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Title: Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl

Abstract

To MCoMe reacts rapidly with CO to give a low spin To MCo{C(O)Me}CO species, which is selectively oxygenated to form To MCoOAc.

Authors:
 [1];  [1];  [2];  [1]; ORCiD logo [1]
  1. Iowa State Univ., Ames, IA (United States). Dept. of Chemistry; Ames Lab., Ames, IA (United States)
  2. Iowa State Univ., Ames, IA (United States). Dept. of Chemistry
Publication Date:
Research Org.:
Ames Laboratory (AMES), Ames, IA (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1394815
Report Number(s):
IS-J-9445
Journal ID: ISSN 1359-7345; CHCOFS
Grant/Contract Number:  
AC02-07CH11358
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
ChemComm
Additional Journal Information:
Journal Volume: 53; Journal Issue: 80; Journal ID: ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Reinig, Regina R., Fought, Ellie L., Ellern, Arkady, Windus, Theresa L., and Sadow, Aaron D.. Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl. United States: N. p., 2017. Web. doi:10.1039/C7CC06339C.
Reinig, Regina R., Fought, Ellie L., Ellern, Arkady, Windus, Theresa L., & Sadow, Aaron D.. Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl. United States. doi:10.1039/C7CC06339C.
Reinig, Regina R., Fought, Ellie L., Ellern, Arkady, Windus, Theresa L., and Sadow, Aaron D.. Fri . "Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl". United States. doi:10.1039/C7CC06339C. https://www.osti.gov/servlets/purl/1394815.
@article{osti_1394815,
title = {Rapid and ordered carbonylation and oxygenation of a cobalt(II) methyl},
author = {Reinig, Regina R. and Fought, Ellie L. and Ellern, Arkady and Windus, Theresa L. and Sadow, Aaron D.},
abstractNote = {ToMCoMe reacts rapidly with CO to give a low spin ToMCo{C(O)Me}CO species, which is selectively oxygenated to form ToMCoOAc.},
doi = {10.1039/C7CC06339C},
journal = {ChemComm},
number = 80,
volume = 53,
place = {United States},
year = {Fri Sep 15 00:00:00 EDT 2017},
month = {Fri Sep 15 00:00:00 EDT 2017}
}

Journal Article:
Free Publicly Available Full Text
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Cited by: 1 work
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