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Title: A High Power Rechargeable Nonaqueous Multivalent Zn/V 2 O 5 Battery

Abstract

A beyond Li-ion battery based on Zn metal, aprotic electrolyte, and a hydrated bilayered V2O5 cathode with a large gallery spacing of 11–13 Å is introduced. The battery exhibits high 20 C rate capability with good specific capacity of 130 mA h g-1. This work provides some design rules for Zn intercalation behavior in host electrodes in a nonaqueous environment.

Authors:
 [1];  [1];  [1];  [1];  [2];  [1];  [3];  [1];  [1]
  1. Joint Center for Energy Storage Research, Argonne National Laboratory, Argonne IL 60439 USA; Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne IL 60439 USA
  2. Joint Center for Energy Storage Research, Argonne National Laboratory, Argonne IL 60439 USA; Material Science Division, Argonne National Laboratory, Argonne IL 60439 USA
  3. Chemical Sciences and Engineering Division, Argonne National Laboratory, Argonne IL 60439 USA
Publication Date:
Research Org.:
Argonne National Lab. (ANL), Argonne, IL (United States)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES) (SC-22)
OSTI Identifier:
1390936
DOE Contract Number:  
AC02-06CH11357
Resource Type:
Journal Article
Resource Relation:
Journal Name: Advanced Energy Materials; Journal Volume: 6; Journal Issue: 24
Country of Publication:
United States
Language:
English
Subject:
36 MATERIALS SCIENCE; 25 ENERGY STORAGE; high capacity; high power; non-aqueous Zn2+ ion electrolyte; vanadium oxide cathode; zinc metal anode

Citation Formats

Senguttuvan, Premkumar, Han, Sang-Don, Kim, Soojeong, Lipson, Albert L., Tepavcevic, Sanja, Fister, Timothy T., Bloom, Ira D., Burrell, Anthony K., and Johnson, Christopher S. A High Power Rechargeable Nonaqueous Multivalent Zn/V 2 O 5 Battery. United States: N. p., 2016. Web. doi:10.1002/aenm.201600826.
Senguttuvan, Premkumar, Han, Sang-Don, Kim, Soojeong, Lipson, Albert L., Tepavcevic, Sanja, Fister, Timothy T., Bloom, Ira D., Burrell, Anthony K., & Johnson, Christopher S. A High Power Rechargeable Nonaqueous Multivalent Zn/V 2 O 5 Battery. United States. doi:10.1002/aenm.201600826.
Senguttuvan, Premkumar, Han, Sang-Don, Kim, Soojeong, Lipson, Albert L., Tepavcevic, Sanja, Fister, Timothy T., Bloom, Ira D., Burrell, Anthony K., and Johnson, Christopher S. Fri . "A High Power Rechargeable Nonaqueous Multivalent Zn/V 2 O 5 Battery". United States. doi:10.1002/aenm.201600826.
@article{osti_1390936,
title = {A High Power Rechargeable Nonaqueous Multivalent Zn/V 2 O 5 Battery},
author = {Senguttuvan, Premkumar and Han, Sang-Don and Kim, Soojeong and Lipson, Albert L. and Tepavcevic, Sanja and Fister, Timothy T. and Bloom, Ira D. and Burrell, Anthony K. and Johnson, Christopher S.},
abstractNote = {A beyond Li-ion battery based on Zn metal, aprotic electrolyte, and a hydrated bilayered V2O5 cathode with a large gallery spacing of 11–13 Å is introduced. The battery exhibits high 20 C rate capability with good specific capacity of 130 mA h g-1. This work provides some design rules for Zn intercalation behavior in host electrodes in a nonaqueous environment.},
doi = {10.1002/aenm.201600826},
journal = {Advanced Energy Materials},
number = 24,
volume = 6,
place = {United States},
year = {Fri Aug 26 00:00:00 EDT 2016},
month = {Fri Aug 26 00:00:00 EDT 2016}
}