Highly efficient conversion of terpenoid biomass to jet-fuel range cycloalkanes in a biphasic tandem catalytic process

doi:10.1039/C7GC00710H

Title: Highly efficient conversion of terpenoid biomass to jet-fuel range cycloalkanes in a biphasic tandem catalytic process

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Abstract

The demand for bio-jet fuels to reduce carbon emissions is increasing substantially in the aviation sector, while the scarcity of high-density jet fuel components limits the use of bio-jet fuels in high-performance aircrafts compared with conventional jet fuels. In this paper, we report a novel biphasic tandem catalytic process (biTCP) for synthesizing cycloalkanes from renewable terpenoid biomass, such as 1,8-cineole. Multistep tandem reactions, including C–O ring opening by hydrolysis, dehydration, and hydrogenation, were carried out in the “one-pot” biTCP. 1,8-Cineole was efficiently converted to p-menthane at high yields (>99%) in the biTCP under mild reaction conditions. Finally, the catalytic reaction mechanism is discussed.

Authors:

; Li, Teng ^[2]; Tang, Kan ^[2]; Zhou, Xinpei ^[1]; Lu, Mi ^[1]; Ounkham, Whalmany L. ^[1]; Spain, Stephen M. ^[1]; Frost, Brian J. ^[1];

Univ. of Nevada, Reno, NV (United States)
Washington State Univ., Pullman, WA (United States)

Publication Date:: Mon Jun 12 00:00:00 EDT 2017

Research Org.:: Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)

Sponsoring Org.:: USDOE Office of Energy Efficiency and Renewable Energy (EERE), Bioenergy Technologies Office (EE-3B)

OSTI Identifier:: 1394368

DOE Contract Number:: AC05-00OR22725

Resource Type:: Journal Article

Resource Relation:: Journal Name: Green Chemistry; Journal Volume: 19; Journal Issue: 15

Country of Publication:: United States

Language:: English

Subject:: 37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY

Citation Formats


                    Yang, Xiaokun, Li, Teng, Tang, Kan, Zhou, Xinpei, Lu, Mi, Ounkham, Whalmany L., Spain, Stephen M., Frost, Brian J., and Lin, Hongfei. Highly efficient conversion of terpenoid biomass to jet-fuel range cycloalkanes in a biphasic tandem catalytic process.  United States: N. p., 2017. 
        Web.  doi:10.1039/C7GC00710H.

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                    Yang, Xiaokun, Li, Teng, Tang, Kan, Zhou, Xinpei, Lu, Mi, Ounkham, Whalmany L., Spain, Stephen M., Frost, Brian J., & Lin, Hongfei. Highly efficient conversion of terpenoid biomass to jet-fuel range cycloalkanes in a biphasic tandem catalytic process.  United States.  doi:10.1039/C7GC00710H.

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                    Yang, Xiaokun, Li, Teng, Tang, Kan, Zhou, Xinpei, Lu, Mi, Ounkham, Whalmany L., Spain, Stephen M., Frost, Brian J., and Lin, Hongfei. Mon .  
        "Highly efficient conversion of terpenoid biomass to jet-fuel range cycloalkanes in a biphasic tandem catalytic process".  United States.  
        doi:10.1039/C7GC00710H.

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@article{osti_1394368,

  title        = {Highly efficient conversion of terpenoid biomass to jet-fuel range cycloalkanes in a biphasic tandem catalytic process},

  author       = {Yang, Xiaokun and Li, Teng and Tang, Kan and Zhou, Xinpei and Lu, Mi and Ounkham, Whalmany L. and Spain, Stephen M. and Frost, Brian J. and Lin, Hongfei},

  abstractNote = {The demand for bio-jet fuels to reduce carbon emissions is increasing substantially in the aviation sector, while the scarcity of high-density jet fuel components limits the use of bio-jet fuels in high-performance aircrafts compared with conventional jet fuels. In this paper, we report a novel biphasic tandem catalytic process (biTCP) for synthesizing cycloalkanes from renewable terpenoid biomass, such as 1,8-cineole. Multistep tandem reactions, including C–O ring opening by hydrolysis, dehydration, and hydrogenation, were carried out in the “one-pot” biTCP. 1,8-Cineole was efficiently converted to p-menthane at high yields (>99%) in the biTCP under mild reaction conditions. Finally, the catalytic reaction mechanism is discussed.},

  doi          = {10.1039/C7GC00710H},

  journal      = {Green Chemistry},

  number       = 15,

  volume       = 19,

  place        = {United States},

  year         = {Mon Jun 12 00:00:00 EDT 2017},

  month        = {Mon Jun 12 00:00:00 EDT 2017}

}

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DOI: 10.1039/C7GC00710H

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