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Title: Ab initio study of cross-interface electron-phonon couplings in FeSe thin films on SrTiO 3 and BaTiO 3

Abstract

We study the electron-phonon coupling strength near the interface of monolayer and bilayer FeSe thin films on SrTiO 3 , BaTiO 3 , and oxygen-vacant SrTiO 3 substrates, using ab initio methods. The calculated total electron-phonon coupling strength λ = 0.2 – 0.3 cannot account for the high T c ~ 70 K observed in these systems through the conventional phonon-mediated pairing mechanism. In all of these systems, however, we find that the coupling constant of a polar oxygen branch peaks at q = 0 with negligible coupling elsewhere, while the energy of this mode coincides with the offset energy of the replica bands measured recently by angle-resolved photoemission spectroscopy experiments. However, the integrated coupling strength for this mode from our current calculations is still too small to produce the observed high T c , even through the more efficient pairing mechanism provided by the forward scattering. Also, we arrive at the same qualitative conclusion when considering a checkerboard antiferromagnetic configuration in the Fe layer. In light of the experimental observations of the replica band feature and the relatively high T c of FeSe monolayers on polar substrates, our results point towards a cooperative role for the electron-phonon interaction, wheremore » the cross-interface interaction acts in conjunction with a purely electronic interaction. Finally, we discuss a few scenarios where the coupling strength obtained here may be enhanced.« less

Authors:
 [1];  [2]; ORCiD logo [3];  [1]
  1. Univ. of Tennessee, Knoxville, TN (United States). Dept. of Physics and Astronomy
  2. Univ. of Florida, Gainesville, FL (United States). Dept. of Physics
  3. Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States). Center for Nanophase Materials Sciences, Computer Science and Mathematics Division
Publication Date:
Research Org.:
Oak Ridge National Lab. (ORNL), Oak Ridge, TN (United States)
Sponsoring Org.:
USDOE Office of Science (SC)
OSTI Identifier:
1393894
Alternate Identifier(s):
OSTI ID: 1249680
Grant/Contract Number:  
AC05-00OR22725; FG02-05ER46236
Resource Type:
Journal Article: Accepted Manuscript
Journal Name:
Physical Review B
Additional Journal Information:
Journal Volume: 93; Journal Issue: 13; Journal ID: ISSN 2469-9950
Publisher:
American Physical Society (APS)
Country of Publication:
United States
Language:
English
Subject:
75 CONDENSED MATTER PHYSICS, SUPERCONDUCTIVITY AND SUPERFLUIDITY

Citation Formats

Wang, Y., Linscheid, A., Berlijn, T., and Johnston, S. Ab initio study of cross-interface electron-phonon couplings in FeSe thin films on SrTiO3 and BaTiO3. United States: N. p., 2016. Web. doi:10.1103/PhysRevB.93.134513.
Wang, Y., Linscheid, A., Berlijn, T., & Johnston, S. Ab initio study of cross-interface electron-phonon couplings in FeSe thin films on SrTiO3 and BaTiO3. United States. doi:10.1103/PhysRevB.93.134513.
Wang, Y., Linscheid, A., Berlijn, T., and Johnston, S. Fri . "Ab initio study of cross-interface electron-phonon couplings in FeSe thin films on SrTiO3 and BaTiO3". United States. doi:10.1103/PhysRevB.93.134513. https://www.osti.gov/servlets/purl/1393894.
@article{osti_1393894,
title = {Ab initio study of cross-interface electron-phonon couplings in FeSe thin films on SrTiO3 and BaTiO3},
author = {Wang, Y. and Linscheid, A. and Berlijn, T. and Johnston, S.},
abstractNote = {We study the electron-phonon coupling strength near the interface of monolayer and bilayer FeSe thin films on SrTiO 3 , BaTiO 3 , and oxygen-vacant SrTiO 3 substrates, using ab initio methods. The calculated total electron-phonon coupling strength λ = 0.2 – 0.3 cannot account for the high T c ~ 70 K observed in these systems through the conventional phonon-mediated pairing mechanism. In all of these systems, however, we find that the coupling constant of a polar oxygen branch peaks at q = 0 with negligible coupling elsewhere, while the energy of this mode coincides with the offset energy of the replica bands measured recently by angle-resolved photoemission spectroscopy experiments. However, the integrated coupling strength for this mode from our current calculations is still too small to produce the observed high T c , even through the more efficient pairing mechanism provided by the forward scattering. Also, we arrive at the same qualitative conclusion when considering a checkerboard antiferromagnetic configuration in the Fe layer. In light of the experimental observations of the replica band feature and the relatively high T c of FeSe monolayers on polar substrates, our results point towards a cooperative role for the electron-phonon interaction, where the cross-interface interaction acts in conjunction with a purely electronic interaction. Finally, we discuss a few scenarios where the coupling strength obtained here may be enhanced.},
doi = {10.1103/PhysRevB.93.134513},
journal = {Physical Review B},
number = 13,
volume = 93,
place = {United States},
year = {Fri Apr 22 00:00:00 EDT 2016},
month = {Fri Apr 22 00:00:00 EDT 2016}
}

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Works referenced in this record:

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EPW: A program for calculating the electron–phonon coupling using maximally localized Wannier functions
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