Nickel–Gallium-Catalyzed Electrochemical Reduction of CO 2 to Highly Reduced Products at Low Overpotentials

Torelli, Daniel A.; Francis, Sonja A.; Crompton, J. Chance; Javier, Alnald; Thompson, Jonathan R.; Brunschwig, Bruce S.; Soriaga, Manuel P.; Lewis, Nathan S.

doi:10.1021/acscatal.5b02888

Title: Nickel–Gallium-Catalyzed Electrochemical Reduction of CO ₂ to Highly Reduced Products at Low Overpotentials

Journal Article · Tue Feb 23 00:00:00 EST 2016 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.5b02888· OSTI ID:1392190

Torelli, Daniel A. ^[1]; Francis, Sonja A. ^[1]; Crompton, J. Chance ^[1]; Javier, Alnald ^[1]; Thompson, Jonathan R. ^[1]; Brunschwig, Bruce S. ^[1]; Soriaga, Manuel P. ^[1]; Lewis, Nathan S. ^[1]

Division of Chemistry and Chemical Engineering, ‡Joint Center for Artificial Photosynthesis, £Resnick Sustainability Institute, ∥Division of Engineering and Applied Sciences, and §Beckman Institute Molecular Materials Research Center, California Institute of Technology, Pasadena, California 91125, United States

View Journal Article

Cite

Export

Save

Sponsoring Organization:: USDOE

Grant/Contract Number:: SC0004993

OSTI ID:: 1392190

Journal Information:: ACS Catalysis, Journal Name: ACS Catalysis Vol. 6 Journal Issue: 3; ISSN 2155-5435

Publisher:: American Chemical SocietyCopyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 207 works

Citation information provided by
Web of Science

References (44)

CO₂ Reduction at Low Overpotential on Cu Electrodes Resulting from the Reduction of Thick Cu₂O Films Li, Christina W.; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 134, Issue 17, p. 7231-7234 https://doi.org/10.1021/ja3010978	journal	April 2012
The importance of surface morphology in controlling the selectivity of polycrystalline copper for CO2 electroreduction Tang, Wei; Peterson, Andrew A.; Varela, Ana Sofia Phys. Chem. Chem. Phys., Vol. 14, Issue 1 https://doi.org/10.1039/C1CP22700A	journal	January 2012
A Highly Selective Copper-Indium Bimetallic Electrocatalyst for the Electrochemical Reduction of Aqueous CO ₂ to CO Rasul, Shahid; Anjum, Dalaver H.; Jedidi, Abdesslem Angewandte Chemie International Edition, Vol. 54, Issue 7 https://doi.org/10.1002/anie.201410233	journal	December 2014
Electrochemistry of Acids on Platinum. Application to the Reduction of Carbon Dioxide in the Presence of Pyridinium Ion in Water Costentin, Cyrille; Canales, Juan Carlos; Haddou, Baptiste Journal of the American Chemical Society, Vol. 135, Issue 47 https://doi.org/10.1021/ja407988w	journal	November 2013
Electroreduction of carbon monoxide to liquid fuel on oxide-derived nanocrystalline copper Li, Christina W.; Ciston, Jim; Kanan, Matthew W. Nature, Vol. 508, Issue 7497 https://doi.org/10.1038/nature13249	journal	April 2014
Electrochemical Reduction of CO at a Copper Electrode Hori, Yoshio; Takahashi, Ryutaro; Yoshinami, Yuzuru The Journal of Physical Chemistry B, Vol. 101, Issue 36 https://doi.org/10.1021/jp970284i	journal	September 1997
Design of alloy electrocatalysts for CO2 reduction Watanabe, Masahiro; Shibata, Masami; Katoh, Akihiro Journal of Electroanalytical Chemistry and Interfacial Electrochemistry, Vol. 305, Issue 2 https://doi.org/10.1016/0022-0728(91)85528-W	journal	May 1991
Composition-dependent activity of Cu–Pt alloy nanocubes for electrocatalytic CO ₂ reduction Zhao, Xueyu; Luo, Binbin; Long, Ran Journal of Materials Chemistry A, Vol. 3, Issue 8 https://doi.org/10.1039/C4TA06608A	journal	January 2015
Discovery of a Ni-Ga catalyst for carbon dioxide reduction to methanol Studt, Felix; Sharafutdinov, Irek; Abild-Pedersen, Frank Nature Chemistry, Vol. 6, Issue 4 https://doi.org/10.1038/nchem.1873	journal	March 2014
Selective electrochemical reduction of CO₂ to ethylene at a three-phase interface on copper(I) halide-confined Cu-mesh electrodes in acidic solutions of potassium halides Yano, H.; Tanaka, T.; Nakayama, M. Journal of Electroanalytical Chemistry, Vol. 565, Issue 2, p. 287-293 https://doi.org/10.1016/j.jelechem.2003.10.021	journal	April 2004
Enhanced selectivity for the electrochemical reduction of CO2 to alcohols in aqueous solution with nanostructured Cu–Au alloy as catalyst Jia, Falong; Yu, Xinxing; Zhang, Lizhi Journal of Power Sources, Vol. 252 https://doi.org/10.1016/j.jpowsour.2013.12.002	journal	April 2014
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces Kuhl, Kendra P.; Hatsukade, Toru; Cave, Etosha R. Journal of the American Chemical Society, Vol. 136, Issue 40 https://doi.org/10.1021/ja505791r	journal	August 2014
Electronic-structure study of the NiGa and the NiIn intermetallic compounds using X-ray photoemission spectroscopy Hsu, Li-Shing; Williams, R. Stanley Journal of Physics and Chemistry of Solids, Vol. 55, Issue 4, p. 305-312 https://doi.org/10.1016/0022-3697(94)90226-7	journal	April 1994
Design of Allory Electrocatalysts for CO₂ Reduction (I)．The Selective and Reversible Reduction of CO₂ at Cu-Ni Alloy Electrodes Watanabe, Masahiro; Shibata, Masami; Katoh, Akihiro Denki Kagaku oyobi Kogyo Butsuri Kagaku, Vol. 59, Issue 6 https://doi.org/10.5796/kogyobutsurikagaku.59.508	journal	January 1991
Pulsed Electroreduction of CO[sub 2] on Cu-Ag Alloy Electrodes Ishimaru, S.; Shiratsuchi, R.; Nogami, G. Journal of The Electrochemical Society, Vol. 147, Issue 5 https://doi.org/10.1149/1.1393448	journal	January 2000
Insights into the electrocatalytic reduction of CO ₂ on metallic silver surfaces Hatsukade, Toru; Kuhl, Kendra P.; Cave, Etosha R. Phys. Chem. Chem. Phys., Vol. 16, Issue 27 https://doi.org/10.1039/C4CP00692E	journal	January 2014
The influence of pH on the reduction of CO and ${CO}_{2}$ to hydrocarbons on copper electrodes Schouten, Klaas Jan P.; Pérez Gallent, Elena; Koper, Marc T. M. Journal of Electroanalytical Chemistry, Vol. 716 https://doi.org/10.1016/j.jelechem.2013.08.033	journal	March 2014
Efficient Electrochemical Reduction of Carbon Dioxide to Acetate on Nitrogen-Doped Nanodiamond Liu, Yanming; Chen, Shuo; Quan, Xie Journal of the American Chemical Society, Vol. 137, Issue 36 https://doi.org/10.1021/jacs.5b02975	journal	September 2015
Selective Electrochemical Reduction of Carbon Dioxide to Ethylene and Ethanol on Copper(I) Oxide Catalysts Ren, Dan; Deng, Yilin; Handoko, Albertus Denny ACS Catalysis, Vol. 5, Issue 5 https://doi.org/10.1021/cs502128q	journal	March 2015
Gold–Copper Nanoalloys Supported on TiO ₂ as Photocatalysts for CO ₂ Reduction by Water Neaţu, Ştefan; Maciá-Agulló, Juan Antonio; Concepción, Patricia Journal of the American Chemical Society, Vol. 136, Issue 45 https://doi.org/10.1021/ja506433k	journal	October 2014
Electrochemical CO ₂ reduction on Cu ₂ O-derived copper nanoparticles: controlling the catalytic selectivity of hydrocarbons Kas, Recep; Kortlever, Ruud; Milbrat, Alexander Phys. Chem. Chem. Phys., Vol. 16, Issue 24 https://doi.org/10.1039/c4cp01520g	journal	January 2014
Selective Solar-Driven Reduction of CO ₂ to Methanol Using a Catalyzed p-GaP Based Photoelectrochemical Cell Barton, Emily E.; Rampulla, David M.; Bocarsly, Andrew B. Journal of the American Chemical Society, Vol. 130, Issue 20 https://doi.org/10.1021/ja0776327	journal	May 2008
Enhanced Electrochemical Methanation of Carbon Dioxide with a Dispersible Nanoscale Copper Catalyst Manthiram, Karthish; Beberwyck, Brandon J.; Alivisatos, A. Paul Journal of the American Chemical Society, Vol. 136, Issue 38 https://doi.org/10.1021/ja5065284	journal	September 2014
Benchmarking Heterogeneous Electrocatalysts for the Oxygen Evolution Reaction McCrory, Charles C. L.; Jung, Suho; Peters, Jonas C. Journal of the American Chemical Society, Vol. 135, Issue 45 https://doi.org/10.1021/ja407115p	journal	October 2013
Electrochemical CO ₂ Reduction to Formic Acid at Low Overpotential and with High Faradaic Efficiency on Carbon-Supported Bimetallic Pd–Pt Nanoparticles Kortlever, Ruud; Peters, Ines; Koper, Sander ACS Catalysis, Vol. 5, Issue 7 https://doi.org/10.1021/acscatal.5b00602	journal	June 2015
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels Peterson, Andrew A.; Abild-Pedersen, Frank; Studt, Felix Energy & Environmental Science, Vol. 3, Issue 9 https://doi.org/10.1039/c0ee00071j	journal	January 2010
PRODUCTION OF CO AND CH ₄ IN ELECTROCHEMICAL REDUCTION OF CO ₂ AT METAL ELECTRODES IN AQUEOUS HYDROGENCARBONATE SOLUTION Hori, Yoshio; Kikuchi, Katsuhei; Suzuki, Shin Chemistry Letters, Vol. 14, Issue 11 https://doi.org/10.1246/cl.1985.1695	journal	November 1985
Reactions and Mechanism of the Electrochemical Reduction of Carbon Dioxide at Alloyed Copper-Silver Electrodes Nakato, Yoshihiro; Yano, Shuji; Yamaguchi, Takashi Denki Kagaku oyobi Kogyo Butsuri Kagaku, Vol. 59, Issue 6 https://doi.org/10.5796/kogyobutsurikagaku.59.491	journal	January 1991
Synthesis of thin film AuPd alloys and their investigation for electrocatalytic CO ₂ reduction Hahn, Christopher; Abram, David N.; Hansen, Heine A. Journal of Materials Chemistry A, Vol. 3, Issue 40 https://doi.org/10.1039/C5TA04863J	journal	January 2015
Formation of hydrocarbons in the electrochemical reduction of carbon dioxide at a copper electrode in aqueous solution Hori, Yoshio; Murata, Akira; Takahashi, Ryutaro Journal of the Chemical Society, Faraday Transactions 1: Physical Chemistry in Condensed Phases, Vol. 85, Issue 8 https://doi.org/10.1039/f19898502309	journal	January 1989
Reduction of Carbon Dioxide to Methanol on n- and p-GaAs and p-InP. Effect of Crystal Face, Electrolyte and Current Density Canfield, D. Journal of The Electrochemical Society, Vol. 130, Issue 8 https://doi.org/10.1149/1.2120090	journal	January 1983
Fe and Pt carbon nanotubes for the electrocatalytic conversion of carbon dioxide to oxygenates Gangeri, M.; Perathoner, S.; Caudo, S. Catalysis Today, Vol. 143, Issue 1-2 https://doi.org/10.1016/j.cattod.2008.11.001	journal	May 2009
Intermetallic Alloys as CO Electroreduction Catalysts—Role of Isolated Active Sites Karamad, Mohammadreza; Tripkovic, Vladimir; Rossmeisl, Jan ACS Catalysis, Vol. 4, Issue 7 https://doi.org/10.1021/cs500328c	journal	May 2014
Synergistic geometric and electronic effects for electrochemical reduction of carbon dioxide using gold–copper bimetallic nanoparticles Kim, Dohyung; Resasco, Joaquin; Yu, Yi Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms5948	journal	September 2014
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N. Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21234j	journal	January 2012
Electrochemical evidence of intermediate formation of adsorbed CO in cathodic reduction of CO₂ at a nickel electrode Hori, Yoshio; Murata, Akira Electrochimica Acta, Vol. 35, Issue 11-12, p. 1777-1780 https://doi.org/10.1016/0013-4686(90)87078-G	journal	November 1990
Electrochemical reduction of CO ₂ to ethylene glycol on imidazolium ion-terminated self-assembly monolayer-modified Au electrodes in an aqueous solution Tamura, Jun; Ono, Akihiko; Sugano, Yoshitsune Physical Chemistry Chemical Physics, Vol. 17, Issue 39 https://doi.org/10.1039/C5CP03028E	journal	January 2015
Metal-Doped Nitrogenated Carbon as an Efficient Catalyst for Direct CO ₂ Electroreduction to CO and Hydrocarbons Varela, Ana Sofia; Ranjbar Sahraie, Nastaran; Steinberg, Julian Angewandte Chemie International Edition, Vol. 54, Issue 37 https://doi.org/10.1002/anie.201502099	journal	July 2015
Reduction of CO[sub 2] on n-GaAs Electrodes and Selective Methanol Synthesis Frese, K. W. Journal of The Electrochemical Society, Vol. 131, Issue 11 https://doi.org/10.1149/1.2115351	journal	January 1984
High Selectivity for Ethylene from Carbon Dioxide Reduction over Copper Nanocube Electrocatalysts Roberts, F. Sloan; Kuhl, Kendra P.; Nilsson, Anders Angewandte Chemie International Edition, Vol. 54, Issue 17 https://doi.org/10.1002/anie.201412214	journal	February 2015
Structure Sensitivity of the Electrochemical Reduction of Carbon Monoxide on Copper Single Crystals Schouten, Klaas Jan P.; Pérez Gallent, Elena; Koper, Marc T. M. ACS Catalysis, Vol. 3, Issue 6 https://doi.org/10.1021/cs4002404	journal	April 2013
Carbon dioxide reduction on gallium arsenide electrodes Sears, W. M.; Morrison, S. Roy The Journal of Physical Chemistry, Vol. 89, Issue 15 https://doi.org/10.1021/j100261a026	journal	July 1985
Electroreduction of Carbon Dioxide on Copper-Based Electrodes: Activity of Copper Single Crystals and Copper–Gold Alloys Christophe, J.; Doneux, Th.; Buess-Herman, C. Electrocatalysis, Vol. 3, Issue 2 https://doi.org/10.1007/s12678-012-0095-0	journal	April 2012
A review of catalysts for the electroreduction of carbon dioxide to produce low-carbon fuels Qiao, Jinli; Liu, Yuyu; Hong, Feng Chem. Soc. Rev., Vol. 43, Issue 2 https://doi.org/10.1039/C3CS60323G	journal	January 2014

Similar Records

Metal–Ligand Cooperativity via Exchange Coupling Promotes Iron- Catalyzed Electrochemical CO₂ Reduction at Low Overpotentials

Journal Article · Wed Nov 18 00:00:00 EST 2020 · Journal of the American Chemical Society · OSTI ID:1392190

Derrick, Jeffrey S.; Loipersberger, Matthias; Chatterjee, Ruchira; +7 more

Deciphering Distinct Overpotential-Dependent Pathways for Electrochemical CO₂ Reduction Catalyzed by an Iron–Terpyridine Complex

Journal Article · Fri Apr 22 00:00:00 EDT 2022 · Inorganic Chemistry · OSTI ID:1392190

Loipersberger, Matthias; Derrick, Jeffrey S.; Chang, Christopher J.; +1 more

An amide-based second coordination sphere promotes the dimer pathway of Mn-catalyzed CO ₂ -to-CO reduction at low overpotential

Journal Article · Thu Apr 08 00:00:00 EDT 2021 · Chemical Science · OSTI ID:1392190

Yang, Yong; Ertem, Mehmed Z.; Duan, Lele

Title: Nickel–Gallium-Catalyzed Electrochemical Reduction of CO 2 to Highly Reduced Products at Low Overpotentials

Citation Formats

References (44)

Similar Records

Related Subjects

Title: Nickel–Gallium-Catalyzed Electrochemical Reduction of CO ₂ to Highly Reduced Products at Low Overpotentials