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Title: Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]

Abstract

In situ high energy X-ray diffraction (HEXRD) and in situ X-ray absorption near edge spectroscopy (XANES) were carried out to understand the soild state synthesis of NaxMnO2, with particular interest on the synthesis of P2 type Na2/3MnO2. It was found that there were multi intermediate phases formed before NaMnO2 appeared at about 600 °C. And the final product after cooling process is a combination of O'3 NaMnO2 with P2 Na2/3MnO2. A P2 type Na2/3MnO2 was synthesized at reduced temperature (600 °C). The influence of Na2CO3 impurity on the electrochemical performance of P2 Na2/3MnO2 was thoroughly investigated in our work. It was found that the content of Na2CO3 can be reduced by optimizing Na2CO3/MnCO3 ratio during the solid state reaction or other post treatment such as washing with water. Lastly, we expected our results could provide a good guide for future development of high performance cathode materials for sodium-ion batteries.

Authors:
 [1];  [2];  [2];  [2];  [2];  [2];  [2];  [3];  [2];  [2]
  1. Argonne National Lab. (ANL), Argonne, IL (United States); Univ. of Rochester, Rochester, NY (United States)
  2. Argonne National Lab. (ANL), Argonne, IL (United States)
  3. Univ. of Rochester, Rochester, NY (United States)
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V); USDOE
OSTI Identifier:
1369033
Alternate Identifier(s):
OSTI ID: 1397470
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Power Sources
Additional Journal Information:
Journal Volume: 341; Journal Issue: C; Journal ID: ISSN 0378-7753
Publisher:
Elsevier
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 25 ENERGY STORAGE; in situ XANES; P2 type Na2/3MnO2; in situ HEXRD; ion battery; sodium deficiency; solid-state synthesis

Citation Formats

Ma, Tianyuan, Xu, Gui -Liang, Zeng, Xiaoqiao, Li, Yan, Ren, Yang, Sun, Chengjun, Heald, Steve M., Jorne, Jacob, Amine, Khalil, and Chen, Zonghai. Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]. United States: N. p., 2016. Web. doi:10.1016/j.jpowsour.2016.11.022.
Ma, Tianyuan, Xu, Gui -Liang, Zeng, Xiaoqiao, Li, Yan, Ren, Yang, Sun, Chengjun, Heald, Steve M., Jorne, Jacob, Amine, Khalil, & Chen, Zonghai. Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]. United States. https://doi.org/10.1016/j.jpowsour.2016.11.022
Ma, Tianyuan, Xu, Gui -Liang, Zeng, Xiaoqiao, Li, Yan, Ren, Yang, Sun, Chengjun, Heald, Steve M., Jorne, Jacob, Amine, Khalil, and Chen, Zonghai. 2016. "Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]". United States. https://doi.org/10.1016/j.jpowsour.2016.11.022. https://www.osti.gov/servlets/purl/1369033.
@article{osti_1369033,
title = {Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ high energy X-ray diffraction and X-ray absorption near edge spectroscopy [Solid state synthesis of layered sodium manganese oxide for sodium-ion battery by in-situ HEXRD and XANES]},
author = {Ma, Tianyuan and Xu, Gui -Liang and Zeng, Xiaoqiao and Li, Yan and Ren, Yang and Sun, Chengjun and Heald, Steve M. and Jorne, Jacob and Amine, Khalil and Chen, Zonghai},
abstractNote = {In situ high energy X-ray diffraction (HEXRD) and in situ X-ray absorption near edge spectroscopy (XANES) were carried out to understand the soild state synthesis of NaxMnO2, with particular interest on the synthesis of P2 type Na2/3MnO2. It was found that there were multi intermediate phases formed before NaMnO2 appeared at about 600 °C. And the final product after cooling process is a combination of O'3 NaMnO2 with P2 Na2/3MnO2. A P2 type Na2/3MnO2 was synthesized at reduced temperature (600 °C). The influence of Na2CO3 impurity on the electrochemical performance of P2 Na2/3MnO2 was thoroughly investigated in our work. It was found that the content of Na2CO3 can be reduced by optimizing Na2CO3/MnCO3 ratio during the solid state reaction or other post treatment such as washing with water. Lastly, we expected our results could provide a good guide for future development of high performance cathode materials for sodium-ion batteries.},
doi = {10.1016/j.jpowsour.2016.11.022},
url = {https://www.osti.gov/biblio/1369033}, journal = {Journal of Power Sources},
issn = {0378-7753},
number = C,
volume = 341,
place = {United States},
year = {Wed Dec 07 00:00:00 EST 2016},
month = {Wed Dec 07 00:00:00 EST 2016}
}

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Cited by: 21 works
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Works referenced in this record:

Electrode Materials for Rechargeable Sodium-Ion Batteries: Potential Alternatives to Current Lithium-Ion Batteries
journal, May 2012


Sodium-Ion Batteries
journal, May 2012


Structural classification and properties of the layered oxides
journal, January 1980


An advanced cathode for Na-ion batteries with high rate and excellent structural stability
journal, January 2013


Layered Na[Ni1/3Fe1/3Mn1/3]O2 cathodes for Na-ion battery application
journal, January 2012


Na 0.67 Mn 1−x Mg x O 2 (0 ≤ x ≤ 0.2): a high capacity cathode for sodium-ion batteries
journal, January 2014


Sur quelques nouvelles phases de formule NaxMnO2 (x ⩽ 1)
journal, February 1971


Sodium and Manganese Stoichiometry of P2-Type Na 2/3 MnO 2
journal, September 2016


Solid state synthesis of LiFePO4 studied by in situ high energy X-ray diffraction
journal, January 2011


Formation of Li2MnO3 investigated by in situ synchrotron probes
journal, November 2014


ATHENA , ARTEMIS , HEPHAESTUS : data analysis for X-ray absorption spectroscopy using IFEFFIT
journal, June 2005


Structure and reversible lithium intercalation in a new P′3-phase: Na2/3Mn1−yFeyO2 (y = 0, 1/3, 2/3)
journal, January 2012


β-NaMnO 2 : A High-Performance Cathode for Sodium-Ion Batteries
journal, November 2014


In Situ Mn K-edge X-ray Absorption Spectroscopy Studies of Electrodeposited Manganese Oxide Films for Electrochemical Capacitors
journal, January 2007


Review—Manganese-Based P2-Type Transition Metal Oxides as Sodium-Ion Battery Cathode Materials
journal, January 2015


A Comparative Study of Layered Transition Metal Oxide Cathodes for Application in Sodium-Ion Battery
journal, February 2015


Water sensitivity of layered P2/P3-Na x Ni 0.22 Co 0.11 Mn 0.66 O 2 cathode material
journal, January 2014


Thermal and carbothermic decomposition of Na2CO3 and Li2CO3
journal, February 2001


Electrochemical investigation of the P2–NaxCoO2 phase diagram
journal, December 2010


Works referencing / citing this record:

Challenges in Developing Electrodes, Electrolytes, and Diagnostics Tools to Understand and Advance Sodium-Ion Batteries
journal, February 2018


Excellent cyclability of P2-type Na–Co–Mn–Si–O cathode material for high-rate sodium-ion batteries
journal, July 2019


Ni- and/or Mn-based layered transition metal oxides as cathode materials for sodium ion batteries: status, challenges and countermeasures
journal, January 2019