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Title: The migration mechanism of transition metal ions in LiNi 0.5 Mn 1.5 O 4

Abstract

In situhigh-energy X-ray diffraction and neutron diffraction were deployed to trace the migration of transition metal ions in LiNi 0.5Mn 1.5O 4.

Authors:
 [1];  [1];  [2];  [3];  [3];  [1];  [1]
  1. Chemical Sciences and Engineering Division; Argonne National Laboratory; Lemont, USA
  2. X-ray Science Division; Argonne National Laboratory; Lemont, USA
  3. Chemical and Engineering Materials Division; Spallation Neutron Source; Oak Ridge National Laboratory; Oak Ridge, USA
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE) - Office of Vehicle Technology; USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1392431
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 3; Journal Issue: 24; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

Citation Formats

Xu, Gui-Liang, Qin, Yan, Ren, Yang, Cai, Lu, An, Ke, Amine, Khalil, and Chen, Zonghai. The migration mechanism of transition metal ions in LiNi 0.5 Mn 1.5 O 4. United States: N. p., 2015. Web. doi:10.1039/C5TA02522B.
Xu, Gui-Liang, Qin, Yan, Ren, Yang, Cai, Lu, An, Ke, Amine, Khalil, & Chen, Zonghai. The migration mechanism of transition metal ions in LiNi 0.5 Mn 1.5 O 4. United States. doi:10.1039/C5TA02522B.
Xu, Gui-Liang, Qin, Yan, Ren, Yang, Cai, Lu, An, Ke, Amine, Khalil, and Chen, Zonghai. Thu . "The migration mechanism of transition metal ions in LiNi 0.5 Mn 1.5 O 4". United States. doi:10.1039/C5TA02522B.
@article{osti_1392431,
title = {The migration mechanism of transition metal ions in LiNi 0.5 Mn 1.5 O 4},
author = {Xu, Gui-Liang and Qin, Yan and Ren, Yang and Cai, Lu and An, Ke and Amine, Khalil and Chen, Zonghai},
abstractNote = {In situhigh-energy X-ray diffraction and neutron diffraction were deployed to trace the migration of transition metal ions in LiNi0.5Mn1.5O4.},
doi = {10.1039/C5TA02522B},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 24,
volume = 3,
place = {United States},
year = {2015},
month = {1}
}

Works referenced in this record:

Lithium Batteries and Cathode Materials
journal, October 2004

  • Whittingham, M. Stanley
  • Chemical Reviews, Vol. 104, Issue 10, p. 4271-4302
  • DOI: 10.1021/cr020731c

Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides
journal, September 1976


First In Situ Lattice Strains Measurements Under Load at VULCAN
journal, October 2010

  • An, Ke; Skorpenske, Harley D.; Stoica, Alexandru D.
  • Metallurgical and Materials Transactions A, Vol. 42, Issue 1
  • DOI: 10.1007/s11661-010-0495-9

Mitigating Voltage Fade in Cathode Materials by Improving the Atomic Level Uniformity of Elemental Distribution
journal, April 2014

  • Zheng, Jianming; Gu, Meng; Genc, Arda
  • Nano Letters, Vol. 14, Issue 5
  • DOI: 10.1021/nl500486y

Comments on the structural complexity of lithium-rich Li1+xM1−xO2 electrodes (M=Mn, Ni, Co) for lithium batteries
journal, September 2006

  • Thackeray, M. M.; Kang, S.-H.; Johnson, C. S.
  • Electrochemistry Communications, Vol. 8, Issue 9, p. 1531-1538
  • DOI: 10.1016/j.elecom.2006.06.030

Electronic properties of transition-metal oxides—I
journal, January 1957


Recent Advances in First Principles Computational Research of Cathode Materials for Lithium-Ion Batteries
journal, April 2012

  • Meng, Ying Shirley; Arroyo-de Dompablo, M. Elena
  • Accounts of Chemical Research, Vol. 46, Issue 5
  • DOI: 10.1021/ar2002396

Unraveling structural evolution of LiNi0.5Mn1.5O4 by in situ neutron diffraction
journal, January 2013

  • Cai, Lu; Liu, Zengcai; An, Ke
  • Journal of Materials Chemistry A, Vol. 1, Issue 23
  • DOI: 10.1039/c3ta00145h

Single-Crystalline LiMn2O4 Nanotubes Synthesized Via Template-Engaged Reaction as Cathodes for High-Power Lithium Ion Batteries
journal, November 2010

  • Ding, Yuan-Li; Xie, Jian; Cao, Gao-Shao
  • Advanced Functional Materials, Vol. 21, Issue 2
  • DOI: 10.1002/adfm.201001448

A comparative study of Fd-3m and P4332 “LiNi0.5Mn1.5O4”
journal, June 2011


Origin of voltage decay in high-capacity layered oxide electrodes
journal, December 2014

  • Sathiya, M.; Abakumov, A. M.; Foix, D.
  • Nature Materials, Vol. 14, Issue 2
  • DOI: 10.1038/nmat4137

A comparison of destabilization mechanisms of the layered NaxMO2 and LixMO2 compounds upon alkali de-intercalation
journal, January 2012

  • Kim, Sangtae; Ma, Xiaohua; Ong, Shyue Ping
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 44
  • DOI: 10.1039/c2cp43377j

Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density
journal, January 2013

  • Bettge, Martin; Li, Yan; Gallagher, Kevin
  • Journal of The Electrochemical Society, Vol. 160, Issue 11
  • DOI: 10.1149/2.034311jes

Synthesis of layered LiMnO2 as an electrode for rechargeable lithium batteries
journal, June 1996

  • Armstrong, A. Robert; Bruce, Peter G.
  • Nature, Vol. 381, Issue 6582
  • DOI: 10.1038/381499a0

Enhanced Li+ ion transport in LiNi0.5Mn1.5O4 through control of site disorder
journal, January 2012

  • Zheng, Jianming; Xiao, Jie; Yu, Xiqian
  • Physical Chemistry Chemical Physics, Vol. 14, Issue 39
  • DOI: 10.1039/c2cp43007j

The distribution of transition metal cations in spinels
journal, January 1957


First Evidence of Manganese–Nickel Segregation and Densification upon Cycling in Li-Rich Layered Oxides for Lithium Batteries
journal, July 2013

  • Boulineau, Adrien; Simonin, Loïc; Colin, Jean-François
  • Nano Letters, Vol. 13, Issue 8
  • DOI: 10.1021/nl4019275

Nanostructured high-energy cathode materials for advanced lithium batteries
journal, October 2012

  • Sun, Yang-Kook; Chen, Zonghai; Noh, Hyung-Joo
  • Nature Materials, Vol. 11, Issue 11
  • DOI: 10.1038/nmat3435

Suppressed capacity/voltage fading of high-capacity lithium-rich layered materials via the design of heterogeneous distribution in the composition
journal, January 2014

  • Yang, Xiukang; Wang, Di; Yu, Ruizhi
  • Journal of Materials Chemistry A, Vol. 2, Issue 11
  • DOI: 10.1039/c3ta14513a

Electrochemical kinetics of the 0.5Li2MnO3·0.5LiMn0.42Ni0.42Co0.16O2 ‘composite’ layered cathode material for lithium-ion batteries
journal, January 2012

  • Yu, Haijun; Wang, Yarong; Asakura, Daisuke
  • RSC Advances, Vol. 2, Issue 23
  • DOI: 10.1039/c2ra20772a

Electrodes with High Power and High Capacity for Rechargeable Lithium Batteries
journal, February 2006

  • Kang, Kisuk; Shirley Meng, Ying; Breger, Julien
  • Science, Vol. 311, Issue 5763, p. 977-980
  • DOI: 10.1126/science.1122152

High-Performance LiNi 0.5 Mn 1.5 O 4 Spinel Controlled by Mn 3+ Concentration and Site Disorder
journal, March 2012


LixNi0.25Mn0.75Oy (0.5 ≤x≤ 2, 2 ≤y≤ 2.75) compounds for high-energy lithium-ion batteries
journal, January 2009

  • Deng, Haixia; Belharouak, Ilias; Sun, Yang-Kook
  • Journal of Materials Chemistry, Vol. 19, Issue 26
  • DOI: 10.1039/b904098f

Examining Hysteresis in Composite x Li 2 MnO 3 ·(1– x )LiMO 2 Cathode Structures
journal, March 2013

  • Croy, Jason R.; Gallagher, Kevin G.; Balasubramanian, Mahalingam
  • The Journal of Physical Chemistry C, Vol. 117, Issue 13
  • DOI: 10.1021/jp312658q

Understanding Li Diffusion in Li-Intercalation Compounds
journal, May 2012

  • Van der Ven, Anton; Bhattacharya, Jishnu; Belak, Anna A.
  • Accounts of Chemical Research, Vol. 46, Issue 5
  • DOI: 10.1021/ar200329r

Effect of (Al, Mg) substitution in LiNiO2 electrode for lithium batteries
journal, July 2006


Crystal Habit-Tuned Nanoplate Material of Li[Li1/3-2x/3NixMn2/3-x/3]O2 for High-Rate Performance Lithium-Ion Batteries
journal, August 2010


Role of Oxygen Vacancies on the Performance of Li[Ni 0.5– x Mn 1.5+ x ]O 4 ( x = 0, 0.05, and 0.08) Spinel Cathodes for Lithium-Ion Batteries
journal, July 2012

  • Song, Jie; Shin, Dong Wook; Lu, Yuhao
  • Chemistry of Materials, Vol. 24, Issue 15
  • DOI: 10.1021/cm301825h

Neutron Diffraction and Magnetic Susceptibility Studies on a High-Voltage Li 1.2 Mn 0.55 Ni 0.15 Co 0.10 O 2 Lithium Ion Battery Cathode: Insight into the Crystal Structure
journal, September 2013

  • Mohanty, Debasish; Huq, Ashfia; Payzant, E. Andrew
  • Chemistry of Materials, Vol. 25, Issue 20
  • DOI: 10.1021/cm402278q

Countering the Voltage Decay in High Capacity xLi 2 MnO 3 •(1–x)LiMO 2 Electrodes (M=Mn, Ni, Co) for Li + -Ion Batteries
journal, January 2012

  • Croy, Jason R.; Kim, Donghan; Balasubramanian, Mahalingam
  • Journal of The Electrochemical Society, Vol. 159, Issue 6
  • DOI: 10.1149/2.080206jes

Comparative Study of LiNi 0.5 Mn 1.5 O 4 - δ and LiNi 0.5 Mn 1.5 O 4 Cathodes Having Two Crystallographic Structures:  Fdm and P 4 3 32
journal, March 2004

  • Kim, J. -H.; Myung, S. -T.; Yoon, C. S.
  • Chemistry of Materials, Vol. 16, Issue 5
  • DOI: 10.1021/cm035050s

High-energy cathode material for long-life and safe lithium batteries
journal, March 2009

  • Sun, Yang-Kook; Myung, Seung-Taek; Park, Byung-Chun
  • Nature Materials, Vol. 8, Issue 4
  • DOI: 10.1038/nmat2418

Migration of Mn cations in delithiated lithium manganese oxides
journal, January 2014

  • Kan, Yongchun; Hu, Yuan; Lin, Chi-Kai
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 38
  • DOI: 10.1039/C4CP02795G

Atomic resolution of lithium ions in LiCoO2
journal, June 2003

  • Shao-Horn, Yang; Croguennec, Laurence; Delmas, Claude
  • Nature Materials, Vol. 2, Issue 7
  • DOI: 10.1038/nmat922

Probing Thermally Induced Decomposition of Delithiated Li 1.2– x Ni 0.15 Mn 0.55 Co 0.1 O 2 by in Situ High-Energy X-ray Diffraction
journal, July 2014

  • Lin, Chi-kai; Piao, Ying; Kan, Yongchun
  • ACS Applied Materials & Interfaces, Vol. 6, Issue 15
  • DOI: 10.1021/am502689f

Correlating cation ordering and voltage fade in a lithium–manganese-rich lithium-ion battery cathode oxide: a joint magnetic susceptibility and TEM study
journal, January 2013

  • Mohanty, Debasish; Sefat, Athena S.; Li, Jianlin
  • Physical Chemistry Chemical Physics, Vol. 15, Issue 44
  • DOI: 10.1039/c3cp53658k

Stabilization of xLi2MnO3 ⋅  ( 1 − x ) LiMO2 Electrode Surfaces  ( M = Mn ,  Ni ,  Co )  with Mildly Acidic, Fluorinated Solutions
journal, January 2008

  • Kang, S.-H.; Thackeray, M. M.
  • Journal of The Electrochemical Society, Vol. 155, Issue 4, p. A269-A275
  • DOI: 10.1149/1.2834904

Electronic properties of transition-metal oxides-II
journal, January 1957


Solid state synthesis of LiFePO4 studied by in situ high energy X-ray diffraction
journal, January 2011

  • Chen, Zonghai; Ren, Yang; Qin, Yan
  • Journal of Materials Chemistry, Vol. 21, Issue 15
  • DOI: 10.1039/c0jm04049e

Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries
journal, December 2012

  • Gu, Meng; Belharouak, Ilias; Zheng, Jianming
  • ACS Nano, Vol. 7, Issue 1
  • DOI: 10.1021/nn305065u