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Title: Oxygen Vacancy Linear Clustering in a Perovskite Oxide

Abstract

Oxygen vacancies have been implicitly assumed isolated ones, and understanding oxide materials possibly containing oxygen vacancies remains elusive within the scheme of the isolated vacancies, although the oxygen vacancies have been playing a decisive role in oxide materials. We report the presence of oxygen vacancy linear clusters and their orientation along a specific crystallographic direction in SrTiO 3, a representative of a perovskite oxide. The presence of the linear clusters and associated electron localization was revealed by an electronic structure represented in the increase in the Ti 2+ valence state or corresponding Ti 3d 2 electronic configuration along with divacancy cluster model analysis and transport measurement. The orientation of the linear clusters along the [001] direction in perovskite SrTiO 3 was verified by further X-ray diffuse scattering analysis. And because SrTiO 3 is an archetypical perovskite oxide, the vacancy linear clustering with the specific aligned direction and electron localization can be extended to a wide variety of the perovskite oxides.

Authors:
 [1];  [1];  [1];  [2];  [3]; ORCiD logo [1]
  1. Sungkyunkwan Univ., Suwon (Republic of Korea). School of Advanced Materials Science and Engineering
  2. Seoul National Univ. (Korea, Republic of). Dept. of Materials Science and Engineering
  3. Argonne National Lab. (ANL), Argonne, IL (United States). Advanced Photon Source
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
National Research Foundation of Korea (NRF); USDOE
OSTI Identifier:
1394835
Grant/Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Journal of Physical Chemistry Letters
Additional Journal Information:
Journal Volume: 8; Journal Issue: 15; Journal ID: ISSN 1948-7185
Publisher:
American Chemical Society
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Eom, Kitae, Choi, Euiyoung, Choi, Minsu, Han, Seungwu, Zhou, Hua, and Lee, Jaichan. Oxygen Vacancy Linear Clustering in a Perovskite Oxide. United States: N. p., 2017. Web. doi:10.1021/acs.jpclett.7b01348.
Eom, Kitae, Choi, Euiyoung, Choi, Minsu, Han, Seungwu, Zhou, Hua, & Lee, Jaichan. Oxygen Vacancy Linear Clustering in a Perovskite Oxide. United States. doi:10.1021/acs.jpclett.7b01348.
Eom, Kitae, Choi, Euiyoung, Choi, Minsu, Han, Seungwu, Zhou, Hua, and Lee, Jaichan. Fri . "Oxygen Vacancy Linear Clustering in a Perovskite Oxide". United States. doi:10.1021/acs.jpclett.7b01348. https://www.osti.gov/servlets/purl/1394835.
@article{osti_1394835,
title = {Oxygen Vacancy Linear Clustering in a Perovskite Oxide},
author = {Eom, Kitae and Choi, Euiyoung and Choi, Minsu and Han, Seungwu and Zhou, Hua and Lee, Jaichan},
abstractNote = {Oxygen vacancies have been implicitly assumed isolated ones, and understanding oxide materials possibly containing oxygen vacancies remains elusive within the scheme of the isolated vacancies, although the oxygen vacancies have been playing a decisive role in oxide materials. We report the presence of oxygen vacancy linear clusters and their orientation along a specific crystallographic direction in SrTiO3, a representative of a perovskite oxide. The presence of the linear clusters and associated electron localization was revealed by an electronic structure represented in the increase in the Ti2+ valence state or corresponding Ti 3d2 electronic configuration along with divacancy cluster model analysis and transport measurement. The orientation of the linear clusters along the [001] direction in perovskite SrTiO3 was verified by further X-ray diffuse scattering analysis. And because SrTiO3 is an archetypical perovskite oxide, the vacancy linear clustering with the specific aligned direction and electron localization can be extended to a wide variety of the perovskite oxides.},
doi = {10.1021/acs.jpclett.7b01348},
journal = {Journal of Physical Chemistry Letters},
number = 15,
volume = 8,
place = {United States},
year = {Fri Jul 14 00:00:00 EDT 2017},
month = {Fri Jul 14 00:00:00 EDT 2017}
}

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Cited by: 3 works
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