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Title: Stable isotope analyses of oxygen ( 18O: 17O: 16O) and chlorine ( 37Cl: 35Cl) in perchlorate: reference materials, calibrations, methods, and interferences

Abstract

Perchlorate (ClO 4 -) is a common trace constituent of water, soils, and plants; it has both natural and synthetic sources and is subject to biodegradation. The stable isotope ratios of Cl and O provide three independent quantities for ClO 4 - source attribution and natural attenuation studies: δ 37Cl, δ 18O, and δ 17O (or Δ 17O or 17Δ) values. Finally, documented reference materials, calibration schemes, methods, and interferences will improve the reliability of such studies.

Authors:
 [1];  [1];  [2];  [2];  [3];  [3];  [3]; ORCiD logo [4];  [5]
  1. US Geological Survey, Reston, VA (United States). National Research Program
  2. Univ. of Delaware, Newark, DE (United States). Dept. of Geological Sciences
  3. American Pacific, Cedar City, UT (United States)
  4. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Environmental Sciences Division
  5. CB&I Federal Services, Lawrenceville, NJ (United States). Biotechnology Development and Applications Group
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE; USDOD
OSTI Identifier:
1394542
DOE Contract Number:  
AC05-00OR22725
Resource Type:
Journal Article
Journal Name:
Rapid Communications in Mass Spectrometry
Additional Journal Information:
Journal Volume: 31; Journal Issue: 1; Journal ID: ISSN 0951-4198
Publisher:
Wiley
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats

Böhlke, J. K., Mroczkowski, Stanley J., Sturchio, Neil C., Heraty, Linnea J., Richman, Kent W., Sullivan, Donald B., Griffith, Kris N., Gu, Baohua, and Hatzinger, Paul B. Stable isotope analyses of oxygen (18O:17O:16O) and chlorine (37Cl:35Cl) in perchlorate: reference materials, calibrations, methods, and interferences. United States: N. p., 2016. Web. doi:10.1002/rcm.7751.
Böhlke, J. K., Mroczkowski, Stanley J., Sturchio, Neil C., Heraty, Linnea J., Richman, Kent W., Sullivan, Donald B., Griffith, Kris N., Gu, Baohua, & Hatzinger, Paul B. Stable isotope analyses of oxygen (18O:17O:16O) and chlorine (37Cl:35Cl) in perchlorate: reference materials, calibrations, methods, and interferences. United States. doi:10.1002/rcm.7751.
Böhlke, J. K., Mroczkowski, Stanley J., Sturchio, Neil C., Heraty, Linnea J., Richman, Kent W., Sullivan, Donald B., Griffith, Kris N., Gu, Baohua, and Hatzinger, Paul B. Mon . "Stable isotope analyses of oxygen (18O:17O:16O) and chlorine (37Cl:35Cl) in perchlorate: reference materials, calibrations, methods, and interferences". United States. doi:10.1002/rcm.7751.
@article{osti_1394542,
title = {Stable isotope analyses of oxygen (18O:17O:16O) and chlorine (37Cl:35Cl) in perchlorate: reference materials, calibrations, methods, and interferences},
author = {Böhlke, J. K. and Mroczkowski, Stanley J. and Sturchio, Neil C. and Heraty, Linnea J. and Richman, Kent W. and Sullivan, Donald B. and Griffith, Kris N. and Gu, Baohua and Hatzinger, Paul B.},
abstractNote = {Perchlorate (ClO4-) is a common trace constituent of water, soils, and plants; it has both natural and synthetic sources and is subject to biodegradation. The stable isotope ratios of Cl and O provide three independent quantities for ClO4- source attribution and natural attenuation studies: δ37Cl, δ18O, and δ17O (or Δ17O or 17Δ) values. Finally, documented reference materials, calibration schemes, methods, and interferences will improve the reliability of such studies.},
doi = {10.1002/rcm.7751},
journal = {Rapid Communications in Mass Spectrometry},
issn = {0951-4198},
number = 1,
volume = 31,
place = {United States},
year = {2016},
month = {10}
}

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