Fragility of ferromagnetic double exchange interactions and pressure tuning of magnetism in 3d-5d double perovskite Sr2FeOsO6

Veiga, L. S.  I.; Fabbris, G.; van Veenendaal, M.; Souza-Neto, N. M.; Feng, H. L.; Yamaura, K.; Haskel, D.

doi:10.1103/PhysRevB.91.235135

Title: Fragility of ferromagnetic double exchange interactions and pressure tuning of magnetism in $3 d - 5 d$ double perovskite ${Sr}_{2} {FeOsO}_{6}$

Journal Article · Fri Jun 19 00:00:00 EDT 2015 · Physical Review. B, Condensed Matter and Materials Physics

DOI:https://doi.org/10.1103/PhysRevB.91.235135· OSTI ID:1391913

Veiga, L. S. I.; Fabbris, G.; van Veenendaal, M.; Souza-Neto, N. M.; Feng, H. L.; Yamaura, K.; Haskel, D.

The ability to tune exchange (magnetic) interactions between 3d transition metals in perovskite structures has proven to be a powerful route to discovery of novel properties. Here we demonstrate that the introduction of 3d-5d exchange pathways in double perovskites enables additional tunability, a result of the large spatial extent of 5d wave functions. Using x-ray probes of magnetism and structure at high pressure, we show that compression of Sr2FeOsO6 drives an unexpected continuous change in the sign of Fe-Os exchange interactions and a transition from antiferromagnetic to ferrimagnetic order. We analyze the relevant electron-electron interactions, shedding light into fundamental differences with the more thoroughly studied 3d-3d systems.

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Research Organization:: Argonne National Lab. (ANL), Argonne, IL (United States)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: AC02-06CH11357

OSTI ID:: 1391913

Journal Information:: Physical Review. B, Condensed Matter and Materials Physics, Vol. 91, Issue 23; ISSN 1098-0121

Publisher:: American Physical Society (APS)

Country of Publication:: United States

Language:: English

References (34)

Considerations on Double Exchange Anderson, P. W.; Hasegawa, H. Physical Review, Vol. 100, Issue 2 https://doi.org/10.1103/PhysRev.100.675	journal	October 1955
Composite domain walls in a multiferroic perovskite ferrite Tokunaga, Yusuke; Furukawa, Nobuo; Sakai, Hideaki Nature Materials, Vol. 8, Issue 7 https://doi.org/10.1038/nmat2469	journal	June 2009
Compensated magnetism by design in double perovskite oxides Pardo, Victor; Pickett, Warren E. Physical Review B, Vol. 80, Issue 5 https://doi.org/10.1103/PhysRevB.80.054415	journal	August 2009
Probing the Links between Structure and Magnetism in Sr _{2– x} Ca _x FeOsO ₆ Double Perovskites Morrow, Ryan; Freeland, John W.; Woodward, Patrick M. Inorganic Chemistry, Vol. 53, Issue 15 https://doi.org/10.1021/ic5006715	journal	July 2014
Electronically coupled complementary interfaces between perovskite band insulators Huijben, Mark; Rijnders, Guus; Blank, Dave H. A. Nature Materials, Vol. 5, Issue 7 https://doi.org/10.1038/nmat1675	journal	June 2006
A General Mechanism Underlying Ferromagnetism in Transition Metal Compounds Kanamori, Junjiro; Terakura, Kiyoyuki Journal of the Physical Society of Japan, Vol. 70, Issue 5 https://doi.org/10.1143/JPSJ.70.1433	journal	May 2001
EXPGUI , a graphical user interface for GSAS Toby, Brian H. Journal of Applied Crystallography, Vol. 34, Issue 2 https://doi.org/10.1107/S0021889801002242	journal	April 2001
Stability of the ferromagnetic ground state of La $_{2}$ MnNiO $_{6}$ against large compressive stress Haskel, D.; Fabbris, G.; Souza-Neto, N. M. Physical Review B, Vol. 84, Issue 10 https://doi.org/10.1103/PhysRevB.84.100403	journal	September 2011
Synthesis, Crystal Structure, and Physical Properties of Sr ₂ FeOsO ₆ Paul, Avijit Kumar; Jansen, Martin; Yan, Binghai Inorganic Chemistry, Vol. 52, Issue 11 https://doi.org/10.1021/ic400740f	journal	May 2013
Lattice Instability and Competing Spin Structures in the Double Perovskite Insulator ${Sr}_{2} {FeOsO}_{6}$ Paul, Avijit Kumar; Reehuis, Manfred; Ksenofontov, Vadim Physical Review Letters, Vol. 111, Issue 16 https://doi.org/10.1103/PhysRevLett.111.167205	journal	October 2013
Ab initio study of low-temperature magnetic properties of double perovskite ${Sr}_{2}$ ${FeOsO}_{6}$ Kanungo, Sudipta; Yan, Binghai; Jansen, Martin Physical Review B, Vol. 89, Issue 21 https://doi.org/10.1103/PhysRevB.89.214414	journal	June 2014
Antiferromagnetism. Theory of Superexchange Interaction Anderson, P. W. Physical Review, Vol. 79, Issue 2 https://doi.org/10.1103/PhysRev.79.350	journal	July 1950
Structural and doping effects in the half-metallic double perovskite $A_{2} {CrWO}_{6}$ $(A =$ Sr, Ba, and Ca) Philipp, J. B.; Majewski, P.; Alff, L. Physical Review B, Vol. 68, Issue 14 https://doi.org/10.1103/PhysRevB.68.144431	journal	October 2003
Hf–Co and Zr–Co alloys for rare-earth-free permanent magnets Balamurugan, B.; Das, B.; Zhang, W. Y. Journal of Physics: Condensed Matter, Vol. 26, Issue 6 https://doi.org/10.1088/0953-8984/26/6/064204	journal	January 2014
Local Probe for Spin-Orbit Interaction van der Laan, G.; Thole, B. T. Physical Review Letters, Vol. 60, Issue 19 https://doi.org/10.1103/PhysRevLett.60.1977	journal	May 1988
3d x-ray-absorption lines and the 3 $d^{9}$ 4 $f^{n + 1}$ multiplets of the lanthanides Thole, B. T.; van der Laan, G.; Fuggle, J. C. Physical Review B, Vol. 32, Issue 8 https://doi.org/10.1103/PhysRevB.32.5107	journal	October 1985
Orbital Magnetism and Spin-Orbit Effects in the Electronic Structure of ${BaIrO}_{3}$ Laguna-Marco, M. A.; Haskel, D.; Souza-Neto, N. Physical Review Letters, Vol. 105, Issue 21 https://doi.org/10.1103/PhysRevLett.105.216407	journal	November 2010
An interpretation of the magnetic properties of the perovskite-type mixed crystals La1−xSrxCoO3−λ Goodenough, John B. Journal of Physics and Chemistry of Solids, Vol. 6, Issue 2-3 https://doi.org/10.1016/0022-3697(58)90107-0	journal	August 1958
Superexchange interaction and symmetry properties of electron orbitals Kanamori, Junjiro Journal of Physics and Chemistry of Solids, Vol. 10, Issue 2-3 https://doi.org/10.1016/0022-3697(59)90061-7	journal	July 1959
Phase-Sensitive Observation of a Spin-Orbital Mott State in Sr2IrO4 Kim, B. J.; Ohsumi, H.; Komesu, T. Science, Vol. 323, Issue 5919 https://doi.org/10.1126/science.1167106	journal	March 2009
Ferrimagnetism in the double perovskite ${Ca}_{2} {FeOsO}_{6}$ : A density functional study Wang, Hongbo; Zhu, Shasha; Ou, Xuedong Physical Review B, Vol. 90, Issue 5 https://doi.org/10.1103/PhysRevB.90.054406	journal	August 2014
Multiferroics progress and prospects in thin films Ramesh, R.; Spaldin, Nicola A. Nature Materials, Vol. 6, Issue 1, p. 21-29 https://doi.org/10.1038/nmat1805	journal	January 2007
Magnetism in Double Perovskites Saha-Dasgupta, T. Journal of Superconductivity and Novel Magnetism, Vol. 26, Issue 5 https://doi.org/10.1007/s10948-012-1920-7	journal	December 2012
Multiferroics: a magnetic twist for ferroelectricity Cheong, Sang-Wook; Mostovoy, Maxim Nature Materials, Vol. 6, Issue 1 https://doi.org/10.1038/nmat1804	journal	January 2007
Intergrain tunneling magnetoresistance in polycrystals of the ordered double perovskite ${Sr}_{2} {FeReO}_{6}$ Kobayashi, K. -I.; Kimura, T.; Tomioka, Y. Physical Review B, Vol. 59, Issue 17 https://doi.org/10.1103/PhysRevB.59.11159	journal	May 1999
High-Temperature Ferrimagnetism Driven by Lattice Distortion in Double Perovskite Ca ₂ FeOsO ₆ Feng, Hai L.; Arai, Masao; Matsushita, Yoshitaka Journal of the American Chemical Society, Vol. 136, Issue 9 https://doi.org/10.1021/ja411713q	journal	February 2014
Interaction between the $d$ -Shells in the Transition Metals. II. Ferromagnetic Compounds of Manganese with Perovskite Structure Zener, Clarence Physical Review, Vol. 82, Issue 3 https://doi.org/10.1103/PhysRev.82.403	journal	May 1951
Artificial charge-modulationin atomic-scale perovskite titanate superlattices Ohtomo, A.; Muller, D. A.; Grazul, J. L. Nature, Vol. 419, Issue 6905 https://doi.org/10.1038/nature00977	journal	September 2002
Exchange-coupled nanocomposite magnets by nanoparticle self-assembly Zeng, Hao; Li, Jing; Liu, J. P. Nature, Vol. 420, Issue 6914, p. 395-398 https://doi.org/10.1038/nature01208	journal	November 2002
Pressure Tuning of the Spin-Orbit Coupled Ground State in ${Sr}_{2} {IrO}_{4}$ Haskel, D.; Fabbris, G.; Zhernenkov, Mikhail Physical Review Letters, Vol. 109, Issue 2 https://doi.org/10.1103/PhysRevLett.109.027204	journal	July 2012
Moderate to large magneto-optical signals in high Tc double perovskites Das, Hena; De Raychaudhury, Molly; Saha-Dasgupta, T. Applied Physics Letters, Vol. 92, Issue 20 https://doi.org/10.1063/1.2936304	journal	May 2008
Two-dimensional detector software: From real detector to idealised image or two-theta scan Hammersley, A. P.; Svensson, S. O.; Hanfland, M. High Pressure Research, Vol. 14, Issue 4-6, p. 235-248 https://doi.org/10.1080/08957959608201408	journal	January 1996
Theory of the Role of Covalence in the Perovskite-Type Manganites $[La, M (II)] Mn O_{3}$ Goodenough, John B. Physical Review, Vol. 100, Issue 2 https://doi.org/10.1103/PhysRev.100.564	journal	October 1955
High pressure synthesis, crystal structure, and magnetic properties of the double-perovskite Sr ₂ FeOsO ₆ Feng, Hai Luke; Tsujimoto, Yoshihiro; Guo, Yanfeng High Pressure Research, Vol. 33, Issue 1 https://doi.org/10.1080/08957959.2013.773590	journal	March 2013

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