium and Manganese Stoichiometry of P2-Type Na 2/3 MnO 2
journal, September 2016
- Kumakura, Shinichi; Tahara, Yoshiyuki; Kubota, Kei
- Angewandte Chemie International Edition, Vol. 55, Issue 41
Solid state synthesis of LiFePO4 studied by in situ high energy X-ray diffraction
journal, January 2011
- Chen, Zonghai; Ren, Yang; Qin, Yan
- Journal of Materials Chemistry, Vol. 21, Issue 15
Formation of Li2MnO3 investigated by in situ synchrotron probes
journal, November 2014
- Kan, Yongchun; Hu, Yuan; Croy, Jason
- Journal of Power Sources, Vol. 266
ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005
- Ravel, B.; Newville, M.
- Journal of Synchrotron Radiation, Vol. 12, Issue 4
Synthesis of full concentration gradient cathode studied by high energy X-ray diffraction
journal, January 2016
- Li, Yan; Xu, Rui; Ren, Yang
- Nano Energy, Vol. 19
Structure and reversible lithium intercalation in a new P′3-phase: Na2/3Mn1−yFeyO2 (y = 0, 1/3, 2/3)
journal, January 2012
- Yoncheva, M.; Stoyanova, R.; Zhecheva, E.
- Journal of Materials Chemistry, Vol. 22, Issue 44
β-NaMnO 2 : A High-Performance Cathode for Sodium-Ion Batteries
journal, November 2014
- Billaud, Juliette; Clément, Raphaële J.; Armstrong, A. Robert
- Journal of the American Chemical Society, Vol. 136, Issue 49
Local Atomic Arrangement and Electronic Structure of Nanocrystalline Transition Metal Oxides Determined by X-ray Absorption Spectroscopy
journal, June 2003
- Hwang, Seong-Ju; Choy, Jin-Ho
- The Journal of Physical Chemistry B, Vol. 107, Issue 24
In Situ Mn K-edge X-ray Absorption Spectroscopy Studies of Electrodeposited Manganese Oxide Films for Electrochemical Capacitors
journal, January 2007
- Nam, Kyung-Wan; Kim, Min Gyu; Kim, Kwang-Bum
- The Journal of Physical Chemistry C, Vol. 111, Issue 2
Review—Manganese-Based P2-Type Transition Metal Oxides as Sodium-Ion Battery Cathode Materials
journal, January 2015
- Clément, Raphaële J.; Bruce, Peter G.; Grey, Clare P.
- Journal of The Electrochemical Society, Vol. 162, Issue 14
A Comparative Study of Layered Transition Metal Oxide Cathodes for Application in Sodium-Ion Battery
journal, February 2015
- Hasa, Ivana; Buchholz, Daniel; Passerini, Stefano
- ACS Applied Materials & Interfaces, Vol. 7, Issue 9
Water sensitivity of layered P2/P3-Na x Ni 0.22 Co 0.11 Mn 0.66 O 2 cathode material
journal, January 2014
- Buchholz, Daniel; Chagas, Luciana Gomes; Vaalma, Christoph
- J. Mater. Chem. A, Vol. 2, Issue 33
Thermal and carbothermic decomposition of Na2CO3 and Li2CO3
journal, February 2001
- Kim, Jong-Wan; Lee, Hae-Geon
- Metallurgical and Materials Transactions B, Vol. 32, Issue 1
Electrochemical investigation of the P2–NaxCoO2 phase diagram
journal, December 2010
- Berthelot, R.; Carlier, D.; Delmas, C.
- Nature Materials, Vol. 10, Issue 1
Works referencing / citing this record:
Challenges in Developing Electrodes, Electrolytes, and Diagnostics Tools to Understand and Advance Sodium-Ion Batteries
journal, February 2018
- Xu, Gui-Liang; Amine, Rachid; Abouimrane, Ali
- Advanced Energy Materials, Vol. 8, Issue 14
Excellent cyclability of P2-type Na–Co–Mn–Si–O cathode material for high-rate sodium-ion batteries
journal, July 2019
- Wang, Lijun; Wang, Yanzhi; Yang, Xiaheng
- Journal of Materials Science, Vol. 54, Issue 19
A Novel Graphene Oxide Wrapped Na 2 Fe 2 (SO 4 ) 3 /C Cathode Composite for Long Life and High Energy Density Sodium-Ion Batteries
journal, August 2018
- Chen, Mingzhe; Cortie, David; Hu, Zhe
- Advanced Energy Materials, Vol. 8, Issue 27
Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: status, challenges and countermeasures
journal, January 2019
- Wang, Shenghan; Sun, Chenglin; Wang, Ning
- Journal of Materials Chemistry A, Vol. 7, Issue 17