skip to main content
OSTI.GOV title logo U.S. Department of Energy
Office of Scientific and Technical Information

Title: Role of Cr 3+ /Cr 6+ redox in chromium-substituted Li 2 MnO 3 ·LiNi 1/2 Mn 1/2 O 2 layered composite cathodes: electrochemistry and voltage fade

Abstract

The substitution of chromium into the composite Li 2MnO 3·LiNi 1/2Mn 1/2O 2cathode dramatically affects the initial electrochemical activation process; however the voltage fade process during cycling persists.

Authors:
 [1];  [1];  [2];  [2];  [3];  [3];  [1];  [4];  [1]
  1. Chemical Sciences and Engineering Division; Argonne National Laboratory; Argonne, USA
  2. Advanced Photon Source; Argonne National Laboratory; Argonne, USA
  3. Chemical Sciences and Engineering Division; Argonne National Laboratory; Argonne, USA; Catalysis Center; Northwestern University
  4. Chemical Sciences and Engineering Division; Argonne National Laboratory; Argonne, USA; Department of Chemical Engineering; University of Rochester
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Energy Efficiency and Renewable Energy (EERE)
OSTI Identifier:
1392413
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 3; Journal Issue: 18; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
batteries; layered oxide; lithium-ion; voltage fade

Citation Formats

Lee, Eungje, Park, Joong Sun, Wu, Tianpin, Sun, Cheng-Jun, Kim, Hacksung, Stair, Peter C., Lu, Jun, Zhou, Dehua, and Johnson, Christopher S. Role of Cr 3+ /Cr 6+ redox in chromium-substituted Li 2 MnO 3 ·LiNi 1/2 Mn 1/2 O 2 layered composite cathodes: electrochemistry and voltage fade. United States: N. p., 2015. Web. doi:10.1039/c5ta01214g.
Lee, Eungje, Park, Joong Sun, Wu, Tianpin, Sun, Cheng-Jun, Kim, Hacksung, Stair, Peter C., Lu, Jun, Zhou, Dehua, & Johnson, Christopher S. Role of Cr 3+ /Cr 6+ redox in chromium-substituted Li 2 MnO 3 ·LiNi 1/2 Mn 1/2 O 2 layered composite cathodes: electrochemistry and voltage fade. United States. doi:10.1039/c5ta01214g.
Lee, Eungje, Park, Joong Sun, Wu, Tianpin, Sun, Cheng-Jun, Kim, Hacksung, Stair, Peter C., Lu, Jun, Zhou, Dehua, and Johnson, Christopher S. Thu . "Role of Cr 3+ /Cr 6+ redox in chromium-substituted Li 2 MnO 3 ·LiNi 1/2 Mn 1/2 O 2 layered composite cathodes: electrochemistry and voltage fade". United States. doi:10.1039/c5ta01214g.
@article{osti_1392413,
title = {Role of Cr 3+ /Cr 6+ redox in chromium-substituted Li 2 MnO 3 ·LiNi 1/2 Mn 1/2 O 2 layered composite cathodes: electrochemistry and voltage fade},
author = {Lee, Eungje and Park, Joong Sun and Wu, Tianpin and Sun, Cheng-Jun and Kim, Hacksung and Stair, Peter C. and Lu, Jun and Zhou, Dehua and Johnson, Christopher S.},
abstractNote = {The substitution of chromium into the composite Li2MnO3·LiNi1/2Mn1/2O2cathode dramatically affects the initial electrochemical activation process; however the voltage fade process during cycling persists.},
doi = {10.1039/c5ta01214g},
journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 18,
volume = 3,
place = {United States},
year = {2015},
month = {1}
}

Works referenced in this record:

In Situ X-Ray Absorption Study of a Layered Manganese-Chromium Oxide-Based Cathode Material
journal, January 2002

  • Balasubramanian, M.; McBreen, J.; Davidson, I. J.
  • Journal of The Electrochemical Society, Vol. 149, Issue 2
  • DOI: 10.1149/1.1431962

Advances in Stabilizing ‘Layered-Layered’ xLi2MnO3·(1-x)LiMO2(M=Mn, Ni, Co) Electrodes with a Spinel Component
journal, January 2014

  • Long, Brandon R.; Croy, Jason R.; Park, Joong Sun
  • Journal of The Electrochemical Society, Vol. 161, Issue 14, p. A2160-A2167
  • DOI: 10.1149/2.0681414jes

Local Structure of Layered Oxide Electrode Materials for Lithium-Ion Batteries
journal, January 2010


Morphology, Structure, and Electrochemistry of Solution-Derived LiMn[sub 0.5−x]Cr[sub 2x]Ni[sub 0.5−x]O[sub 2] for Lithium-Ion Cells
journal, January 2009

  • Karan, N. K.; Abraham, D. P.; Balasubramanian, M.
  • Journal of The Electrochemical Society, Vol. 156, Issue 7
  • DOI: 10.1149/1.3125702

First-Principles Analysis of Phase Stability in Layered–Layered Composite Cathodes for Lithium-Ion Batteries
journal, March 2014

  • Iddir, Hakim; Benedek, Roy
  • Chemistry of Materials, Vol. 26, Issue 7
  • DOI: 10.1021/cm403256a

Correlating hysteresis and voltage fade in lithium- and manganese-rich layered transition-metal oxide electrodes
journal, August 2013

  • Gallagher, Kevin G.; Croy, Jason R.; Balasubramanian, Mahalingam
  • Electrochemistry Communications, Vol. 33
  • DOI: 10.1016/j.elecom.2013.04.022

Effect of interface modifications on voltage fade in 0.5Li2MnO3·0.5LiNi0.375Mn0.375Co0.25O2 cathode materials
journal, March 2014


Aluminum and Gallium Substitution into 0.5Li 2 MnO 3 ·0.5Li(Ni 0.375 Mn 0.375 Co 0.25 )O 2 Layered Composite and the Voltage Fade Effect
journal, December 2014

  • Lee, Eungje; Koritala, Rachel; Miller, Dean J.
  • Journal of The Electrochemical Society, Vol. 162, Issue 3
  • DOI: 10.1149/2.0321503jes

Lattice vibrations of materials for lithium rechargeable batteries III. Lithium manganese oxides
journal, June 2003


Uncovering the roles of oxygen vacancies in cation migration in lithium excess layered oxides
journal, January 2014

  • Qian, Danna; Xu, Bo; Chi, Miaofang
  • Phys. Chem. Chem. Phys., Vol. 16, Issue 28
  • DOI: 10.1039/C4CP01799D

Structural Analysis of Li2MnO3 and Related Li-Mn-O Materials
journal, January 2011

  • Yu, Denis Y. W.; Yanagida, Katsunori
  • Journal of The Electrochemical Society, Vol. 158, Issue 9
  • DOI: 10.1149/1.3609849

Ambivalent Effect of Oxygen Vacancies on Li 2 MnO 3 : A First-Principles Study
journal, January 2011

  • Okamoto, Yasuharu
  • Journal of The Electrochemical Society, Vol. 159, Issue 2
  • DOI: 10.1149/2.079202jes

Lithium–manganese–nickel-oxide electrodes with integrated layered–spinel structures for lithium batteries
journal, February 2007


Materials Challenges and Opportunities of Lithium Ion Batteries
journal, January 2011

  • Manthiram, Arumugam
  • The Journal of Physical Chemistry Letters, Vol. 2, Issue 3
  • DOI: 10.1021/jz1015422

Electrochemical and Structural Study of the Layered, “Li-Excess” Lithium-Ion Battery Electrode Material Li[Li 1/9 Ni 1/3 Mn 5/9 ]O 2
journal, July 2009

  • Jiang, Meng; Key, Baris; Meng, Ying S.
  • Chemistry of Materials, Vol. 21, Issue 13
  • DOI: 10.1021/cm900279u

Identification of LiNi0.5Mn1.5O4 spinel in layered manganese enriched electrode materials
journal, March 2011

  • Belharouak, Ilias; Koenig, Gary M.; Ma, Jiwei
  • Electrochemistry Communications, Vol. 13, Issue 3, p. 232-236
  • DOI: 10.1016/j.elecom.2010.12.021

Local Structure and First Cycle Redox Mechanism of Layered Li[sub 1.2]Cr[sub 0.4]Mn[sub 0.4]O[sub 2] Cathode Material
journal, January 2002

  • Ammundsen, Brett; Paulsen, Jens; Davidson, Isobel
  • Journal of The Electrochemical Society, Vol. 149, Issue 4
  • DOI: 10.1149/1.1456535

Composite ‘Layered-Layered-Spinel’ Cathode Structures for Lithium-Ion Batteries
journal, November 2012

  • Kim, Donghan; Sandi, Giselle; Croy, Jason R.
  • Journal of The Electrochemical Society, Vol. 160, Issue 1, p. A31-A38
  • DOI: 10.1149/2.049301jes

Understanding Long-Term Cycling Performance of Li 1.2 Ni 0.15 Mn 0.55 Co 0.1 O 2 –Graphite Lithium-Ion Cells
journal, January 2013

  • Li, Y.; Bettge, M.; Polzin, B.
  • Journal of The Electrochemical Society, Vol. 160, Issue 5
  • DOI: 10.1149/2.002305jes

Voltage Fade of Layered Oxides: Its Measurement and Impact on Energy Density
journal, January 2013

  • Bettge, Martin; Li, Yan; Gallagher, Kevin
  • Journal of The Electrochemical Society, Vol. 160, Issue 11
  • DOI: 10.1149/2.034311jes

Improving high-capacity Li1.2Ni0.15Mn0.55Co0.1O2-based lithium-ion cells by modifiying the positive electrode with alumina
journal, July 2013


Electrical energy storage for transportation—approaching the limits of, and going beyond, lithium-ion batteries
journal, January 2012

  • Thackeray, Michael M.; Wolverton, Christopher; Isaacs, Eric D.
  • Energy & Environmental Science, Vol. 5, Issue 7
  • DOI: 10.1039/c2ee21892e

The Li-Ion Rechargeable Battery: A Perspective
journal, January 2013

  • Goodenough, John B.; Park, Kyu-Sung
  • Journal of the American Chemical Society, Vol. 135, Issue 4
  • DOI: 10.1021/ja3091438

Next-generation lithium-ion batteries: The promise of near-term advancements
journal, May 2014

  • Croy, Jason R.; Abouimrane, Ali; Zhang, Zhengcheng
  • MRS Bulletin, Vol. 39, Issue 5
  • DOI: 10.1557/mrs.2014.84

Formation of the Spinel Phase in the Layered Composite Cathode Used in Li-Ion Batteries
journal, December 2012

  • Gu, Meng; Belharouak, Ilias; Zheng, Jianming
  • ACS Nano, Vol. 7, Issue 1
  • DOI: 10.1021/nn305065u

In Situ and Ex Situ XRD Investigation of Li[Cr[sub x]Li[sub 1/3−x/3]Mn[sub 2/3−2x/3]]O[sub 2] (x=1/3) Cathode Material
journal, January 2003

  • Lu, Zhonghua; Dahn, J. R.
  • Journal of The Electrochemical Society, Vol. 150, Issue 8
  • DOI: 10.1149/1.1584439