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Title: Hydrophobic pillared square grids for selective removal of CO 2 from simulated flue gas

Journal Article · · ChemComm
DOI:https://doi.org/10.1039/c5cc06577a· OSTI ID:1392948
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Capture of CO2 from flue gas is considered to be a feasible approach to mitigate the effects of anthropogenic emission of CO2. Herein we report that an isostructural family of metal organic materials (MOMs) of general formula [M(linker)(2)(pillar)], linker = pyrazine, pillar = hexaflourosilicate and M = Zn, Cu, Ni and Co exhibits highly selective removal of CO2 fromdry and wet simulated flue gas. Two members of the family, M = Ni and Co, SIFSIX-3-Ni and SIFSIX-3-Co, respectively, are reported for the first time and compared with the previously reported Zn and Cu analogs.

Research Organization:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES); USDOE Office of Science - Office of Basic Energy Sciences - Materials Sciences and Engineering Division
DOE Contract Number:
AC02-06CH11357
OSTI ID:
1392948
Journal Information:
ChemComm, Vol. 51, Issue 85; ISSN 1359-7345
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

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