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Title: Two coexisting liquid phases in switchable ionic liquids

Journal Article · · Physical Chemistry Chemical Physics. PCCP
DOI:https://doi.org/10.1039/C7CP03754F· OSTI ID:1390444
ORCiD logo [1];  [2]; ORCiD logo [1];  [3]; ORCiD logo [2]; ORCiD logo [4]; ORCiD logo [5]; ORCiD logo [5]; ORCiD logo [3]; ORCiD logo [2]; ORCiD logo [1]
  1. Earth and Biological Sciences Directorate, Pacific Northwest National Laboratory; Richland; USA
  2. Energy and Environment Directorate, Pacific Northwest National Laboratory; Richland; USA
  3. W. R. Wiley Environmental Molecular Science Laboratory, Pacific Northwest National Laboratory; Richland; USA
  4. Dept. Chemistry, Idaho State University; Pocatello; USA
  5. Chemical Sciences Division, Lawrence Berkeley National Laboratory; Berkeley; USA

Switchable ionic liquids are attractive in gas capture, separations, and nanomaterial synthesis.

Research Organization:
Lawrence Berkeley National Laboratory (LBNL), Berkeley, CA (United States); Pacific Northwest National Laboratory (PNNL), Richland, WA (United States)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES). Chemical Sciences, Geosciences, and Biosciences Division
DOE Contract Number:
AC02-05CH11231; AC05-76RL01830
OSTI ID:
1390444
Report Number(s):
PNNL-SA-122167; PPCPFQ; 49694
Journal Information:
Physical Chemistry Chemical Physics. PCCP, Vol. 19, Issue 34; ISSN 1463-9076
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English

References (31)

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CO2 removal with ‘switchable’ versus ‘classical’ ionic liquids journal September 2012
A clean enzymatic process for producing flavour esters by direct esterification in switchable ionic liquid/solid phases journal January 2012
The Reaction of 1,8-Diazabicyclo[5.4.0]undec-7-ene (DBU) with Carbon Dioxide journal June 2005
Comprehensive monitoring of a biphasic switchable solvent synthesis journal January 2013
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Making a hybrid microfluidic platform compatible for in situ imaging by vacuum-based techniques journal November 2011
“Switchable Water”: Aqueous Solutions of Switchable Ionic Strength journal April 2010
CO2 -binding organic liquids, an integrated acid gas capture system journal January 2011
Low viscosity alkanolguanidine and alkanolamidine liquids for CO 2 capture journal January 2013
A time-of-flight secondary ion mass spectroscopy study of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide RT-ionic liquid journal November 2008
Capturing the transient species at the electrode–electrolyte interface by in situ dynamic molecular imaging journal January 2016
A green and sustainable nanotechnology: Role of ionic liquids journal July 2012
Improving the Molecular Ion Signal Intensity for In Situ Liquid SIMS Analysis journal September 2016
Molecular Design of High Capacity, Low Viscosity, Chemically Tunable Ionic Liquids for CO2 Capture journal December 2010
Probing liquid surfaces under vacuum using SEM and ToF-SIMS journal January 2011
In Situ Molecular Imaging of the Biofilm and Its Matrix journal October 2016
CO2-triggered switchable solvents, surfactants, and other materials journal January 2012
Precursor Ion–Ion Aggregation in the Brust–Schiffrin Synthesis of Alkanethiol Nanoparticles journal August 2016
In situ chemical probing of the electrode–electrolyte interface by ToF-SIMS journal January 2014
Switchable 1,8-diazabicycloundec-7-ene and 1-hexanol ionic liquid analyzed by liquid ToF-SIMS journal June 2016
Evaluating Transformational Solvent Systems for Post-combustion CO2 Separations journal January 2014
Homogeneous Hydrogenation of CO 2 to Methyl Formate Utilizing Switchable Ionic Liquids journal August 2014
CO2 Capture by a Task-Specific Ionic Liquid journal February 2002
Switchable Ionic Liquids: An Environmentally Friendly Medium to Synthesise Nanoparticulate Green Rust journal June 2016
Organized 3D-alkyl imidazolium ionic liquids could be used to control the size of in situ generated ruthenium nanoparticles? journal January 2009
Synthesis of ammonia borane for hydrogen storage applications journal January 2008
Carbon Dioxide Capture by Superbase-Derived Protic Ionic Liquids journal July 2010
Dynamic Acid/Base Equilibrium in Single Component Switchable Ionic Liquids and Consequences on Viscosity journal April 2016

Cited By (6)

Dark air–liquid interfacial chemistry of glyoxal and hydrogen peroxide journal August 2019
Assessing the impacts of dynamic soft-templates innate to switchable ionic liquids on nanoparticulate green rust crystalline structures journal January 2019
From atoms to aerosols: probing clusters and nanoparticles with synchrotron based mass spectrometry and X-ray spectroscopy journal January 2020
Enabling liquid vapor analysis using synchrotron VUV single photon ionization mass spectrometry with a microfluidic interface journal November 2018
Enabling liquid solvent structure analysis using hard x-ray absorption spectroscopy with a transferrable microfluidic reactor journal April 2018
Effect of Ionic Composition on Physicochemical Properties of Mono-Ether Functional Ionic Liquids journal August 2019

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