Structural studies of Bi 2 O 3 -Nb 2 O 5 -TeO 2 glasses
Abstract
Bi2O3-Nb2O5-TeO2 glasses show unusual annealing behavior with appearance of spherulites within the matrix glass structure for the Bi0.5Nb0.5Te3O8 composition. The textures resemble those found previously among polyamorphic Al2O3-Y2O3 glasses containing metastably co-existing high- and low-density phases produced during quenching. However the spherulites produced within the Bi2O3-Nb2O5-TeO2 glass are crystalline and can be identified as an “anti-glass” phase related to β-Bi2Te4O11. Here, we used high energy synchrotron X-ray diffraction data to study structures of binary and ternary glasses quenched from liquids within the Bi2O3-Nb2O5-TeO2 system. These reveal a glassy network based on interconnected TeO4 and TeO3 units that is related to TeO2 crystalline materials but with larger Te…Te separations due to the presence of TeO3 groups and non-bridging oxygens linked to modifier (Bi3 +, Nb5 +) cations. Analysis of the viscosity-temperature relations indicates that the glass-forming liquids are “fragile” and there is no evidence for a LLPT occurring in the supercooled liquid. The glasses obtained by quenching likely correspond to a high-density amorphous (HDA) state. Subsequent annealing above Tg shows mainly evidence for direct crystallization of the “anti-glass” tellurite phase. But, some evidence may exist for simultaneous formation of nanoscale amorphous spherulites that could correspond to the LDA polyamorph. The quenchingmore »
- Authors:
-
- Univ. College London (United Kingdom). Dept. of Chemistry; Univ. of Bath (United Kingdom). Dept. of Physics
- Univ. of Limoges (France)
- Argonne National Lab. (ANL), Argonne, IL (United States). X-ray Science Division
- Univ. of Rennes (France)
- Tohoku Univ., Sendai (Japan). Inst. of Multidisciplinary Research for Advanced Materials (IMRAM)
- Univ. College London (United Kingdom). Dept. of Chemistry
- Publication Date:
- Research Org.:
- Argonne National Lab. (ANL), Argonne, IL (United States)
- Sponsoring Org.:
- USDOE Office of Science (SC)
- OSTI Identifier:
- 1389309
- Alternate Identifier(s):
- OSTI ID: 1396667
- Grant/Contract Number:
- AC02-06CH11357
- Resource Type:
- Journal Article: Accepted Manuscript
- Journal Name:
- Journal of Non-Crystalline Solids
- Additional Journal Information:
- Journal Volume: 451; Journal Issue: C; Journal ID: ISSN 0022-3093
- Publisher:
- Elsevier
- Country of Publication:
- United States
- Language:
- English
- Subject:
- 36 MATERIALS SCIENCE; Tellurite glass; Polyamorphism; Fragility; High energy X-ray diffraction
Citation Formats
Wilding, Martin C., Delaizir, Gaelle, Benmore, Chris J., Gueguen, Yann, Dolhen, Morgane, Duclère, Jean-René, Chenu, Sébastien, Sukenaga, Sohei, and McMillan, Paul F. Structural studies of Bi 2 O 3 -Nb 2 O 5 -TeO 2 glasses. United States: N. p., 2016.
Web. doi:10.1016/j.jnoncrysol.2016.07.004.
Wilding, Martin C., Delaizir, Gaelle, Benmore, Chris J., Gueguen, Yann, Dolhen, Morgane, Duclère, Jean-René, Chenu, Sébastien, Sukenaga, Sohei, & McMillan, Paul F. Structural studies of Bi 2 O 3 -Nb 2 O 5 -TeO 2 glasses. United States. https://doi.org/10.1016/j.jnoncrysol.2016.07.004
Wilding, Martin C., Delaizir, Gaelle, Benmore, Chris J., Gueguen, Yann, Dolhen, Morgane, Duclère, Jean-René, Chenu, Sébastien, Sukenaga, Sohei, and McMillan, Paul F. 2016.
"Structural studies of Bi 2 O 3 -Nb 2 O 5 -TeO 2 glasses". United States. https://doi.org/10.1016/j.jnoncrysol.2016.07.004. https://www.osti.gov/servlets/purl/1389309.
@article{osti_1389309,
title = {Structural studies of Bi 2 O 3 -Nb 2 O 5 -TeO 2 glasses},
author = {Wilding, Martin C. and Delaizir, Gaelle and Benmore, Chris J. and Gueguen, Yann and Dolhen, Morgane and Duclère, Jean-René and Chenu, Sébastien and Sukenaga, Sohei and McMillan, Paul F.},
abstractNote = {Bi2O3-Nb2O5-TeO2 glasses show unusual annealing behavior with appearance of spherulites within the matrix glass structure for the Bi0.5Nb0.5Te3O8 composition. The textures resemble those found previously among polyamorphic Al2O3-Y2O3 glasses containing metastably co-existing high- and low-density phases produced during quenching. However the spherulites produced within the Bi2O3-Nb2O5-TeO2 glass are crystalline and can be identified as an “anti-glass” phase related to β-Bi2Te4O11. Here, we used high energy synchrotron X-ray diffraction data to study structures of binary and ternary glasses quenched from liquids within the Bi2O3-Nb2O5-TeO2 system. These reveal a glassy network based on interconnected TeO4 and TeO3 units that is related to TeO2 crystalline materials but with larger Te…Te separations due to the presence of TeO3 groups and non-bridging oxygens linked to modifier (Bi3 +, Nb5 +) cations. Analysis of the viscosity-temperature relations indicates that the glass-forming liquids are “fragile” and there is no evidence for a LLPT occurring in the supercooled liquid. The glasses obtained by quenching likely correspond to a high-density amorphous (HDA) state. Subsequent annealing above Tg shows mainly evidence for direct crystallization of the “anti-glass” tellurite phase. But, some evidence may exist for simultaneous formation of nanoscale amorphous spherulites that could correspond to the LDA polyamorph. The quenching and annealing behavior of Bi2O3-Nb2O5-TeO2 supercooled liquids and glasses is compared with similar materials in the Al2O3-Y2O3 system.},
doi = {10.1016/j.jnoncrysol.2016.07.004},
url = {https://www.osti.gov/biblio/1389309},
journal = {Journal of Non-Crystalline Solids},
issn = {0022-3093},
number = C,
volume = 451,
place = {United States},
year = {Mon Jul 25 00:00:00 EDT 2016},
month = {Mon Jul 25 00:00:00 EDT 2016}
}
Web of Science
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