Quantitatively in Situ Imaging Silver Nanowire Hollowing Kinetics

Yu, Le; Yan, Zhongying; Cai, Zhonghou; Zhang, Dongtang; Han, Ping; Cheng, Xuemei; Sun, Yugang

doi:10.1021/acs.nanolett.6b03218

Title: Quantitatively in Situ Imaging Silver Nanowire Hollowing Kinetics

Journal Article · Wed Sep 28 00:00:00 EDT 2016 · Nano Letters

DOI:https://doi.org/10.1021/acs.nanolett.6b03218· OSTI ID:1393205

Yu, Le ^[1]; Yan, Zhongying ^[2]; Cai, Zhonghou ^[3]; Zhang, Dongtang ^[4]; Han, Ping ^[5]; Cheng, Xuemei ^[2]; Sun, Yugang ^[4]

Nanjing Univ., Jiangsu (China); Bryn Mawr College, Bryn Mawr, PA (United States)
Bryn Mawr College, Bryn Mawr, PA (United States)
Argonne National Lab. (ANL), Argonne, IL (United States)
Temple Univ., Philadelphia, PA (United States)
Nanjing Univ., Jiangsu (China)

We report the in-situ investigation of the morphological evolution of silver nanowires to hollow silver oxide nanotubes using transmission x-ray microscopy (TXM). Complex silver diffusion kinetics and hollowing process via the Kirkendall effect have been captured in real time. Further quantitative x-ray absorption analysis reveals the difference between the longitudinal and radial diffusions. In conclusion, the diffusion coefficient of silver in its oxide nanoshell is, for the first time, calculated to be 1.2 × 10^-13 cm²/s from the geometrical parameters extracted from the TXM images.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: Temple University; China Scholarship Council; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Scientific User Facilities Division

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1393205

Journal Information:: Nano Letters, Vol. 16, Issue 10; ISSN 1530-6984

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 19 works

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Formation of hierarchical porosity in oxidation of Ag films by reactive sputtering deposition of metal oxides via the Kirkendall effect Xu, W.; Li, C. X.; Zhang, Q. Y. Nanoscale, Vol. 11, Issue 20 https://doi.org/10.1039/c9nr00678h	journal	January 2019
In Situ Observation of Dynamic Galvanic Replacement Reactions in Twinned Metallic Nanowires by Liquid Cell Transmission Electron Microscopy Zhuang, Chunqiang; Qi, Heyang; Cheng, Xing Angewandte Chemie, Vol. 131, Issue 51 https://doi.org/10.1002/ange.201910379	journal	November 2019
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36 MATERIALS SCIENCE
Kirkendall effect
diffusion coefficient
nanotubes
silver nanowire
transmission x-ray microscopy
void formation

Title: Quantitatively in Situ Imaging Silver Nanowire Hollowing Kinetics

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