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Title: MIL-101(Fe) as a lithium-ion battery electrode material: a relaxation and intercalation mechanism during lithium insertion

Abstract

The electrochemical performance and mechanism of a MIL-101(Fe) metal–organic framework (MOF) as a lithium ion battery electrode is reported for the first time.

Authors:
 [1];  [2];  [2];  [1];  [3];  [1];  [2];  [2];  [1]
  1. Department of Nanoengineering; University of California; La Jolla, USA
  2. Department of Chemistry and Biochemistry; University of California; La Jolla, USA
  3. X-ray Science Division; Advanced Photon Source; Argonne National Laboratory; Argonne, USA
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1392541
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 3; Journal Issue: 8; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
Density Functional Theory; Electronic structure; Lithium ion battery; X - ray absorption spectroscopy; metal - organic framework; powder X - ray diffraction; synchrotron

Citation Formats

Shin, JaeWook, Kim, Min, Cirera, Jordi, Chen, Shawn, Halder, Gregory J., Yersak, Thomas A., Paesani, Francesco, Cohen, Seth M., and Meng, Ying Shirley. MIL-101(Fe) as a lithium-ion battery electrode material: a relaxation and intercalation mechanism during lithium insertion. United States: N. p., 2015. Web. doi:10.1039/c4ta06694d.
Shin, JaeWook, Kim, Min, Cirera, Jordi, Chen, Shawn, Halder, Gregory J., Yersak, Thomas A., Paesani, Francesco, Cohen, Seth M., & Meng, Ying Shirley. MIL-101(Fe) as a lithium-ion battery electrode material: a relaxation and intercalation mechanism during lithium insertion. United States. doi:10.1039/c4ta06694d.
Shin, JaeWook, Kim, Min, Cirera, Jordi, Chen, Shawn, Halder, Gregory J., Yersak, Thomas A., Paesani, Francesco, Cohen, Seth M., and Meng, Ying Shirley. Thu . "MIL-101(Fe) as a lithium-ion battery electrode material: a relaxation and intercalation mechanism during lithium insertion". United States. doi:10.1039/c4ta06694d.
@article{osti_1392541,
title = {MIL-101(Fe) as a lithium-ion battery electrode material: a relaxation and intercalation mechanism during lithium insertion},
author = {Shin, JaeWook and Kim, Min and Cirera, Jordi and Chen, Shawn and Halder, Gregory J. and Yersak, Thomas A. and Paesani, Francesco and Cohen, Seth M. and Meng, Ying Shirley},
abstractNote = {The electrochemical performance and mechanism of a MIL-101(Fe) metal–organic framework (MOF) as a lithium ion battery electrode is reported for the first time.},
doi = {10.1039/c4ta06694d},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 8,
volume = 3,
place = {United States},
year = {2015},
month = {1}
}

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