Giant magnetoelectric effects achieved by tuning spin cone symmetry in Y-type hexaferrites

doi:https://doi.org/10.1038/s41467-017-00637-x

Title: Giant magnetoelectric effects achieved by tuning spin cone symmetry in Y-type hexaferrites

Abstract

Multiferroics materials, which exhibit coupled magnetic and ferroelectric properties, have attracted tremendous research interest because of their potential in constructing next-generation multifunctional devices. The application of single-phase multiferroics is currently limited by their usually small magnetoelectric effects. Here, we report the realization of giant magnetoelectric effects in a Y-type hexaferrite Ba _0.4Sr _1.6Mg ₂Fe ₁₂O ₂₂ single crystal, which exhibits record-breaking direct and converse magnetoelectric coefficients and a large electric-field-reversed magnetization. We have uncovered the origin of the giant magnetoelectric effects by a systematic study in the Ba _2-x Sr _x Mg ₂Fe ₁₂O ₂₂ family with magnetization, ferroelectricity and neutron diffraction measurements. With the transverse spin cone symmetry restricted to be two-fold, the one-step sharp magnetization reversal is realized and giant magnetoelectric coefficients are achieved. Our study reveals that tuning magnetic symmetry is an effective route to enhance the magnetoelectric effects also in multiferroic hexaferrites.

Authors:

Zhai, Kun ^[1];

^[2]; Shen, Shipeng ^[3]; Tian, Wei ^[2]; Cao, Huibo ^[2]; Chai, Yisheng ^[3]; Chakoumakos, Bryan C. ^[2];

^[3]; Yan, Liqin ^[3]; Wang, Fangwei ^[3];

^[1]

Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics. Inst. of Physics; Univ. of Chinese Academy of Sciences, Beijing (China). School of Physical Science
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Quantum Condensed Matter Division
Chinese Academy of Sciences (CAS), Beijing (China). Beijing National Lab. for Condensed Matter Physics. Inst. of Physics

Publication Date:: 2017-09-12

Research Org.:: Chinese Academy of Sciences (CAS), Beijing (China); Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES); National Key Research and Development Program of China; National Natural Science Foundation of China (NNSFC); Chinese Academy of Sciences (CAS)

OSTI Identifier:: 1394576

Grant/Contract Number:: AC05-00OR22725; 2016YFA0300700; 11534015; 11374347; 11675255; XDB07030200; KJZD-EW-M05

Resource Type:: Journal Article: Accepted Manuscript

Journal Name:: Nature Communications

Additional Journal Information:: Journal Volume: 8; Journal ID: ISSN 2041-1723

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

Subject:: 36 MATERIALS SCIENCE; ferroelectrics and multiferroics; magnetic properties and materials

Citation Formats


                    Zhai, Kun, Wu, Yan, Shen, Shipeng, Tian, Wei, Cao, Huibo, Chai, Yisheng, Chakoumakos, Bryan C., Shang, Dashan, Yan, Liqin, Wang, Fangwei, and Sun, Young. Giant magnetoelectric effects achieved by tuning spin cone symmetry in Y-type hexaferrites.  United States: N. p., 2017. 
        Web.  doi:10.1038/s41467-017-00637-x.

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                    Zhai, Kun, Wu, Yan, Shen, Shipeng, Tian, Wei, Cao, Huibo, Chai, Yisheng, Chakoumakos, Bryan C., Shang, Dashan, Yan, Liqin, Wang, Fangwei, & Sun, Young. Giant magnetoelectric effects achieved by tuning spin cone symmetry in Y-type hexaferrites.  United States.  https://doi.org/10.1038/s41467-017-00637-x

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                    Zhai, Kun, Wu, Yan, Shen, Shipeng, Tian, Wei, Cao, Huibo, Chai, Yisheng, Chakoumakos, Bryan C., Shang, Dashan, Yan, Liqin, Wang, Fangwei, and Sun, Young. Tue .  
        "Giant magnetoelectric effects achieved by tuning spin cone symmetry in Y-type hexaferrites".  United States.  https://doi.org/10.1038/s41467-017-00637-x.  https://www.osti.gov/servlets/purl/1394576.

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@article{osti_1394576,

  title        = {Giant magnetoelectric effects achieved by tuning spin cone symmetry in Y-type hexaferrites},

  author       = {Zhai, Kun and Wu, Yan and Shen, Shipeng and Tian, Wei and Cao, Huibo and Chai, Yisheng and Chakoumakos, Bryan C. and Shang, Dashan and Yan, Liqin and Wang, Fangwei and Sun, Young},

  abstractNote = {Multiferroics materials, which exhibit coupled magnetic and ferroelectric properties, have attracted tremendous research interest because of their potential in constructing next-generation multifunctional devices. The application of single-phase multiferroics is currently limited by their usually small magnetoelectric effects. Here, we report the realization of giant magnetoelectric effects in a Y-type hexaferrite Ba0.4Sr1.6Mg2Fe12O22 single crystal, which exhibits record-breaking direct and converse magnetoelectric coefficients and a large electric-field-reversed magnetization. We have uncovered the origin of the giant magnetoelectric effects by a systematic study in the Ba2-x Sr x Mg2Fe12O22 family with magnetization, ferroelectricity and neutron diffraction measurements. With the transverse spin cone symmetry restricted to be two-fold, the one-step sharp magnetization reversal is realized and giant magnetoelectric coefficients are achieved. Our study reveals that tuning magnetic symmetry is an effective route to enhance the magnetoelectric effects also in multiferroic hexaferrites.},

  doi          = {10.1038/s41467-017-00637-x},

  url          = {https://www.osti.gov/biblio/1394576},
  journal      = {Nature Communications},

  issn         = {2041-1723},

  number       = ,

  volume       = 8,

  place        = {United States},

  year         = {2017},

  month        = {9}

}

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Electromagnon with Sensitive Terahertz Magnetochromism in a Room-Temperature Magnetoelectric Hexaferrite

Journal Article Chun, Sae Hwan ; Shin, Kwang Woo ; Kim, Hyung Joon ; ... - Physical Review Letters

An electromagnon in the magnetoelectric (ME) hexaferrite Ba _0.5Sr _2.5Co ₂Fe ₂₄O ₄₁ (Co ₂ Z-type) single cystal is identified by time-domain terahertz (THz) spectroscopy. The associated THz resonance is active on the electric field (E ^ω) of the THz light parallel to the c axis (∥ [001]), whose spectral weight develops at a markedly high temperature, coinciding with a transverse conical magnetic order below 410 K. The resonance frequency of 1.03 THz at 20 K changes -8.7% and +5.8% under external magnetic field (H) of 2 kOe along [001] and [120], respectively. A model Hamiltonian describing the conical magneticmore »« less
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https://doi.org/10.1103/PhysRevLett.120.027202

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journal, July 2005

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journal, January 2014

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journal, September 2012

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journal, September 2001

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journal, March 2006

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journal, November 2003

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journal, November 2007

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journal, January 2008

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journal, December 2010

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journal, March 2013

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journal, January 2010

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journal, February 2010

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journal, May 2010

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journal, November 2015

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journal, October 1993

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journal, February 2015

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journal, April 2005

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journal, March 2007

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journal, April 1993

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journal, March 2008

Field-induced incommensurate-to-commensurate phase transition in the magnetoelectric hexaferrite Ba $_{0.5}$ Sr $_{1.5}$ Zn $_{2}$ (Fe $_{1 - x}$ Al $_{x}$ ) $_{12}$ O $_{22}$
journal, April 2011

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journal, July 2015

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journal, January 2014

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journal, February 2015

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journal, August 2006

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journal, June 1987

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journal, January 2014

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journal, June 2014

Single-phase multiferroics: new materials, phenomena, and physics
journal, July 2019

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journal, August 2019

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journal, November 2018

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