Graphene-modified nanostructured vanadium pentoxide hybrids with extraordinary electrochemical performance for Li-ion batteries

Liu, Qi; Li, Zhe-Fei; Liu, Yadong; Zhang, Hangyu; Ren, Yang; Sun, Cheng-Jun; Lu, Wenquan; Zhou, Yun; Stanciu, Lia; Stach, Eric A.; Xie, Jian

doi:10.1038/ncomms7127

Title: Graphene-modified nanostructured vanadium pentoxide hybrids with extraordinary electrochemical performance for Li-ion batteries

Journal Article · Tue Jan 20 00:00:00 EST 2015 · Nature Communications

DOI:https://doi.org/10.1038/ncomms7127· OSTI ID:1396038

Liu, Qi ^[1]; Li, Zhe-Fei ^[1]; Liu, Yadong ^[1]; Zhang, Hangyu ^[2]; Ren, Yang ^[3]; Sun, Cheng-Jun ^[3]; Lu, Wenquan ^[4]; Zhou, Yun ^[2]; Stanciu, Lia ^[5]; Stach, Eric A. ^[6]; Xie, Jian ^[1]

Indiana Univ.-Purdue Univ., Indianapolis, IN (United States). Purdue School of Engineering and Technology, Dept. of Mechanical Engineering
Purdue Univ., West Lafayette, IN (United States). School of Materials Engineering
Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source (APS), X-ray Science Division
Argonne National Lab. (ANL), Argonne, IL (United States). Chemical Science and Engineering Division
Purdue Univ., West Lafayette, IN (United States). School of Materials Engineering; Purdue Univ., West Lafayette, IN (United States). Weldon School of Biomedical Engineering
Brookhaven National Lab. (BNL), Upton, NY (United States). Center for Functional Nanomaterials (CFN)

The long-standing issues of low intrinsic electronic conductivity, slow lithium-ion diffusion and irreversible phase transitions on deep discharge prevent the high specific capacity/energy (443 mAh g^-1 and 1,550 Wh kg^-1) vanadium pentoxide from being used as the cathode material in practical battery applications. Here we develop a method to incorporate graphene sheets into vanadium pentoxide nanoribbons via the sol–gel process. The resulting graphene-modified nanostructured vanadium pentoxide hybrids contain only 2 wt. % graphene, yet exhibits extraordinary electrochemical performance: a specific capacity of 438 mAh g^-1, approaching the theoretical value (443 mAh g^-1), a long cyclability and significantly enhanced rate capability. Such performance is the result of the combined effects of the graphene on structural stability, electronic conduction, vanadium redox reaction and lithium-ion diffusion supported by various experimental studies. Finally, this method provides a new avenue to create nanostructured metal oxide/graphene materials for advanced battery applications.

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Research Organization:: Argonne National Laboratory (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357; AC02-98CH10886

OSTI ID:: 1396038

Journal Information:: Nature Communications, Vol. 6; ISSN 2041-1723

Publisher:: Nature Publishing GroupCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 180 works

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References (64)

Conductive polymer/oxide bronze nanocomposites. Intercalated polythiophene in vanadium pentoxide (V2O5) xerogels Kanatzidis, Mercouri G.; Wu, Chun Guey; Marcy, Henry O. Chemistry of Materials, Vol. 2, Issue 3 https://doi.org/10.1021/cm00009a005	journal	May 1990
XAS and electrochemical characterization of lithium intercalated V2O5 xerogels Passerini, S. Solid State Ionics, Vol. 90, Issue 1-4 https://doi.org/10.1016/S0167-2738(96)00380-3	journal	September 1996
Lithium Batteries and Cathode Materials Whittingham, M. Stanley Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302 https://doi.org/10.1021/cr020731c	journal	October 2004
Structure and Electrochemical Properties of Boron-Doped LiCoO2 Alcántara, R.; Lavela, P.; Tirado, J. L. Journal of Solid State Chemistry, Vol. 134, Issue 2 https://doi.org/10.1006/jssc.1997.7552	journal	December 1997
Direct Observation of Lithium Staging in Partially Delithiated LiFePO ₄ at Atomic Resolution Gu, Lin; Zhu, Changbao; Li, Hong Journal of the American Chemical Society, Vol. 133, Issue 13 https://doi.org/10.1021/ja109412x	journal	April 2011
Facile synthesis of nanostructured vanadium oxide as cathode materials for efficient Li-ion batteries Liu, Yanyi; Uchaker, Evan; Zhou, Nan Journal of Materials Chemistry, Vol. 22, Issue 46 https://doi.org/10.1039/c2jm34078j	journal	January 2012
Hierarchical Nanocomposites of Vanadium Oxide Thin Film Anchored on Graphene as High-Performance Cathodes in Li-Ion Batteries Li, Zhe-Fei; Zhang, Hangyu; Liu, Qi ACS Applied Materials & Interfaces, Vol. 6, Issue 21 https://doi.org/10.1021/am5047262	journal	October 2014
Performance of Lithium/V[sub 2]O[sub 5] Xerogel Coin Cells Tipton, A. L. Journal of The Electrochemical Society, Vol. 143, Issue 11 https://doi.org/10.1149/1.1837239	journal	January 1996
Facile synthesized nanorod structured vanadium pentoxide for high-rate lithium batteries Pan, Anqiang; Zhang, Ji-Guang; Nie, Zimin Journal of Materials Chemistry, Vol. 20, Issue 41 https://doi.org/10.1039/c0jm01306d	journal	January 2010
Synthesis of polyoxovanadates via “chimie douce” Livage, Jacques Coordination Chemistry Reviews, Vol. 178-180 https://doi.org/10.1016/S0010-8545(98)00105-2	journal	December 1998
A Comparative In Situ X-Ray Absorption Spectroscopy Study of Nanophase V[sub 2]O[sub 5] Aerogel and Ambigel Cathodes Mansour, A. N.; Smith, P. H.; Baker, W. M. Journal of The Electrochemical Society, Vol. 150, Issue 4 https://doi.org/10.1149/1.1554911	journal	January 2003
Failure Study of Commercial LiFePO ₄ Cells in over-Discharge Conditions Using Electrochemical Impedance Spectroscopy Liu, Yadong; Liu, Qi; Li, Zhefei Journal of The Electrochemical Society, Vol. 161, Issue 4 https://doi.org/10.1149/2.090404jes	journal	January 2014
The Organic-Inorganic Polyaniline/V[sub 2]O[sub 5] System. Application as a High-Capacity Hybrid Cathode for Rechargeable Lithium Batteries Lira-Cantú, M. Journal of The Electrochemical Society, Vol. 146, Issue 6 https://doi.org/10.1149/1.1391886	journal	June 1999
$K$ -edge absorption spectra of selected vanadium compounds Wong, J.; Lytle, F. W.; Messmer, R. P. Physical Review B, Vol. 30, Issue 10 https://doi.org/10.1103/PhysRevB.30.5596	journal	November 1984
Accurate Control of Multishelled Co ₃ O ₄ Hollow Microspheres as High-Performance Anode Materials in Lithium-Ion Batteries Wang, Jiangyan; Yang, Nailiang; Tang, Hongjie Angewandte Chemie International Edition, Vol. 52, Issue 25 https://doi.org/10.1002/anie.201301622	journal	May 2013
Approaching Theoretical Capacity of LiFePO[sub 4] at Room Temperature at High Rates Huang, H.; Yin, S. -C.; Nazar, L. F. Electrochemical and Solid-State Letters, Vol. 4, Issue 10 https://doi.org/10.1149/1.1396695	journal	January 2001
Chemical and Electrochemical Characterization of a Novel Nanocomposite Formed from V[sub 2]O[sub 5] and Poly(N-propane sulfonic acid aniline), a Self-Doped Polyaniline Huguenin, Fritz; Gambardella, Maria Teresa do Prado; Torresi, Roberto M. Journal of The Electrochemical Society, Vol. 147, Issue 7 https://doi.org/10.1149/1.1393550	journal	January 2000
Porous monodisperse V2O5 microspheres as cathode materials for lithium-ion batteries Wang, Suqing; Lu, Zhenda; Wang, Da Journal of Materials Chemistry, Vol. 21, Issue 17 https://doi.org/10.1039/c0jm04398b	journal	January 2011
Ultralong single crystalline V2O5 nanowire/graphene composite fabricated by a facile green approach and its lithium storage behavior Liu, Haimei; Yang, Wensheng Energy & Environmental Science, Vol. 4, Issue 10 https://doi.org/10.1039/c1ee01353j	journal	January 2011
Redox Intercalative Polymerization of Aniline in V ₂ O ₅ Xerogel. The Postintercalative Intralamellar Polymer Growth in Polyaniline/Metal Oxide Nanocomposites Is Facilitated by Molecular Oxygen Wu, C. -G.; DeGroot, D. C.; Marcy, H. O. Chemistry of Materials, Vol. 8, Issue 8 https://doi.org/10.1021/cm9600236	journal	January 1996
Improvement in the Ppy/V2O5 hybrid as a cathode material for Li ion batteries using PSA as an organic additive Boyano, I.; Bengoechea, M.; de Meatza, I. Journal of Power Sources, Vol. 166, Issue 2 https://doi.org/10.1016/j.jpowsour.2006.12.106	journal	April 2007
Rate-Dependent, Li-Ion Insertion/Deinsertion Behavior of LiFePO ₄ Cathodes in Commercial 18650 LiFePO ₄ Cells Liu, Qi; He, Hao; Li, Zhe-Fei ACS Applied Materials & Interfaces, Vol. 6, Issue 5 https://doi.org/10.1021/am405150c	journal	February 2014
CuO/graphene composite as anode materials for lithium-ion batteries Mai, Y. J.; Wang, X. L.; Xiang, J. Y. Electrochimica Acta, Vol. 56, Issue 5 https://doi.org/10.1016/j.electacta.2010.11.036	journal	February 2011
Influences of Treatment Temperature and Water Content on Capacity and Rechargeability of V[sub 2]O[sub 5] Xerogel Films Wang, Jiaxiong; Curtis, Calvin J.; Schulz, Douglas L. Journal of The Electrochemical Society, Vol. 151, Issue 1 https://doi.org/10.1149/1.1627342	journal	January 2004
Vanadium pentoxide gels Livage, J. Chemistry of Materials, Vol. 3, Issue 4 https://doi.org/10.1021/cm00016a006	journal	July 1991
Synthesis and characterization of sodium vanadium oxide gels: the effects of water (n) and sodium (x) content on the electrochemistry of NaxV2O5·nH2O Lee, Chia-Ying; Marschilok, Amy C.; Subramanian, Aditya Physical Chemistry Chemical Physics, Vol. 13, Issue 40 https://doi.org/10.1039/c1cp21658a	journal	January 2011
Honeycomb Carbon: A Review of Graphene Allen, Matthew J.; Tung, Vincent C.; Kaner, Richard B. Chemical Reviews, Vol. 110, Issue 1, p. 132-145 https://doi.org/10.1021/cr900070d	journal	January 2010
Facile Preparation and Electrochemical Properties of V ₂ O ₅ -Graphene Composite Films as Free-Standing Cathodes for Rechargeable Lithium Batteries Qian, Yuqiang; Vu, Anh; Smyrl, William Journal of The Electrochemical Society, Vol. 159, Issue 8 https://doi.org/10.1149/2.004208jes	journal	January 2012
Self-Assembled Vanadium Pentoxide (V2O5) Hollow Microspheres from Nanorods and Their Application in Lithium-Ion Batteries Cao, An-Min; Hu, Jin-Song; Liang, Han-Pu Angewandte Chemie International Edition, Vol. 44, Issue 28 https://doi.org/10.1002/anie.200500946	journal	July 2005
Performance of copper-doped V2O5 xerogel in coin cell assembly Coustier, Fabrice; Jarero, Gabriel; Passerini, Stefano Journal of Power Sources, Vol. 83, Issue 1-2 https://doi.org/10.1016/S0378-7753(99)00243-8	journal	October 1999
Aerogels and Xerogels of V[sub 2]O[sub 5] as Intercalation Hosts Le, D. B. Journal of The Electrochemical Society, Vol. 142, Issue 6 https://doi.org/10.1149/1.2044250	journal	January 1995
In situ XAS investigation of the oxidation state and local structure of vanadium in discharged and charged V2O5 aerogel cathodes Mansour, A. N.; Smith, P. H.; Baker, W. M. Electrochimica Acta, Vol. 47, Issue 19 https://doi.org/10.1016/S0013-4686(02)00234-7	journal	July 2002
Electrochemical Li Insertion into Conductive Polymer/V[sub 2]O[sub 5] Nanocomposites Leroux, F. Journal of The Electrochemical Society, Vol. 144, Issue 11 https://doi.org/10.1149/1.1838107	journal	January 1997
Synthesis of polymeric tetraphenylphosphonium (tetraselenido)argentate(1-) [(Ph4P)AgSe4]n. A novel one-dimensional inorganic polymer Kanatzidis, Mercouri G.; Huang, Song Ping Journal of the American Chemical Society, Vol. 111, Issue 2 https://doi.org/10.1021/ja00184a070	journal	January 1989
Morphology, structure and electrochemical properties of single phase electrospun vanadium pentoxide nanofibers for lithium ion batteries Cheah, Yan L.; Gupta, Nutan; Pramana, Stevin S. Journal of Power Sources, Vol. 196, Issue 15 https://doi.org/10.1016/j.jpowsour.2011.03.039	journal	August 2011
Fabrication of High-Surface-Area Graphene/Polyaniline Nanocomposites and Their Application in Supercapacitors Li, Zhe-Fei; Zhang, Hangyu; Liu, Qi ACS Applied Materials & Interfaces, Vol. 5, Issue 7 https://doi.org/10.1021/am4001634	journal	March 2013
Enhancement of the electrochemical performance of a Li-intercalated V2O5 xerogel doped with Eu Almeida, E. Solid State Ionics, Vol. 160, Issue 1-2 https://doi.org/10.1016/S0167-2738(03)00126-7	journal	May 2003
Investigation of a Catalyst Ink Dispersion Using Both Ultra-Small-Angle X-ray Scattering and Cryogenic TEM Xu, Fan; Zhang, HangYu; Ilavsky, Jan Langmuir, Vol. 26, Issue 24 https://doi.org/10.1021/la1028228	journal	December 2010
Preparation and Electrochemical Properties of SnO2 Nanowires for Application in Lithium-Ion Batteries Park, Min-Sik; Wang, Guo-Xiu; Kang, Yong-Mook Angewandte Chemie, Vol. 119, Issue 5 https://doi.org/10.1002/ange.200603309	journal	January 2007
Design and synthesis of inorganic–organic hybrid microstructures Harreld, J. H.; Dunn, B.; Nazar, L. F. International Journal of Inorganic Materials, Vol. 1, Issue 2 https://doi.org/10.1016/S1466-6049(99)00022-7	journal	August 1999
In Situ X-Ray Absorption Spectroscopy Characterization of V₂O₅ Xerogel Cathodes upon Lithium Intercalation Giorgetti, Marco; Passerini, Stefano; Smyrl, William H. Journal of The Electrochemical Society, Vol. 146, Issue 7, p. 2387-2392 https://doi.org/10.1149/1.1391946	journal	January 1999
Structure of V ₂ O ₅ · n H ₂ O Xerogel Solved by the Atomic Pair Distribution Function Technique Petkov, Valeri; Trikalitis, Pantelis N.; Bozin, Emil S. Journal of the American Chemical Society, Vol. 124, Issue 34 https://doi.org/10.1021/ja026143y	journal	August 2002
The Structural Evolution of V2O5 Nanocystals during Electrochemical Cycling Studied Using In operando Synchrotron Techniques Liu, Qi; Liu, Yadong; Sun, Cheng-Jun Electrochimica Acta, Vol. 136 https://doi.org/10.1016/j.electacta.2014.05.100	journal	August 2014
Ultraflat graphene Lui, Chun Hung; Liu, Li; Mak, Kin Fai Nature, Vol. 462, Issue 7271 https://doi.org/10.1038/nature08569	journal	November 2009
Electrospun Ultralong Hierarchical Vanadium Oxide Nanowires with High Performance for Lithium Ion Batteries Mai, Liqiang; Xu, Lin; Han, Chunhua Nano Letters, Vol. 10, Issue 11 https://doi.org/10.1021/nl103343w	journal	November 2010
Vanadium Oxide-Carbon Nanotube Composite Electrodes for Use in Secondary Lithium Batteries Sakamoto, J. S.; Dunn, B. Journal of The Electrochemical Society, Vol. 149, Issue 1 https://doi.org/10.1149/1.1425791	journal	January 2002
(De)Lithiation Mechanism of Li/SeS _x ( x = 0–7) Batteries Determined by in Situ Synchrotron X-ray Diffraction and X-ray Absorption Spectroscopy Cui, Yanjie; Abouimrane, Ali; Lu, Jun Journal of the American Chemical Society, Vol. 135, Issue 21 https://doi.org/10.1021/ja402597g	journal	May 2013
Dip-coated silver-doped V2O5 xerogels as host materials for lithium intercalation Coustier, F. Solid State Ionics, Vol. 100, Issue 3-4 https://doi.org/10.1016/S0167-2738(97)00354-8	journal	October 1997
Graphene–V2O5·nH2O xerogel composite cathodes for lithium ion batteries Du, Guodong; Seng, Kuok Hau; Guo, Zaiping RSC Advances, Vol. 1, Issue 4 https://doi.org/10.1039/c1ra00258a	journal	January 2011
Electrically conductive oxide aerogels: new materials in electrochemistry Rolison, Debra R.; Dunn, Bruce Journal of Materials Chemistry, Vol. 11, Issue 4, p. 963-980 https://doi.org/10.1039/b007591o	journal	January 2001
Coral-like V2O5 nanowhiskers as high-capacity cathode materials for lithium-ion batteries Wang, Bei; Wang, Ying; Sun, Bing RSC Advances, Vol. 3, Issue 15 https://doi.org/10.1039/c3ra22425b	journal	January 2013
Nanostructured Vanadium Oxide Electrodes for Enhanced Lithium-Ion Intercalation Wang, Y.; Takahashi, K.; Lee, K. H. Advanced Functional Materials, Vol. 16, Issue 9, p. 1133-1144 https://doi.org/10.1002/adfm.200500662	journal	June 2006
On the δ → γ irreversible transformation in Li//V2O5 secondary batteries Cocciantelli, J. Solid State Ionics, Vol. 78, Issue 1-2 https://doi.org/10.1016/0167-2738(95)00015-X	journal	May 1995
Synthesis and electrochemical properties of V2O5 nanostructures prepared via a precipitation process for lithium-ion battery cathodes Ng, S. H.; Chew, S. Y.; Wang, J. Journal of Power Sources, Vol. 174, Issue 2 https://doi.org/10.1016/j.jpowsour.2007.06.166	journal	December 2007
Structural Modification of Graphene Sheets to Create a Dense Network of Defect Sites Wang, Mei-xian; Liu, Qi; Li, Zhe-Fei The Journal of Physical Chemistry Letters, Vol. 4, Issue 9 https://doi.org/10.1021/jz4001664	journal	April 2013
Facile preparation of hydrated vanadium pentoxide nanobelts based bulky paper as flexible binder-free cathodes for high-performance lithium ion batteries Rui, Xianhong; Zhu, Jixin; Liu, Weiling RSC Advances, Vol. 1, Issue 1 https://doi.org/10.1039/c1ra00281c	journal	January 2011
Mesoporous vanadium pentoxide nanofibers with significantly enhanced Li-ion storage properties by electrospinning Yu, Danmei; Chen, Changguo; Xie, Shuhong Energy Environ. Sci., Vol. 4, Issue 3 https://doi.org/10.1039/C0EE00313A	journal	January 2011
Vanadium pentoxide cathode materials for high-performance lithium-ion batteries enabled by a hierarchical nanoflower structure via an electrochemical process Tang, Yuxin; Rui, Xianhong; Zhang, Yanyan J. Mater. Chem. A, Vol. 1, Issue 1 https://doi.org/10.1039/C2TA00351A	journal	January 2013
Recent advances in micro-/nano-structured hollow spheres for energy applications: From simple to complex systems Lai, Xiaoyong; Halpert, Jonathan E.; Wang, Dan Energy Environ. Sci., Vol. 5, Issue 2 https://doi.org/10.1039/C1EE02426D	journal	January 2012
Self-Assembled Vanadium Pentoxide (V2O5) Hollow Microspheres from Nanorods and Their Application in Lithium-Ion Batteries Cao, An-Min; Hu, Jin-Song; Liang, Han-Pu Angewandte Chemie, Vol. 117, Issue 28 https://doi.org/10.1002/ange.200500946	journal	July 2005
Accurate Control of Multishelled Co ₃ O ₄ Hollow Microspheres as High-Performance Anode Materials in Lithium-Ion Batteries Wang, Jiangyan; Yang, Nailiang; Tang, Hongjie Angewandte Chemie, Vol. 125, Issue 25 https://doi.org/10.1002/ange.201301622	journal	May 2013
Lithium Batteries and Cathode Materials Whittingham, M. Stanley ChemInform, Vol. 35, Issue 50 https://doi.org/10.1002/chin.200450266	journal	December 2004
Self-Assembled Vanadium Pentoxide (V2O5) Hollow Microspheres from Nanorods and Their Application in Lithium-Ion Batteries. Cao, An-Min; Hu, Jin-Song; Liang, Han-Pu ChemInform, Vol. 36, Issue 41 https://doi.org/10.1002/chin.200541012	journal	October 2005
Preparation and Electrochemical Properties of SnO₂ Nanowires for Application in Lithium-Ion Batteries Park, Min-Sik; Wang, Guo-Xiu; Kang, Yong-Mook Angewandte Chemie International Edition, Vol. 46, Issue 5, p. 750-753 https://doi.org/10.1002/anie.200603309	journal	January 2007

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Ionic gating drives correlated insulator–metal transition Rappe, Andrew M. Proceedings of the National Academy of Sciences, Vol. 115, Issue 39 https://doi.org/10.1073/pnas.1812913115	journal	September 2018
High areal capacitance of vanadium oxides intercalated Ti ₃ C ₂ MXene for flexible supercapacitors with high mass loading Zhang, Zezhong; Guo, Miao; Tang, Yanhong Nanotechnology, Vol. 31, Issue 16 https://doi.org/10.1088/1361-6528/ab6689	journal	January 2020
Polyaniline globules as a catalyst for WO ₃ nanoparticles for supercapacitor application Kadam, Anamika V.; Patil, Shubham B. Materials Research Express, Vol. 5, Issue 8 https://doi.org/10.1088/2053-1591/aad406	journal	July 2018
In Situ Constructing Flexible V ₂ O ₅ @GO Composite Thin Film Electrode for Superior Electrochemical Energy Storage Hu, Bingbing; Xiang, Qin; Cen, Yuan Journal of The Electrochemical Society, Vol. 165, Issue 16 https://doi.org/10.1149/2.0341816jes	journal	January 2018
Nanostructured V ₂ O ₅ /Nitrogen-doped Graphene Hybrids for High Rate Lithium Storage Yang, Yiqun; Strong, Kayla; Pandey, Gaind P. MRS Advances, Vol. 3, Issue 60 https://doi.org/10.1557/adv.2018.424	journal	January 2018
Self-Doped Conjugated Polymeric Binders Improve the Capacity and Mechanical Properties of V2O5 Cathodes Li, Xiaoyi; An, Hyosung; Strzalka, Joseph Polymers, Vol. 11, Issue 4 https://doi.org/10.3390/polym11040589	journal	April 2019
Synthesis of graphene–transition metal oxide hybrid nanoparticles and their application in various fields Jana, Arpita; Scheer, Elke; Polarz, Sebastian Beilstein Journal of Nanotechnology, Vol. 8 https://doi.org/10.3762/bjnano.8.74	journal	January 2017
Electrodeposition of hydrated vanadium pentoxide on nanoporous carbon cloth for hybrid energy storage Lee, Juhan; Badie, Sylvain; Srimuk, Pattarachai Universität des Saarlandes https://doi.org/10.22028/d291-28918	collection	January 2018
Nanostructured porous graphene and its composites for energy storage applications Ramos Ferrer, Pablo; Mace, Annsley; Thomas, Samantha N. Nano Convergence, Vol. 4, Issue 1 https://doi.org/10.1186/s40580-017-0123-0	journal	October 2017
Vanadium Pentoxide Nanobelt-Reduced Graphene Oxide Nanosheet Composites as High-Performance Pseudocapacitive Electrodes: ac Impedance Spectroscopy Data Modeling and Theoretical Calculations Gupta, Sanju; Aberg, Bryce; Carrizosa, Sara Materials, Vol. 9, Issue 8 https://doi.org/10.3390/ma9080615	journal	July 2016

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