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Title: Hydrophobic pillared square grids for selective removal of CO 2 from simulated flue gas

Abstract

Capture of CO2 from flue gas is considered to be a feasible approach to mitigate the effects of anthropogenic emission of CO2. Herein we report that an isostructural family of metal organic materials (MOMs) of general formula [M(linker)2(pillar)], linker = pyrazine, pillar = hexaflourosilicate and M = Zn, Cu, Ni and Co exhibits highly selective removal of CO2 from dry and wet simulated flue gas. Two members of the family, M = Ni and Co, SIFSIX-3-Ni and SIFSIX-3-Co, respectively, are reported for the first time and compared with the previously reported Zn and Cu analogs.

Authors:
; ; ; ; ; ; ; ; ; ; ; ;
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22); National Science Foundation (NSF)
OSTI Identifier:
1391983
DOE Contract Number:
AC02-06CH11357
Resource Type:
Journal Article
Resource Relation:
Journal Name: ChemComm; Journal Volume: 51; Journal Issue: 85
Country of Publication:
United States
Language:
English

Citation Formats

Elsaidi, Sameh K., Mohamed, Mona H., Schaef, Herbert T., Kumar, Amrit, Lusi, Matteo, Pham, Tony, Forrest, Katherine A., Space, Brian, Xu, Wenqian, Halder, Gregory J., Liu, Jun, Zaworotko, Michael J., and Thallapally, Praveen K. Hydrophobic pillared square grids for selective removal of CO 2 from simulated flue gas. United States: N. p., 2015. Web. doi:10.1039/c5cc06577a.
Elsaidi, Sameh K., Mohamed, Mona H., Schaef, Herbert T., Kumar, Amrit, Lusi, Matteo, Pham, Tony, Forrest, Katherine A., Space, Brian, Xu, Wenqian, Halder, Gregory J., Liu, Jun, Zaworotko, Michael J., & Thallapally, Praveen K. Hydrophobic pillared square grids for selective removal of CO 2 from simulated flue gas. United States. doi:10.1039/c5cc06577a.
Elsaidi, Sameh K., Mohamed, Mona H., Schaef, Herbert T., Kumar, Amrit, Lusi, Matteo, Pham, Tony, Forrest, Katherine A., Space, Brian, Xu, Wenqian, Halder, Gregory J., Liu, Jun, Zaworotko, Michael J., and Thallapally, Praveen K. Thu . "Hydrophobic pillared square grids for selective removal of CO 2 from simulated flue gas". United States. doi:10.1039/c5cc06577a.
@article{osti_1391983,
title = {Hydrophobic pillared square grids for selective removal of CO 2 from simulated flue gas},
author = {Elsaidi, Sameh K. and Mohamed, Mona H. and Schaef, Herbert T. and Kumar, Amrit and Lusi, Matteo and Pham, Tony and Forrest, Katherine A. and Space, Brian and Xu, Wenqian and Halder, Gregory J. and Liu, Jun and Zaworotko, Michael J. and Thallapally, Praveen K.},
abstractNote = {Capture of CO2 from flue gas is considered to be a feasible approach to mitigate the effects of anthropogenic emission of CO2. Herein we report that an isostructural family of metal organic materials (MOMs) of general formula [M(linker)2(pillar)], linker = pyrazine, pillar = hexaflourosilicate and M = Zn, Cu, Ni and Co exhibits highly selective removal of CO2 from dry and wet simulated flue gas. Two members of the family, M = Ni and Co, SIFSIX-3-Ni and SIFSIX-3-Co, respectively, are reported for the first time and compared with the previously reported Zn and Cu analogs.},
doi = {10.1039/c5cc06577a},
journal = {ChemComm},
number = 85,
volume = 51,
place = {United States},
year = {Thu Jan 01 00:00:00 EST 2015},
month = {Thu Jan 01 00:00:00 EST 2015}
}