Rotational superstructure in van der Waals heterostructure of self-assembled C60 monolayer on the WSe2 surface

Santos, Elton J. G.; Scullion, Declan; Chu, Ximo S.; Li, Duo O.; Guisinger, Nathan P.; Wang, Qing Hua

doi:10.1039/C7NR03951D

Title: Rotational superstructure in van der Waals heterostructure of self-assembled C₆₀ monolayer on the WSe₂ surface

Journal Article · Wed Aug 23 00:00:00 EDT 2017 · Nanoscale

DOI:https://doi.org/10.1039/C7NR03951D· OSTI ID:1395061

^[1];

^[2];

^[3];

^[2]

Queen's Univ., Belfast (United Kingdom)
Arizona State Univ., Tempe, AZ (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)

Hybrid van der Waals (vdW) heterostructures composed of two-dimensional (2D) layered materials and self-assembled organic molecules are promising systems for electronic and optoelectronic applications with enhanced properties and performance. Control of molecular assembly is therefore paramount to fundamentally understand the nucleation, ordering, alignment, and electronic interaction of organic molecules with 2D materials. Here, we report the formation and detailed study of highly ordered, crystalline monolayers of C₆₀ molecules self-assembled on the surface of WSe₂ in well-ordered arrays with large grain sizes (~5 μm). Using high-resolution scanning tunneling microscopy (STM), we observe a periodic 2 × 2 superstructure in the C₆₀ monolayer and identify four distinct molecular appearances. Using vdW-corrected ab initio density functional theory (DFT) simulations, we determine that the interplay between vdW and Coulomb interactions as well as adsorbate–adsorbate and adsorbate–substrate interactions results in specific rotational arrangements of the molecules forming the superstructure. The orbital ordering through the relative positions of bonds in adjacent molecules creates a charge redistribution that links the molecule units in a long-range network. Furthermore, this rotational superstructure extends throughout the self-assembled monolayer and opens a pathway towards engineering aligned hybrid organic/inorganic vdW heterostructures with 2D layered materials in a precise and controlled way.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1395061

Journal Information:: Nanoscale, Vol. 9, Issue 35; ISSN 2040-3364

Publisher:: Royal Society of ChemistryCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 21 works

Citation information provided by
Web of Science

References (76)

Generalized Gradient Approximation Made Simple Perdew, John P.; Burke, Kieron; Ernzerhof, Matthias Physical Review Letters, Vol. 77, Issue 18, p. 3865-3868 https://doi.org/10.1103/PhysRevLett.77.3865	journal	October 1996
Mixed-dimensional van der Waals heterostructures Jariwala, Deep; Marks, Tobin J.; Hersam, Mark C. Nature Materials, Vol. 16, Issue 2 https://doi.org/10.1038/nmat4703	journal	August 2016
Scanning tunneling microscopy of ordered C60 and C70 layers on Au(111), Cu(111), Ag(110), and Au(110) surfaces Gimzewski, J. K. Journal of Vacuum Science & Technology B: Microelectronics and Nanometer Structures, Vol. 12, Issue 3 https://doi.org/10.1116/1.587676	journal	May 1994
Patterning organic single-crystal transistor arrays Briseno, Alejandro L.; Mannsfeld, Stefan C. B.; Ling, Mang M. Nature, Vol. 444, Issue 7121, p. 913-917 https://doi.org/10.1038/nature05427	journal	December 2006
Tunneling spectroscopy of isolated $C_{60}$ molecules in the presence of charging effects Porath, Danny; Levi, Yair; Tarabiah, Moeen Physical Review B, Vol. 56, Issue 15 https://doi.org/10.1103/PhysRevB.56.9829	journal	October 1997
Epitaxially Grown Strained Pentacene Thin Film on Graphene Membrane Kim, Kwanpyo; Santos, Elton J. G.; Lee, Tae Hoon Small, Vol. 11, Issue 17 https://doi.org/10.1002/smll.201403006	journal	January 2015
Molecular Orientation-Dependent Interfacial Energetics and Built-in Voltage Tuned by a Template Graphene Monolayer Zhang, Lushuai; Roy, Susmit Singha; Hamers, Robert J. The Journal of Physical Chemistry C, Vol. 119, Issue 1 https://doi.org/10.1021/jp508931e	journal	December 2014
Ultrafast charge-transfer in organic photovoltaic interfaces: geometrical and functionalization effects Santos, Elton J. G.; Wang, W. L. Nanoscale, Vol. 8, Issue 35 https://doi.org/10.1039/C6NR02857H	journal	January 2016
Room-temperature molecular-resolution characterization of self-assembled organic monolayers on epitaxial graphene Wang, Qing Hua; Hersam, Mark C. Nature Chemistry, Vol. 1, Issue 3 https://doi.org/10.1038/nchem.212	journal	May 2009
Orientation of individual $C_{60}$ molecules adsorbed on Cu(111): Low-temperature scanning tunneling microscopy and density functional calculations Larsson, J. Andreas; Elliott, Simon D.; Greer, James C. Physical Review B, Vol. 77, Issue 11 https://doi.org/10.1103/PhysRevB.77.115434	journal	March 2008
Orientationally Ordered ( $7 \times 7$ ) Superstructure of $C_{60}$ on Au(111) Schull, G.; Berndt, R. Physical Review Letters, Vol. 99, Issue 22 https://doi.org/10.1103/PhysRevLett.99.226105	journal	November 2007
Nucleation, growth, and structure of fullerene films on Au(111) Altman, Eric I.; Colton, Richard J. Surface Science, Vol. 279, Issue 1-2 https://doi.org/10.1016/0039-6028(92)90741-N	journal	December 1992
Observation of Ground- and Excited-State Charge Transfer at the C ₆₀ /Graphene Interface Jnawali, Giriraj; Rao, Yi; Beck, Jonathan H. ACS Nano, Vol. 9, Issue 7 https://doi.org/10.1021/acsnano.5b01896	journal	June 2015
Structure, dynamics and ordering transition of solid C60 Heiney, Paul A. Journal of Physics and Chemistry of Solids, Vol. 53, Issue 11 https://doi.org/10.1016/0022-3697(92)90231-2	journal	November 1992
Weakly Interacting Molecular Layer of Spinning C ₆₀ Molecules on TiO ₂ (110) Surfaces Sanchez-Sanchez, Carlos; Lanzilotto, Valeria; Gonzalez, Cesar Chemistry - A European Journal, Vol. 18, Issue 24 https://doi.org/10.1002/chem.201200627	journal	May 2012
2D materials and van der Waals heterostructures Novoselov, K. S.; Mishchenko, A.; Carvalho, A. Science, Vol. 353, Issue 6298 https://doi.org/10.1126/science.aac9439	journal	July 2016
Charge Photogeneration in Organic Solar Cells Clarke, Tracey M.; Durrant, James R. Chemical Reviews, Vol. 110, Issue 11, p. 6736-6767 https://doi.org/10.1021/cr900271s	journal	November 2010
Van der Waals heterostructures and devices Liu, Yuan; Weiss, Nathan O.; Duan, Xidong Nature Reviews Materials, Vol. 1, Issue 9 https://doi.org/10.1038/natrevmats.2016.42	journal	July 2016
Self-assembly of C ₆₀ monolayer on epitaxially grown, nanostructured graphene on Ru(0001) surface Li, G.; Zhou, H. T.; Pan, L. D. Applied Physics Letters, Vol. 100, Issue 1 https://doi.org/10.1063/1.3673830	journal	January 2012
Fabrication and processing of polymer solar cells: A review of printing and coating techniques Krebs, Frederik C. Solar Energy Materials and Solar Cells, Vol. 93, Issue 4, p. 394-412 https://doi.org/10.1016/j.solmat.2008.10.004	journal	April 2009
Low-Temperature Orientationally Ordered Structures of Two-Dimensional C ₆₀ Yuan, Lan-Feng; Yang, Jinlong; Wang, Haiqian Journal of the American Chemical Society, Vol. 125, Issue 1 https://doi.org/10.1021/ja025775h	journal	January 2003
Semiconductor–Insulator–Semiconductor Diode Consisting of Monolayer MoS ₂ , h-BN, and GaN Heterostructure Jeong, Hyun; Bang, Seungho; Oh, Hye Min ACS Nano, Vol. 9, Issue 10 https://doi.org/10.1021/acsnano.5b04233	journal	September 2015
Direct imaging of intrinsic molecular orbitals using two-dimensional, epitaxially-grown, nanostructured graphene for study of single molecule and interactions Zhou, H. T.; Mao, J. H.; Li, G. Applied Physics Letters, Vol. 99, Issue 15 https://doi.org/10.1063/1.3646406	journal	October 2011
Light-emitting diodes by band-structure engineering in van der Waals heterostructures Withers, F.; Del Pozo-Zamudio, O.; Mishchenko, A. Nature Materials, Vol. 14, Issue 3 https://doi.org/10.1038/nmat4205	journal	February 2015
Gate-Controlled Energy Barrier at a Graphene/Molecular Semiconductor Junction Parui, Subir; Pietrobon, Luca; Ciudad, David Advanced Functional Materials, Vol. 25, Issue 20 https://doi.org/10.1002/adfm.201403407	journal	March 2015
Tuning fulleride electronic structure and molecular ordering via variable layer index Wang, Yayu; Yamachika, Ryan; Wachowiak, Andre Nature Materials, Vol. 7, Issue 3, p. 194-197 https://doi.org/10.1038/nmat2100	journal	January 2008
Flexible and Transparent MoS ₂ Field-Effect Transistors on Hexagonal Boron Nitride-Graphene Heterostructures Lee, Gwan-Hyoung; Yu, Young-Jun; Cui, Xu ACS Nano, Vol. 7, Issue 9 https://doi.org/10.1021/nn402954e	journal	August 2013
Nanoscale Imaging of Charge Carrier and Exciton Trapping at Structural Defects in Organic Semiconductors Große, Christoph; Gunnarsson, Olle; Merino, Pablo Nano Letters, Vol. 16, Issue 3 https://doi.org/10.1021/acs.nanolett.6b00190	journal	February 2016
Efficient thin-film organic solar cells based on pentacene/C60 heterojunctions Yoo, S.; Domercq, B.; Kippelen, B. Applied Physics Letters, Vol. 85, Issue 22 https://doi.org/10.1063/1.1829777	journal	November 2004
Hybrid, Gate-Tunable, van der Waals p–n Heterojunctions from Pentacene and MoS ₂ Jariwala, Deep; Howell, Sarah L.; Chen, Kan-Sheng Nano Letters, Vol. 16, Issue 1 https://doi.org/10.1021/acs.nanolett.5b04141	journal	December 2015
Atomically resolved orientational ordering of C ₆₀ molecules on epitaxial graphene on Cu(111) Jung, Minbok; Shin, Dongbin; Sohn, So-Dam Nanoscale, Vol. 6, Issue 20 https://doi.org/10.1039/C4NR03249G	journal	January 2014
van der Waals interactions mediating the cohesion of fullerenes on graphene Švec, M.; Merino, P.; Dappe, Y. J. Physical Review B, Vol. 86, Issue 12 https://doi.org/10.1103/PhysRevB.86.121407	journal	September 2012
Orientational configurations of the $C_{60}$ molecules in the $(2 \times 2)$ superlattice on a solid $C_{60}$ (111) surface at low temperature Wang, Haiqian; Zeng, Changgan; Wang, Bing Physical Review B, Vol. 63, Issue 8 https://doi.org/10.1103/PhysRevB.63.085417	journal	February 2001
Nanofabrication of Heteromolecular Organic Nanostructures on Epitaxial Graphene via Room Temperature Feedback-Controlled Lithography Wang, Qing Hua; Hersam, Mark C. Nano Letters, Vol. 11, Issue 2 https://doi.org/10.1021/nl103590j	journal	February 2011
Complex orientational ordering of C ₆₀ molecules on Au(111) Tang, Lin; Xie, Yangchun; Guo, Quanmin The Journal of Chemical Physics, Vol. 135, Issue 11 https://doi.org/10.1063/1.3639106	journal	September 2011
An STM study of C60 adsorption on Si(100)-(2 × 1) surfaces: from physisorption to chemisorption Chen, Dong; Sarid, Dror Surface Science, Vol. 329, Issue 3 https://doi.org/10.1016/0039-6028(95)00051-8	journal	May 1995
Orientation dependence of charge transfer for C60 on Cu(100) Daughton, D. R.; Gupta, J. A. Applied Physics Letters, Vol. 98, Issue 13 https://doi.org/10.1063/1.3569719	journal	March 2011
Energetic preference in 5,6 and 6,6 ring junction adducts of C60: fulleroids and methanofullerenes Prato, Maurizio; Lucchini, Vittorio; Maggini, Michele Journal of the American Chemical Society, Vol. 115, Issue 18 https://doi.org/10.1021/ja00071a080	journal	September 1993
Structural and Electronic Decoupling of C ₆₀ from Epitaxial Graphene on SiC Cho, Jongweon; Smerdon, Joseph; Gao, Li Nano Letters, Vol. 12, Issue 6 https://doi.org/10.1021/nl3008049	journal	May 2012
Van der Waals heterostructures Geim, A. K.; Grigorieva, I. V. Nature, Vol. 499, Issue 7459, p. 419-425 https://doi.org/10.1038/nature12385	journal	July 2013
Ultrafast Exciton Dissociation and Long-Lived Charge Separation in a Photovoltaic Pentacene–MoS ₂ van der Waals Heterojunction Bettis Homan, Stephanie; Sangwan, Vinod K.; Balla, Itamar Nano Letters, Vol. 17, Issue 1 https://doi.org/10.1021/acs.nanolett.6b03704	journal	December 2016
Density functional study of the adsorption of a $C_{60}$ monolayer on Ag(111) and Au(111) surfaces Wang, Lin-Lin; Cheng, Hai-Ping Physical Review B, Vol. 69, Issue 16 https://doi.org/10.1103/PhysRevB.69.165417	journal	April 2004
Templating Highly Crystalline Organic Semiconductors Using Atomic Membranes of Graphene at the Anode/Organic Interface Singha Roy, Susmit; Bindl, Dominick J.; Arnold, Michael S. The Journal of Physical Chemistry Letters, Vol. 3, Issue 7 https://doi.org/10.1021/jz201559g	journal	March 2012
Ab initio molecular dynamics for open-shell transition metals Kresse, G.; Hafner, J. Physical Review B, Vol. 48, Issue 17 https://doi.org/10.1103/PhysRevB.48.13115	journal	November 1993
Light Generation and Harvesting in a van der Waals Heterostructure Lopez-Sanchez, Oriol; Alarcon Llado, Esther; Koman, Volodymyr ACS Nano, Vol. 8, Issue 3 https://doi.org/10.1021/nn500480u	journal	March 2014
Efficient iterative schemes for ab initio total-energy calculations using a plane-wave basis set Kresse, G.; Furthmüller, J. Physical Review B, Vol. 54, Issue 16, p. 11169-11186 https://doi.org/10.1103/PhysRevB.54.11169	journal	October 1996
Intramolecular structures of $C_{60}$ molecules adsorbed on the Cu(111)-(1×1) surface Hashizume, Tomihiro; Motai, K.; Wang, X. D. Physical Review Letters, Vol. 71, Issue 18 https://doi.org/10.1103/PhysRevLett.71.2959	journal	November 1993
Structural and Electrical Investigation of C ₆₀ –Graphene Vertical Heterostructures Kim, Kwanpyo; Lee, Tae Hoon; Santos, Elton J. G. ACS Nano, Vol. 9, Issue 6 https://doi.org/10.1021/acsnano.5b00581	journal	May 2015
Structural Phase Transitions in the Fullerene C ₆₀ David, W. I. F.; Ibberson, R. M.; Dennis, T. J. S. Europhysics Letters (EPL), Vol. 18, Issue 3 https://doi.org/10.1209/0295-5075/18/3/006	journal	February 1992
Epitaxial Growth of Molecular Crystals on van der Waals Substrates for High-Performance Organic Electronics Lee, Chul-Ho; Schiros, Theanne; Santos, Elton J. G. Advanced Materials, Vol. 26, Issue 18 https://doi.org/10.1002/adma.201304973	journal	January 2014
Orientational ordering of the second layer of C60 molecules on Au(111) Tang, Lin; Guo, Quanmin Physical Chemistry Chemical Physics, Vol. 14, Issue 10 https://doi.org/10.1039/c2cp23871c	journal	January 2012
Seeing molecular orbitals Pascual, J. I.; Gómez-Herrero, J.; Rogero, C. Chemical Physics Letters, Vol. 321, Issue 1-2 https://doi.org/10.1016/S0009-2614(00)00337-7	journal	April 2000
Determination of the orientation of $C_{60}$ adsorbed on Au(111) and Ag(111) Altman, Eric I.; Colton, Richard J. Physical Review B, Vol. 48, Issue 24 https://doi.org/10.1103/PhysRevB.48.18244	journal	December 1993
Interfacial and intermolecular interactions determining the rotational orientation of C60 adsorbed on Au(111) Paßens, Michael; Karthäuser, Silvia Surface Science, Vol. 642 https://doi.org/10.1016/j.susc.2015.07.025	journal	December 2015
Materials and Mechanics for Stretchable Electronics Rogers, J. A.; Someya, T.; Huang, Y. Science, Vol. 327, Issue 5973, p. 1603-1607 https://doi.org/10.1126/science.1182383	journal	March 2010
Van der Waals Density Functional for General Geometries Dion, M.; Rydberg, H.; Schröder, E. Physical Review Letters, Vol. 92, Issue 24 https://doi.org/10.1103/PhysRevLett.92.246401	journal	June 2004
Chemical Vapor-Deposited Hexagonal Boron Nitride as a Scalable Template for High-Performance Organic Field-Effect Transistors Lee, Tae Hoon; Kim, Kwanpyo; Kim, Gwangwoo Chemistry of Materials, Vol. 29, Issue 5 https://doi.org/10.1021/acs.chemmater.6b05517	journal	February 2017
Electronics based on two-dimensional materials Fiori, Gianluca; Bonaccorso, Francesco; Iannaccone, Giuseppe Nature Nanotechnology, Vol. 9, Issue 10 https://doi.org/10.1038/nnano.2014.207	journal	October 2014
Charge transport and mobility engineering in two-dimensional transition metal chalcogenide semiconductors Li, Song-Lin; Tsukagoshi, Kazuhito; Orgiu, Emanuele Chemical Society Reviews, Vol. 45, Issue 1 https://doi.org/10.1039/C5CS00517E	journal	January 2016
Resolution of site-specific bonding properties of C60 adsorbed on Au(111) Rogero, C.; Pascual, J. I.; Gómez-Herrero, J. The Journal of Chemical Physics, Vol. 116, Issue 2 https://doi.org/10.1063/1.1424291	journal	January 2002
Semiconducting π-Conjugated Systems in Field-Effect Transistors: A Material Odyssey of Organic Electronics Wang, Chengliang; Dong, Huanli; Hu, Wenping Chemical Reviews, Vol. 112, Issue 4 https://doi.org/10.1021/cr100380z	journal	November 2011
STM imagery and density functional calculations of C $_{60}$ fullerene adsorption on the 6H-SiC(0001)-3 $\times$ 3 surface Ovramenko, T.; Spillebout, F.; Bocquet, F. C. Physical Review B, Vol. 87, Issue 15 https://doi.org/10.1103/PhysRevB.87.155421	journal	April 2013
Photoinduced charge transfer from vacuum-deposited molecules to single-layer transition metal dichalcogenides Osada, Kazuki; Tanaka, Masatoshi; Ohno, Shinya Japanese Journal of Applied Physics, Vol. 55, Issue 6 https://doi.org/10.7567/JJAP.55.065201	journal	May 2016
Growth and characterization of fullerene nanocrystals on NaCl/Au(111) Rossel, Frédéric; Pivetta, Marina; Patthey, François Physical Review B, Vol. 84, Issue 7 https://doi.org/10.1103/PhysRevB.84.075426	journal	August 2011
Orientationally Ordered C ₆₀ on p -Sexiphenyl Nanostripes on Ag(111) Chen, Wei; Zhang, Hongliang; Huang, Han ACS Nano, Vol. 2, Issue 4 https://doi.org/10.1021/nn800033z	journal	March 2008
A Combined Monte Carlo and Hückel Theory Simulation of Orientational Ordering in C ₆₀ Assemblies Leaf, Jeremy; Stannard, Andrew; Jarvis, Samuel P. The Journal of Physical Chemistry C, Vol. 120, Issue 15 https://doi.org/10.1021/acs.jpcc.6b00638	journal	April 2016
Topology of two-dimensional C60 domains Hou, J. G.; Jinlong, Yang; Haiqian, Wang Nature, Vol. 409, Issue 6818 https://doi.org/10.1038/35053163	journal	January 2001
Organic field-effect transistors Małachowski, M.; Żmija, J. Opto-Electronics Review, Vol. 18, Issue 2 https://doi.org/10.2478/s11772-010-0008-9	journal	January 2010
Nucleation, growth, and structure of fullerene films on Au(111) Altman, Eric I.; Colton, Richard J. Surface Science Letters, Vol. 279, Issue 1-2 https://doi.org/10.1016/0167-2584(92)90205-j	journal	December 1992
Growth and characterization of fullerene nanocrystals on NaCl/Au(111) Rossel, F.; Pivetta, M.; Patthey, F. American Physical Society https://doi.org/10.5167/uzh-51643	text	January 2011
Structural Phase Transitions in the Fullerene C ₆₀ David, W. I. F.; Ibberson, R. M.; Dennis, T. J. S. Europhysics Letters (EPL), Vol. 18, Issue 8 https://doi.org/10.1209/0295-5075/18/8/012	journal	April 1992
Light Generation and Harvesting in a Van der Waals Heterostructure Lopez-Sanchez, Oriol; Llado, Esther Alarcon; Koman, Volodymyr arXiv https://doi.org/10.48550/arxiv.1403.2743	text	January 2014
Light-emitting diodes by bandstructure engineering in van der Waals heterostructures Withers, F.; Del Pozo-Zamudio, O.; Mishchenko, A. arXiv https://doi.org/10.48550/arxiv.1412.7621	text	January 2014
Charge transport and mobility engineering in two-dimensional transition metal chalcogenide semiconductors Li, Song-Lin; Tsukagoshi, Kazihito; Orgiu, Emanuele arXiv https://doi.org/10.48550/arxiv.1602.03116	text	January 2016
Mixed-Dimensional van der Waals Heterostructures Jariwala, Deep; Marks, Tobin J.; Hersam, Mark C. arXiv https://doi.org/10.48550/arxiv.1608.00515	text	January 2016
2D materials and van der Waals heterostructures Novoselov, K. S.; Mishchenko, A.; Carvalho, A. arXiv https://doi.org/10.48550/arxiv.1608.03059	text	January 2016

Cited By (10)

Interface Characterization and Control of 2D Materials and Heterostructures Liu, Xiaolong; Hersam, Mark C. Advanced Materials, Vol. 30, Issue 39 https://doi.org/10.1002/adma.201801586	journal	July 2018
2D–Organic Hybrid Heterostructures for Optoelectronic Applications Sun, Jia; Choi, Yongsuk; Choi, Young Jin Advanced Materials, Vol. 31, Issue 34 https://doi.org/10.1002/adma.201803831	journal	February 2019
Hybrids of Fullerenes and 2D Nanomaterials Chen, Muqing; Guan, Runnan; Yang, Shangfeng Advanced Science, Vol. 6, Issue 1 https://doi.org/10.1002/advs.201800941	journal	September 2018
Asymmetric electric field screening in van der Waals heterostructures Li, Lu Hua; Tian, Tian; Cai, Qiran Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03592-3	journal	March 2018
Sc ₃ N@C ₈₀ and La@C ₈₂ doped graphene for a new class of optoelectronic devices Jayanand, Kishan; Chugh, Srishti; Adhikari, Nirmal Journal of Materials Chemistry C, Vol. 8, Issue 12 https://doi.org/10.1039/c9tc06145b	journal	January 2020
Fullerene/layered antiferromagnetic reconstructed spinterface: Subsurface layer dominates molecular orbitals’ spin-split and large induced magnetic moment Shao, Yangfan; Pang, Rui; Pan, Hui The Journal of Chemical Physics, Vol. 148, Issue 11 https://doi.org/10.1063/1.5012926	journal	March 2018
Tailoring the growth and electronic structures of organic molecular thin films Tan, Andrew; Zhang, Pengpeng Journal of Physics: Condensed Matter, Vol. 31, Issue 50 https://doi.org/10.1088/1361-648x/ab3c22	journal	September 2019
Experimental molecular adsorption: electronic buffer effect of germanene on Al(1 1 1) Massara, Natalia; Marjaoui, Adil; Stephan, Regis 2D Materials, Vol. 6, Issue 3 https://doi.org/10.1088/2053-1583/ab1601	journal	May 2019
Functional hybrid multilayered van der Waals heterostructures from graphene and self-assembled supramolecular 2D crystals Kalashnyk, Nataliya; Gouesmel, Anaïs; Kim, Eunkyoung 2D Materials, Vol. 6, Issue 4 https://doi.org/10.1088/2053-1583/ab2ba7	journal	July 2019
Asymmetric electric field screening in van der Waals heterostructures Li, Lu Hua; Tian, Tian; Cai, Qiran ETH Zurich https://doi.org/10.3929/ethz-b-000255589	text	January 2018

Similar Records

Enhanced valley splitting of WSe₂ in twisted van der Waals WSe₂/CrI₃ heterostructures

Journal Article · Tue Feb 15 00:00:00 EST 2022 · npj Computational Materials · OSTI ID:1395061

Ge, Mei; Wang, Han; Wu, Jizheng; +3 more

Unraveling the Effect of Stacking Configurations on Charge Transfer in WS ₂ and Organic Semiconductor Heterojunctions

Journal Article · Mon Jun 26 00:00:00 EDT 2023 · Precision Chemistry · OSTI ID:1395061

Zhang, Shuchen; Sun, Dewei; Sun, Jiaonan; +7 more

Unusual exciton–phonon interactions at van der Waals engineered interfaces

Journal Article · Fri Jan 13 00:00:00 EST 2017 · Nano Letters · OSTI ID:1395061

Chow, Colin M.; Yu, Hongyi; Jones, Aaron M.; +6 more

Related Subjects

36 MATERIALS SCIENCE
self-assembly
C60
two-dimensional materials
scanning tunneling microscopy
density functional theory

Title: Rotational superstructure in van der Waals heterostructure of self-assembled C60 monolayer on the WSe2 surface

Citation Formats

References (76)

Cited By (10)

Similar Records

Related Subjects

Title: Rotational superstructure in van der Waals heterostructure of self-assembled C₆₀ monolayer on the WSe₂ surface