Molecular Engineering toward Stabilized Interface: An Electrolyte Additive for High-Performance Li-Ion Battery

Zhang, Lu; Huang, Jinhua; Youssef, Kyrrilos; Redfern, Paul C.; Curtiss, Larry A.; Amine, Khalil; Zhang, Zhengcheng

doi:10.1149/2.0971414jes

Title: Molecular Engineering toward Stabilized Interface: An Electrolyte Additive for High-Performance Li-Ion Battery

Journal Article · Fri Oct 31 00:00:00 EDT 2014 · Journal of the Electrochemical Society

DOI:https://doi.org/10.1149/2.0971414jes· OSTI ID:1392637

Zhang, Lu ^[1]; Huang, Jinhua ^[1]; Youssef, Kyrrilos ^[1]; Redfern, Paul C. ^[1]; Curtiss, Larry A. ^[1]; Amine, Khalil ^[1]; Zhang, Zhengcheng ^[1]

Argonne National Lab. (ANL), Argonne, IL (United States)

A novel electrolyte additive, 3-oxabicyclo[3.1.0]hexane-2,4-dione (OHD), has been discovered and evaluated in Li-_1.1(Mn_1/3Ni_1/3Co_1/3)_0.9O₂/graphite cells under elevated temperature. When an appropriate amount of OHD is used, the cell capacity retention is improved from 60% (Gen 2 electrolyte alone) to 82% (Gen 2 electrolyte plus OHD) after 200 cycles with no obvious impedance increase. The amount of OHD added is the key to achieving the superior cell performance. In conclusion, the effect of OHD additive was investigated by means of electrochemical analysis, fourier transform infrared spectroscopy, scanning electron microscopy, and density functional theory computation.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22), Joint Center for Energy Storage Research (JCESR); USDOE Office of Energy Efficiency and Renewable Energy (EERE), Vehicle Technologies Office (EE-3V)

Grant/Contract Number:: AC02-06CH11357

OSTI ID:: 1392637

Journal Information:: Journal of the Electrochemical Society, Vol. 161, Issue 14; ISSN 0013-4651

Publisher:: The Electrochemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

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Cited by: 9 works

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Review on modeling of the anode solid electrolyte interphase (SEI) for lithium-ion batteries Wang, Aiping; Kadam, Sanket; Li, Hong npj Computational Materials, Vol. 4, Issue 1 https://doi.org/10.1038/s41524-018-0064-0	journal	March 2018
An organophosphine oxide redox shuttle additive that delivers long-term overcharge protection for 4 V lithium-ion batteries Huang, Jinhua; Azimi, Nasim; Cheng, Lei Journal of Materials Chemistry A, Vol. 3, Issue 20 https://doi.org/10.1039/c5ta01326g	journal	January 2015

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25 ENERGY STORAGE
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electrolyte additive
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molecular engineering
surface characterization

Title: Molecular Engineering toward Stabilized Interface: An Electrolyte Additive for High-Performance Li-Ion Battery

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