Linking Group Influences Charge Separation and Recombination in All-Conjugated Block Copolymer Photovoltaics

Mok, Jorge W.; Lin, Yen-Hao; Yager, Kevin G.; Mohite, Aditya D.; Nie, Wanyi; Darling, Seth B.; Lee, Youngmin; Gomez, Enrique; Gosztola, David; Schaller, Richard D.; Verduzco, Rafael

doi:10.1002/adfm.201502623

Title: Linking Group Influences Charge Separation and Recombination in All-Conjugated Block Copolymer Photovoltaics

Journal Article · Mon Aug 10 00:00:00 EDT 2015 · Advanced Functional Materials

DOI:https://doi.org/10.1002/adfm.201502623· OSTI ID:1392436

Mok, Jorge W. ^[1]; Lin, Yen-Hao ^[1]; Yager, Kevin G. ^[2]; Mohite, Aditya D. ^[3]; Nie, Wanyi ^[3]; Darling, Seth B. ^[4]; Lee, Youngmin ^[5]; Gomez, Enrique ^[5]; Gosztola, David ^[6]; Schaller, Richard D. ^[7]; Verduzco, Rafael ^[8]

Department of Chemical and Biomolecular Engineering, Rice University, Houston TX 77005 USA
Center for Functional Nanomaterials, Brookhaven National Laboratory, Upton NY 11973 USA
Center for Integrated Nanotechnologies Materials Physics and Applications Division, Los Alamos National Laboratory, Los Alamos NM 87545 USA
Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439 USA; Institute for Molecular Engineering, The University of Chicago, Chicago IL 60637 USA
Department of Chemical Engineering, The Pennsylvania State University, University Park, PA 16802 USA
Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439 USA
Center for Nanoscale Materials, Argonne National Laboratory, Argonne IL 60439 USA; Department of Chemistry, Northwestern University, Evanston IL 60208 USA
Department of Chemical and Biomolecular Engineering, Rice University, Houston TX 77005 USA; Department of Materials Science and NanoEngineering, Rice University, Houston TX 77005 USA

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES); US Department of the Navy, Office of Naval Research (ONR); National Science Foundation (NSF)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1392436

Journal Information:: Advanced Functional Materials, Vol. 25, Issue 35; ISSN 1616-301X

Publisher:: Wiley

Country of Publication:: United States

Language:: English

References (34)

25th Anniversary Article: No Assembly Required: Recent Advances in Fully Conjugated Block Copolymers Robb, Maxwell J.; Ku, Sung-Yu; Hawker, Craig J. Advanced Materials, Vol. 25, Issue 40 https://doi.org/10.1002/adma.201302677	journal	September 2013
Subnanosecond Geminate Charge Recombination in Polymer-Polymer Photovoltaic Devices Hodgkiss, Justin M.; Campbell, Andrew R.; Marsh, R. Alex Physical Review Letters, Vol. 104, Issue 17 https://doi.org/10.1103/PhysRevLett.104.177701	journal	April 2010
Polymer Blend Solar Cells Based on a High-Mobility Naphthalenediimide-Based Polymer Acceptor: Device Physics, Photophysics and Morphology Moore, Jennifer R.; Albert-Seifried, Sebastian; Rao, Akshay Advanced Energy Materials, Vol. 1, Issue 2 https://doi.org/10.1002/aenm.201000035	journal	February 2011
Determining the Role of Polymer Molecular Weight for High-Performance All-Polymer Solar Cells: Its Effect on Polymer Aggregation and Phase Separation Kang, Hyunbum; Uddin, Mohammad Afsar; Lee, Changyeon Journal of the American Chemical Society, Vol. 137, Issue 6 https://doi.org/10.1021/ja5123182	journal	February 2015
Ultrafast Exciton Dissociation Followed by Nongeminate Charge Recombination in PCDTBT:PCBM Photovoltaic Blends Etzold, Fabian; Howard, Ian A.; Mauer, Ralf Journal of the American Chemical Society, Vol. 133, Issue 24 https://doi.org/10.1021/ja201837e	journal	June 2011
Conjugated-Polymer Blends for Optoelectronics McNeill, Christopher R.; Greenham, Neil C. Advanced Materials, Vol. 21, Issue 38â39 https://doi.org/10.1002/adma.200900783	journal	October 2009
Role of Structural Order and Excess Energy on Ultrafast Free Charge Generation in Hybrid Polythiophene/Si Photovoltaics Probed in Real Time by Near-Infrared Broadband Transient Absorption Herrmann, Daniel; Niesar, Sabrina; Scharsich, Christina Journal of the American Chemical Society, Vol. 133, Issue 45 https://doi.org/10.1021/ja207887q	journal	November 2011
Dual electron donor/electron acceptor character of a conjugated polymer in efficient photovoltaic diodes McNeill, Christopher R.; Abrusci, Agnese; Zaumseil, Jana Applied Physics Letters, Vol. 90, Issue 19 https://doi.org/10.1063/1.2738197	journal	May 2007
Tracing photoinduced electron transfer process in conjugated polymer/fullerene bulk heterojunctions in real time Brabec, Christoph J.; Zerza, Gerald; Cerullo, Giulio Chemical Physics Letters, Vol. 340, Issue 3-4 https://doi.org/10.1016/S0009-2614(01)00431-6	journal	June 2001
Thermally Stable, Efficient Polymer Solar Cells with Nanoscale Control of the Interpenetrating Network Morphology Ma, W.; Yang, C.; Gong, X. Advanced Functional Materials, Vol. 15, Issue 10, p. 1617-1622 https://doi.org/10.1002/adfm.200500211	journal	October 2005
Polymer/Polymer Blend Solar Cells Improved by Using High-Molecular-Weight Fluorene-Based Copolymer as Electron Acceptor Mori, Daisuke; Benten, Hiroaki; Ohkita, Hideo ACS Applied Materials & Interfaces, Vol. 4, Issue 7, p. 3325-3329 https://doi.org/10.1021/am300623f	journal	June 2012
Effect of Annealing on P3HT:PCBM Charge Transfer and Nanoscale Morphology Probed by Ultrafast Spectroscopy Marsh, R. Alex; Hodgkiss, Justin M.; Albert-Seifried, Sebastian Nano Letters, Vol. 10, Issue 3 https://doi.org/10.1021/nl9038289	journal	March 2010
Rod–coil and all-conjugated block copolymers for photovoltaic applications Yassar, Abderrahim; Miozzo, Luciano; Gironda, Ramona Progress in Polymer Science, Vol. 38, Issue 5 https://doi.org/10.1016/j.progpolymsci.2012.10.001	journal	May 2013
Synthesis and crystallinity of all-conjugated poly(3-hexylthiophene) block copolymers Lin, Yen-Hao; Smith, Kendall A.; Kempf, Chloe N. Polym. Chem., Vol. 4, Issue 2 https://doi.org/10.1039/C2PY20830J	journal	January 2013
Supramolecular Conjugated Block Copolymers Lin, Yen-Hao; Darling, Seth B.; Nikiforov, Maxim P. Macromolecules, Vol. 45, Issue 16 https://doi.org/10.1021/ma300829u	journal	July 2012
Photoinduced Carrier Generation in P3HT/PCBM Bulk Heterojunction Materials Hwang, In-Wook; Moses, Daniel; Heeger, Alan J. The Journal of Physical Chemistry C, Vol. 112, Issue 11 https://doi.org/10.1021/jp075565x	journal	February 2008
High-Performance All-Polymer Solar Cells Based on Face-On Stacked Polymer Blends with Low Interfacial Tension Kang, Hyunbum; Kim, Ki-Hyun; Choi, Joonhyeong ACS Macro Letters, Vol. 3, Issue 10 https://doi.org/10.1021/mz500415a	journal	September 2014
Morphology characterization in organic and hybrid solar cells Chen, Wei; Nikiforov, Maxim P.; Darling, Seth B. Energy & Environmental Science, Vol. 5, Issue 8 https://doi.org/10.1039/c2ee22056c	journal	January 2012
Ternary Photovoltaic Blends Incorporating an All-Conjugated Donor–Acceptor Diblock Copolymer Mulherin, Rhiannon C.; Jung, Stefan; Huettner, Sven Nano Letters, Vol. 11, Issue 11 https://doi.org/10.1021/nl202691n	journal	November 2011
Charge Photogeneration in Organic Solar Cells Clarke, Tracey M.; Durrant, James R. Chemical Reviews, Vol. 110, Issue 11, p. 6736-6767 https://doi.org/10.1021/cr900271s	journal	November 2010
Control of Intrachain Charge Transfer in Model Systems for Block Copolymer Photovoltaic Materials Johnson, Kerr; Huang, Ya-Shih; Huettner, Sven Journal of the American Chemical Society, Vol. 135, Issue 13 https://doi.org/10.1021/ja3121247	journal	March 2013
Detection and role of trace impurities in high-performance organic solar cells Nikiforov, Maxim P.; Lai, Barry; Chen, Wei Energy & Environmental Science, Vol. 6, Issue 5 https://doi.org/10.1039/c3ee40556g	journal	January 2013
For the Bright Future-Bulk Heterojunction Polymer Solar Cells with Power Conversion Efficiency of 7.4% Liang, Yongye; Xu, Zheng; Xia, Jiangbin Advanced Materials, Vol. 22, Issue 20, p. E135-E138 https://doi.org/10.1002/adma.200903528	journal	May 2010
Phase Separation in Polyfluorene-Based Conjugated Polymer Blends: Lateral and Vertical Analysis of Blend Spin-Cast Thin Films Kim, Ji-Seon; Ho, Peter K. H.; Murphy, Craig E. Macromolecules, Vol. 37, Issue 8 https://doi.org/10.1021/ma035750i	journal	April 2004
Influence of Nanoscale Phase Separation on the Charge Generation Dynamics and Photovoltaic Performance of Conjugated Polymer Blends: Balancing Charge Generation and Separation McNeill, Christopher R.; Westenhoff, Sebastian; Groves, Chris The Journal of Physical Chemistry C, Vol. 111, Issue 51 https://doi.org/10.1021/jp075904m	journal	December 2007
Nanostructured Surfaces Frustrate Polymer Semiconductor Molecular Orientation Johnston, Danvers E.; Yager, Kevin G.; Hlaing, Htay ACS Nano, Vol. 8, Issue 1 https://doi.org/10.1021/nn4060539	journal	December 2013
Block copolymers for photovoltaics Darling, Seth B. Energy & Environmental Science, Vol. 2, Issue 12 https://doi.org/10.1039/b912086f	journal	January 2009
Separating Charges at Organic Interfaces: Effects of Disorder, Hot States, and Electric Field Nayak, Pabitra K.; Narasimhan, K. L.; Cahen, David The Journal of Physical Chemistry Letters, Vol. 4, Issue 10 https://doi.org/10.1021/jz4002339	journal	May 2013
High Performance All-Polymer Solar Cell via Polymer Side-Chain Engineering Zhou, Yan; Kurosawa, Tadanori; Ma, Wei Advanced Materials, Vol. 26, Issue 22 https://doi.org/10.1002/adma.201306242	journal	March 2014
Controlling Molecular Weight of a High Efficiency Donor-Acceptor Conjugated Polymer and Understanding Its Significant Impact on Photovoltaic Properties Li, Wentao; Yang, Liqiang; Tumbleston, John R. Advanced Materials, Vol. 26, Issue 26 https://doi.org/10.1002/adma.201305251	journal	March 2014
Conjugated Block Copolymer Photovoltaics with near 3% Efficiency through Microphase Separation Guo, Changhe; Lin, Yen-Hao; Witman, Matthew D. Nano Letters, Vol. 13, Issue 6 https://doi.org/10.1021/nl401420s	journal	May 2013
Excitation Transport and Charge Separation in an Organic Photovoltaic Material: Watching Excitations Diffuse to Interfaces Barbour, Larry W.; Pensack, Ryan D.; Hegadorn, Maureen The Journal of Physical Chemistry C, Vol. 112, Issue 10 https://doi.org/10.1021/jp0759628	journal	March 2008
Charge Generation and Recombination Dynamics in Poly(3-hexylthiophene)/Fullerene Blend Films with Different Regioregularities and Morphologies Guo, Jiamo; Ohkita, Hideo; Benten, Hiroaki Journal of the American Chemical Society, Vol. 132, Issue 17 https://doi.org/10.1021/ja100302p	journal	May 2010
Confinement-Driven Increase in Ionomer Thin-Film Modulus Page, Kirt A.; Kusoglu, Ahmet; Stafford, Christopher M. Nano Letters, Vol. 14, Issue 5 https://doi.org/10.1021/nl501233g	journal	April 2014

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