Elucidating the interaction between Ni and CeOx in ethanol steam reforming catalysts: A perspective of recent studies over model and powder systems

Liu, Zongyuan; Senanayake, Sanjaya D.; Rodriguez, Jose A.

doi:10.1016/j.apcatb.2016.03.013

Title: Elucidating the interaction between Ni and CeO_x in ethanol steam reforming catalysts: A perspective of recent studies over model and powder systems

Journal Article · Tue Mar 08 00:00:00 EST 2016 · Applied Catalysis B: Environmental

DOI:https://doi.org/10.1016/j.apcatb.2016.03.013· OSTI ID:1377056

Liu, Zongyuan ^[1]; Senanayake, Sanjaya D. ^[2]; Rodriguez, Jose A. ^[1]

Brookhaven National Lab. (BNL), Upton, NY (United States); SUNY Stony Brook, Stony Brook, NY (United States)
Brookhaven National Lab. (BNL), Upton, NY (United States)

Bulk metallic nickel is a poor catalyst for the reforming of oxygenates being deactivated by the deposition of coke. In contrast, Ni-ceria is an active system for the catalytic extraction of H₂ from the ethanol steam reforming reaction (ESR, C₂H₅OH + 3H₂O ↔ 2CO₂ + 6H₂). Numerous studies, with model (well-defined crystal surfaces) and technical (high surface area powders) catalysts, have been devoted to understand the fundamental role of each catalyst component, the performance of adjacent sites in the metal-oxide interface, and the complex mechanistic steps that convert two oxygenated reactants (ethanol and H₂O) into H₂. The size and low loading of Ni on ceria facilitate metal-oxide support interactions that probably enhance the reactivity of the system. To establish the precise role of both Ni and Ce is challenging. However it is clear that both Ni and Ce are associated with the dissociation of H₂O (OH + H), while ceria readily adsorbs and partially dissociates ethanol (i.e. ethoxy formation). The most difficult step of Csingle bondC bond dissociation likely occurs only on Ni or at the Ni-Ce interface. H₂O and OH remain as important agents for the prevention of excess C build up during the Csingle bondH/Csingle bondC dissociation process. Often, deactivation upon C build up, is a direct result of Ni sintering and decoupling of the Ni-Ce interactions. One strategy to maintain good activity and stability is to protect the Ni-Ce interaction, and this can be achieved through the use of solid solutions (Ce_1–xNi_xO_2–y) or by employing stabilizing agents such as W (Ni_xW_yCe_zO₂). In this paper, we present and discuss the most recent work for the ESR reaction and show the important role of ceria which participates directly in the reaction and also enhances catalytic activity through metal-support interactions.

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Research Organization:: Brookhaven National Laboratory (BNL), Upton, NY (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: SC00112704; SC0012704

OSTI ID:: 1377056

Alternate ID(s):: OSTI ID: 1331071; OSTI ID: 1397032

Report Number(s):: BNL-114203-2017-JA; BNL-113171-2016-JA; R&D Project: CO040; KC0302010

Journal Information:: Applied Catalysis B: Environmental, Vol. 197, Issue C; ISSN 0926-3373

Publisher:: ElsevierCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 33 works

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Dry Reforming of Shale Gas and Carbon Dioxide with Ni-Ce-Al ₂ O ₃ Catalyst: Syngas Production Enhanced over Ni-CeO _x Formation Liu, Yan; Wu, Ye; Akhtamberdinova, Zarina ChemCatChem, Vol. 10, Issue 20 https://doi.org/10.1002/cctc.201800829	journal	September 2018

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