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Title: The unexpected discovery of the Mg(HMDS) 2 /MgCl 2 complex as a magnesium electrolyte for rechargeable magnesium batteries

Journal Article · · Journal of Materials Chemistry. A
DOI:https://doi.org/10.1039/c5ta00118h· OSTI ID:1392326

We developed a unique class of non-Grignard, aluminum-free magnesium electrolytes based on a simple mixture of magnesium compounds: magnesium hexamethyldisilazide (Mg(HMDS)2) and magnesium chloride (MgCl2).

Research Organization:
Argonne National Laboratory (ANL), Argonne, IL (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
Grant/Contract Number:
AC02-06CH11357
OSTI ID:
1392326
Journal Information:
Journal of Materials Chemistry. A, Vol. 3, Issue 11; ISSN 2050-7488
Publisher:
Royal Society of ChemistryCopyright Statement
Country of Publication:
United States
Language:
English
Citation Metrics:
Cited by: 112 works
Citation information provided by
Web of Science

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Cited By (22)

A Crosslinked Polytetrahydrofuran‐Borate‐Based Polymer Electrolyte Enabling Wide‐Working‐Temperature‐Range Rechargeable Magnesium Batteries journal January 2019
Unveiling the Roles of Formation Process in Improving Cycling Performance of Magnesium Stannide Composite Anode for Magnesium‐Ion Batteries journal October 2018
Graphite as a Long‐Life Ca 2+ ‐Intercalation Anode and its Implementation for Rocking‐Chair Type Calcium‐Ion Batteries journal October 2019
Polyanthraquinone-Based Organic Cathode for High-Performance Rechargeable Magnesium-Ion Batteries journal May 2016
One‐Step Synthesis of 2‐Ethylhexylamine Pillared Vanadium Disulfide Nanoflowers with Ultralarge Interlayer Spacing for High‐Performance Magnesium Storage journal April 2019
Fast and Reversible Four‐Electron Storage Enabled by Ethyl Viologen for Rechargeable Magnesium Batteries journal November 2019
Halogenid‐basierte Materialien und Chemie für wiederaufladbare Batterien journal January 2020
A Metal–Organic Framework Thin Film for Selective Mg 2+ Transport journal September 2019
Halide‐Based Materials and Chemistry for Rechargeable Batteries journal January 2020
A Metal–Organic Framework Thin Film for Selective Mg 2+ Transport journal October 2019
Computational Insights into Mg‐Cl Complex Electrolytes for Rechargeable Magnesium Batteries journal June 2019
Solvent Effects on the Reversible Intercalation of Magnesium-Ions into V 2 O 5 Electrodes journal September 2018
The Role of MgCl 2 as a Lewis Base in ROMgCl-MgCl 2 Electrolytes for Magnesium-Ion Batteries journal February 2016
Rechargeable Magnesium Batteries using Conversion-Type Cathodes: A Perspective and Minireview journal July 2018
Fast kinetics of magnesium monochloride cations in interlayer-expanded titanium disulfide for magnesium rechargeable batteries journal August 2017
Modifications in coordination structure of Mg[TFSA] 2 -based supporting salts for high-voltage magnesium rechargeable batteries journal January 2019
Bis(trimethylsilyl)amide complexes of s-block metals with bidentate ether and amine ligands journal January 2019
A novel magnesium electrolyte containing a magnesium bis(diisopropyl)amide–magnesium chloride complex for rechargeable magnesium batteries journal January 2019
2,5-Dimethoxy-1,4-Benzoquinone (DMBQ) as Organic Cathode for Rechargeable Magnesium-Ion Batteries journal January 2016
Review—Development of Advanced Rechargeable Batteries: A Continuous Challenge in the Choice of Suitable Electrolyte Solutions journal January 2015
Practical Stability Limits of Magnesium Electrolytes journal January 2016
Widening Electrochemical Window of Mg Salt by Weakly Coordinating Perfluoroalkoxyaluminate Anion for Mg Battery Electrolyte journal January 2019

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