Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes

Feaster, Jeremy T.; Shi, Chuan; Cave, Etosha R.; Hatsukade, Toru; Abram, David N.; Kuhl, Kendra P.; Hahn, Christopher; Nørskov, Jens K.; Jaramillo, Thomas F.

doi:10.1021/acscatal.7b00687

Title: Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes

Journal Article · Thu Jun 22 00:00:00 EDT 2017 · ACS Catalysis

DOI:https://doi.org/10.1021/acscatal.7b00687· OSTI ID:1390311

Feaster, Jeremy T. ^[1]; Shi, Chuan ^[1]; Cave, Etosha R. ^[2]; Hatsukade, Toru ^[1]; Abram, David N. ^[2]; Kuhl, Kendra P. ^[2];

^[1]; Nørskov, Jens K. ^[1];

^[1]

Stanford Univ., Stanford, CA (United States); SLAC National Accelerator Lab., Menlo Park, CA (United States)
Stanford Univ., Stanford, CA (United States)

Increases in energy demand and in chemical production, together with the rise in CO₂ levels in the atmosphere, motivate the development of renewable energy sources. Electrochemical CO₂ reduction to fuels and chemicals is an appealing alternative to traditional pathways to fuels and chemicals due to its intrinsic ability to couple to solar and wind energy sources. Formate (HCOO^–) is a key chemical for many industries; however, greater understanding is needed regarding the mechanism and key intermediates for HCOO^– production. This work reports a joint experimental and theoretical investigation of the electrochemical reduction of CO₂ to HCOO^– on polycrystalline Sn surfaces, which have been identified as promising catalysts for selectively producing HCOO^–. Our results show that Sn electrodes produce HCOO^–, carbon monoxide (CO), and hydrogen (H₂) across a range of potentials and that HCOO^– production becomes favored at potentials more negative than –0.8 V vs RHE, reaching a maximum Faradaic efficiency of 70% at –0.9 V vs RHE. Scaling relations for Sn and other transition metals are examined using experimental current densities and density functional theory (DFT) binding energies. While *COOH was determined to be the key intermediate for CO production on metal surfaces, we suggest that it is unlikely to be the primary intermediate for HCOO^– production. Instead, *OCHO is suggested to be the key intermediate for the CO₂RR to HCOO^– transformation, and Sn’s optimal *OCHO binding energy supports its high selectivity for HCOO^–. Lastly, these results suggest that oxygen-bound intermediates are critical to understand the mechanism of CO₂ reduction to HCOO^– on metal surfaces.

View Accepted Manuscript (DOE)

Cite

Export

Save

Research Organization:: SLAC National Accelerator Laboratory (SLAC), Menlo Park, CA (United States)

Sponsoring Organization:: USDOE

Grant/Contract Number:: AC02-76SF00515; 1066515

OSTI ID:: 1390311

Journal Information:: ACS Catalysis, Vol. 7, Issue 7; ISSN 2155-5435

Publisher:: American Chemical Society (ACS)Copyright Statement

Country of Publication:: United States

Language:: English

Citation Metrics:

Cited by: 539 works

Citation information provided by
Web of Science

References (37)

Modern Global Climate Change Karl, T. R. Science, Vol. 302, Issue 5651 https://doi.org/10.1126/science.1090228	journal	December 2003
Advanced Technology Paths to Global Climate Stability: Energy for a Greenhouse Planet Hoffert, M. I.; Caldeira, K.; Benford, G. Science, Vol. 298, Issue 5595 https://doi.org/10.1126/science.1072357	journal	November 2002
Carbon Dioxide Capture: Prospects for New Materials D'Alessandro, Deanna M.; Smit, Berend; Long, Jeffrey R. Angewandte Chemie International Edition, Vol. 49, Issue 35, p. 6058-6082 https://doi.org/10.1002/anie.201000431	journal	July 2010
Recent developments on carbon capture and storage: An overview Pires, J. C. M.; Martins, F. G.; Alvim-Ferraz, M. C. M. Chemical Engineering Research and Design, Vol. 89, Issue 9 https://doi.org/10.1016/j.cherd.2011.01.028	journal	September 2011
Prospects of CO₂ Utilization via Direct Heterogeneous Electrochemical Reduction Whipple, Devin T.; Kenis, Paul J. A. The Journal of Physical Chemistry Letters, Vol. 1, Issue 24, p. 3451-3458 https://doi.org/10.1021/jz1012627	journal	December 2010
Catalysis of the electrochemical reduction of carbon dioxide Costentin, Cyrille; Robert, Marc; Savéant, Jean-Michel Chem. Soc. Rev., Vol. 42, Issue 6 https://doi.org/10.1039/C2CS35360A	journal	January 2013
A selective and efficient electrocatalyst for carbon dioxide reduction Lu, Qi; Rosen, Jonathan; Zhou, Yang Nature Communications, Vol. 5, Issue 1 https://doi.org/10.1038/ncomms4242	journal	January 2014
The Electrochemical Reduction of Carbon Dioxide to Formate/Formic Acid: Engineering and Economic Feasibility Agarwal, Arun S.; Zhai, Yumei; Hill, Davion ChemSusChem, Vol. 4, Issue 9 https://doi.org/10.1002/cssc.201100220	journal	September 2011
Electrocatalytic process of CO selectivity in electrochemical reduction of CO₂ at metal electrodes in aqueous media Hori, Yoshio; Wakebe, Hidetoshi; Tsukamoto, Toshio Electrochimica Acta, Vol. 39, Issue 11-12, p. 1833-1839 https://doi.org/10.1016/0013-4686(94)85172-7	journal	August 1994
A review of the aqueous electrochemical reduction of CO₂ to hydrocarbons at copper Gattrell, M.; Gupta, N.; Co, A. Journal of Electroanalytical Chemistry, Vol. 594, Issue 1, p. 1-19 https://doi.org/10.1016/j.jelechem.2006.05.013	journal	August 2006
Electrocatalytic Conversion of Carbon Dioxide to Methane and Methanol on Transition Metal Surfaces Kuhl, Kendra P.; Hatsukade, Toru; Cave, Etosha R. Journal of the American Chemical Society, Vol. 136, Issue 40 https://doi.org/10.1021/ja505791r	journal	August 2014
Electrochemical reduction of carbon dioxide on flat metallic cathodes Jitaru, M.; Lowy, D. A.; Toma, M. Journal of Applied Electrochemistry, Vol. 27, Issue 8, p. 875-889 https://doi.org/10.1023/A:1018441316386	journal	January 1997
Tin Oxide Dependence of the CO ₂ Reduction Efficiency on Tin Electrodes and Enhanced Activity for Tin/Tin Oxide Thin-Film Catalysts Chen, Yihong; Kanan, Matthew W. Journal of the American Chemical Society, Vol. 134, Issue 4 https://doi.org/10.1021/ja2108799	journal	January 2012
Electrocatalytic reduction of CO2 gas at Sn based gas diffusion electrode Machunda, Revocatus L.; Ju, HyungKuK; Lee, Jaeyoung Current Applied Physics, Vol. 11, Issue 4 https://doi.org/10.1016/j.cap.2011.01.003	journal	July 2011
Electrochemical reduction of CO₂ over Sn-Nafion^® coated electrode for a fuel-cell-like device Prakash, G. K. Surya; Viva, Federico A.; Olah, George A. Journal of Power Sources, Vol. 223, p. 68-73 https://doi.org/10.1016/j.jpowsour.2012.09.036	journal	February 2013
Addressing the terawatt challenge: scalability in the supply of chemical elements for renewable energy Vesborg, Peter C. K.; Jaramillo, Thomas F. RSC Advances, Vol. 2, Issue 21 https://doi.org/10.1039/c2ra20839c	journal	January 2012
Effect of solution pH on CO: formate formation rates during electrochemical reduction of aqueous CO2 at Sn cathodes Bumroongsakulsawat, P.; Kelsall, G. H. Electrochimica Acta, Vol. 141 https://doi.org/10.1016/j.electacta.2014.07.057	journal	September 2014
Morphological Stability of Sn Electrode for Electrochemical Conversion of CO2 Wu, J.; Harris, B.; Sharma, P. P. ECS Transactions, Vol. 58, Issue 2 https://doi.org/10.1149/05802.0071ecst	journal	August 2013
Rational Design and Synthesis of SnO _x Electrocatalysts with Coralline Structure for Highly Improved Aqueous CO ₂ Reduction to Formate Li, Yanan; Qiao, Jinli; Zhang, Xia ChemElectroChem, Vol. 3, Issue 10 https://doi.org/10.1002/celc.201600290	journal	August 2016
Electrolytic Reduction of Carbon Dioxide at Mercury Electrode in Aqueous Solution Hori, Yoshio; Suzuki, Shin Bulletin of the Chemical Society of Japan, Vol. 55, Issue 3 https://doi.org/10.1246/bcsj.55.660	journal	March 1982
Kinetic studies of the electrolytic reduction of carbon dioxide on the mercury electrode Paik, W.; Andersen, T. N.; Eyring, H. Electrochimica Acta, Vol. 14, Issue 12 https://doi.org/10.1016/0013-4686(69)87019-2	journal	December 1969
How copper catalyzes the electroreduction of carbon dioxide into hydrocarbon fuels Peterson, Andrew A.; Abild-Pedersen, Frank; Studt, Felix Energy & Environmental Science, Vol. 3, Issue 9 https://doi.org/10.1039/c0ee00071j	journal	January 2010
Theoretical Insight into the Trends that Guide the Electrochemical Reduction of Carbon Dioxide to Formic Acid Yoo, Jong Suk; Christensen, Rune; Vegge, Tejs ChemSusChem, Vol. 9, Issue 4 https://doi.org/10.1002/cssc.201501197	journal	December 2015
New insights into the electrochemical reduction of carbon dioxide on metallic copper surfaces Kuhl, Kendra P.; Cave, Etosha R.; Abram, David N. Energy & Environmental Science, Vol. 5, Issue 5 https://doi.org/10.1039/c2ee21234j	journal	January 2012
Insights into the electrocatalytic reduction of CO ₂ on metallic silver surfaces Hatsukade, Toru; Kuhl, Kendra P.; Cave, Etosha R. Phys. Chem. Chem. Phys., Vol. 16, Issue 27 https://doi.org/10.1039/C4CP00692E	journal	January 2014
State of metallic phase in PtSn/Al2O3 catalysts prepared by different deposition techniques Baronetti, Graciela T.; de Miguel, Sergio R.; Scelza, Osvaldo A. Applied Catalysis, Vol. 24, Issue 1-2 https://doi.org/10.1016/S0166-9834(00)81261-0	journal	July 1986
Activity Descriptors for CO ₂ Electroreduction to Methane on Transition-Metal Catalysts Peterson, Andrew A.; Nørskov, Jens K. The Journal of Physical Chemistry Letters, Vol. 3, Issue 2 https://doi.org/10.1021/jz201461p	journal	January 2012
Soft self-consistent pseudopotentials in a generalized eigenvalue formalism Vanderbilt, David Physical Review B, Vol. 41, Issue 11, p. 7892-7895 https://doi.org/10.1103/PhysRevB.41.7892	journal	April 1990
Improved adsorption energetics within density-functional theory using revised Perdew-Burke-Ernzerhof functionals Hammer, B.; Hansen, L. B.; Nørskov, J. K. Physical Review B, Vol. 59, Issue 11 https://doi.org/10.1103/PhysRevB.59.7413	journal	March 1999
Special points for Brillouin-zone integrations Monkhorst, Hendrik J.; Pack, James D. Physical Review B, Vol. 13, Issue 12, p. 5188-5192 https://doi.org/10.1103/PhysRevB.13.5188	journal	June 1976
Nanostructured Tin Catalysts for Selective Electrochemical Reduction of Carbon Dioxide to Formate Zhang, Sheng; Kang, Peng; Meyer, Thomas J. Journal of the American Chemical Society, Vol. 136, Issue 5 https://doi.org/10.1021/ja4113885	journal	January 2014
Electrochemical Reduction of Carbon Dioxide I. Effects of the Electrolyte on the Selectivity and Activity with Sn Electrode Wu, Jingjie; Risalvato, Frank G.; Ke, Fu-Sheng Journal of The Electrochemical Society, Vol. 159, Issue 7 https://doi.org/10.1149/2.049207jes	journal	January 2012
Mechanistic Insights into the Reduction of CO ₂ on Tin Electrodes using in Situ ATR-IR Spectroscopy Baruch, Maor F.; Pander, James E.; White, James L. ACS Catalysis, Vol. 5, Issue 5 https://doi.org/10.1021/acscatal.5b00402	journal	March 2015
Trends in electrochemical CO2 reduction activity for open and close-packed metal surfaces Shi, Chuan; Hansen, Heine A.; Lausche, Adam C. Physical Chemistry Chemical Physics, Vol. 16, Issue 10 https://doi.org/10.1039/c3cp54822h	journal	January 2014
Structure effects on the energetics of the electrochemical reduction of CO2 by copper surfaces Durand, William J.; Peterson, Andrew A.; Studt, Felix Surface Science, Vol. 605, Issue 15-16 https://doi.org/10.1016/j.susc.2011.04.028	journal	August 2011
Electric Field Effects in Electrochemical CO ₂ Reduction Chen, Leanne D.; Urushihara, Makoto; Chan, Karen ACS Catalysis, Vol. 6, Issue 10 https://doi.org/10.1021/acscatal.6b02299	journal	September 2016
Monitoring the Chemical State of Catalysts for CO ₂ Electroreduction: An In Operando Study Dutta, Abhijit; Kuzume, Akiyoshi; Rahaman, Motiar ACS Catalysis, Vol. 5, Issue 12 https://doi.org/10.1021/acscatal.5b02322	journal	November 2015

Cited By (57)

High Selectivity Towards Formate Production by Electrochemical Reduction of Carbon Dioxide at Copper–Bismuth Dendrites Hoffman, Zachary B.; Gray, Tristan S.; Xu, Yin ChemSusChem, Vol. 12, Issue 1 https://doi.org/10.1002/cssc.201801708	journal	November 2018
Electrochemical Conversion of CO ₂ to Syngas with Controllable CO/H ₂ Ratios over Co and Ni Single‐Atom Catalysts He, Qun; Liu, Daobin; Lee, Ji Hoon Angewandte Chemie, Vol. 132, Issue 8 https://doi.org/10.1002/ange.201912719	journal	January 2020
Copper and Copper-Based Bimetallic Catalysts for Carbon Dioxide Electroreduction Birhanu, Mulatu Kassie; Tsai, Meng-Che; Kahsay, Amaha Woldu Advanced Materials Interfaces, Vol. 5, Issue 24 https://doi.org/10.1002/admi.201800919	journal	October 2018
Chelating N-Heterocyclic Carbene Ligands Enable Tuning of Electrocatalytic CO ₂ Reduction to Formate and Carbon Monoxide: Surface Organometallic Chemistry Cao, Zhi; Derrick, Jeffrey S.; Xu, Jun Angewandte Chemie, Vol. 130, Issue 18 https://doi.org/10.1002/ange.201800367	journal	March 2018
Copper-modulated bismuth nanocrystals alter the formate formation pathway to achieve highly selective CO ₂ electroreduction Zu, Meng Yang; Zhang, Le; Wang, Chongwu Journal of Materials Chemistry A, Vol. 6, Issue 35 https://doi.org/10.1039/c8ta05355c	journal	January 2018
Electrocatalytic conversion of carbon dioxide to formic acid over nanosized Cu ₆ Sn ₅ intermetallic compounds with a SnO ₂ shell layer Gunji, Takao; Ochiai, Hiroya; Isawa, Yu Catalysis Science & Technology, Vol. 9, Issue 23 https://doi.org/10.1039/c9cy01540j	journal	January 2019
Electrochemical Carbon Dioxide Splitting Xie, Jiafang; Huang, Yiyin; Wu, Maoxiang ChemElectroChem, Vol. 6, Issue 6 https://doi.org/10.1002/celc.201801716	journal	February 2019
2D Metal Oxyhalide-Derived Catalysts for Efficient CO ₂ Electroreduction García de Arquer, F. Pelayo; Bushuyev, Oleksandr S.; De Luna, Phil Advanced Materials, Vol. 30, Issue 38 https://doi.org/10.1002/adma.201802858	journal	August 2018
Bronze alloys with tin surface sites for selective electrochemical reduction of CO ₂ Vasileff, Anthony; Xu, Chaochen; Ge, Lei Chemical Communications, Vol. 54, Issue 99 https://doi.org/10.1039/c8cc08066f	journal	January 2018
A Co–N ₄ moiety embedded into graphene as an efficient single-atom-catalyst for NO electrochemical reduction: a computational study Wang, Zhongxu; Zhao, Jingxiang; Wang, Jingyang Journal of Materials Chemistry A, Vol. 6, Issue 17 https://doi.org/10.1039/c8ta00875b	journal	January 2018
Structure‐Sensitivity and Electrolyte Effects in CO ₂ Electroreduction: From Model Studies to Applications Sebastián‐Pascual, Paula; Mezzavilla, Stefano; Stephens, Ifan E. L. ChemCatChem, Vol. 11, Issue 16 https://doi.org/10.1002/cctc.201900552	journal	June 2019
Design of naturally derived lead phytate as an electrocatalyst for highly efficient CO ₂ reduction to formic acid Wu, Haoran; Song, Jinliang; Xie, Chao Green Chemistry, Vol. 20, Issue 20 https://doi.org/10.1039/c8gc02457j	journal	January 2018
Metal-based heterogeneous electrocatalysts for reduction of carbon dioxide and nitrogen: mechanisms, recent advances and perspective Zhou, Jun-Hao; Zhang, Ya-Wen Reaction Chemistry & Engineering, Vol. 3, Issue 5 https://doi.org/10.1039/c8re00111a	journal	January 2018
The effects of currents and potentials on the selectivities of copper toward carbon dioxide electroreduction Ren, Dan; Fong, Jinhuan; Yeo, Boon Siang Nature Communications, Vol. 9, Issue 1 https://doi.org/10.1038/s41467-018-03286-w	journal	March 2018
C ₂ N-graphene supported single-atom catalysts for CO ₂ electrochemical reduction reaction: mechanistic insight and catalyst screening Cui, Xudong; An, Wei; Liu, Xiaoyang Nanoscale, Vol. 10, Issue 32 https://doi.org/10.1039/c8nr04961k	journal	January 2018
Hybridization of Defective Tin Disulfide Nanosheets and Silver Nanowires Enables Efficient Electrochemical Reduction of CO ₂ into Formate and Syngas He, Rong; Yuan, Xin; Shao, Pengfei Small, Vol. 15, Issue 50 https://doi.org/10.1002/smll.201904882	journal	October 2019
Progress in development of electrocatalyst for CO ₂ conversion to selective CO production Nguyen, Dang Le Tri; Kim, Younghye; Hwang, Yun Jeong Carbon Energy, Vol. 2, Issue 1 https://doi.org/10.1002/cey2.27	journal	March 2020
Formic Acid Manufacture: Carbon Dioxide Utilization Alternatives Rumayor, Marta; Dominguez-Ramos, Antonio; Irabien, Angel Applied Sciences, Vol. 8, Issue 6 https://doi.org/10.3390/app8060914	journal	June 2018
Orbital Interactions in Bi-Sn Bimetallic Electrocatalysts for Highly Selective Electrochemical CO ₂ Reduction toward Formate Production Wen, Guobin; Lee, Dong Un; Ren, Bohua Advanced Energy Materials, Vol. 8, Issue 31 https://doi.org/10.1002/aenm.201802427	journal	September 2018
Tuning Gold Nanoparticles with Chelating Ligands for Highly Efficient Electrocatalytic CO 2 Reduction Cao, Zhi; Zacate, Samson B.; Sun, Xiaodong Angewandte Chemie, Vol. 130, Issue 39 https://doi.org/10.1002/ange.201805696	journal	August 2018
Heterogeneous catalysts for catalytic CO2 conversion into value-added chemicals Whang, Ho Seok; Lim, Jinkyu; Choi, Min Suk BMC Chemical Engineering, Vol. 1, Issue 1 https://doi.org/10.1186/s42480-019-0007-7	journal	March 2019
Insight into the Formation and Transfer Process of the First Intermediate of CO ₂ Reduction over Ag‐Decorated Dendritic Cu Yang, Yang; Ajmal, Saira; Feng, Yiqing Chemistry – A European Journal https://doi.org/10.1002/chem.201904063	journal	October 2019
Electrochemical Reduction of CO ₂ over Heterogeneous Catalysts in Aqueous Solution: Recent Progress and Perspectives Long, Chang; Li, Xiang; Guo, Jun Small Methods https://doi.org/10.1002/smtd.201800369	journal	December 2018
Designing materials for electrochemical carbon dioxide recycling Ross, Michael B.; De Luna, Phil; Li, Yifan Nature Catalysis, Vol. 2, Issue 8 https://doi.org/10.1038/s41929-019-0306-7	journal	July 2019
On the Mechanism of Carbon Dioxide Reduction on Sn-Based Electrodes: Insights into the Role of Oxide Surfaces Damas, Giane B.; Miranda, Caetano R.; Sgarbi, Ricardo Catalysts, Vol. 9, Issue 8 https://doi.org/10.3390/catal9080636	journal	July 2019
Strategies for Designing Nanoparticles for Electro‐ and Photocatalytic CO ₂ Reduction Choi, Ji Yong; Choi, Woong; Park, Joon Woo Chemistry – An Asian Journal, Vol. 15, Issue 2 https://doi.org/10.1002/asia.201901533	journal	December 2019
Conversion of Carbon Dioxide into Formic Acid Fegade, Umesh; Jethave, Ganesh Conversion of Carbon Dioxide into Hydrocarbons Vol. 2 Technology, p. 91-110 https://doi.org/10.1007/978-3-030-28638-5_4	book	November 2019
On the origin of the elusive first intermediate of CO ₂ electroreduction Chernyshova, Irina V.; Somasundaran, Ponisseril; Ponnurangam, Sathish Proceedings of the National Academy of Sciences, Vol. 115, Issue 40 https://doi.org/10.1073/pnas.1802256115	journal	September 2018
Electrochemical Reduction of CO ₂ on Nitrogen‐Doped Carbon Catalysts With and Without Iron Silva, Wanderson O.; Silva, Gabriel C.; Webster, Richard F. ChemElectroChem, Vol. 6, Issue 17 https://doi.org/10.1002/celc.201901144	journal	August 2019
Advances and challenges in electrochemical CO ₂ reduction processes: an engineering and design perspective looking beyond new catalyst materials Garg, Sahil; Li, Mengran; Weber, Adam Z. Journal of Materials Chemistry A, Vol. 8, Issue 4 https://doi.org/10.1039/c9ta13298h	journal	January 2020
Theory-guided Sn/Cu alloying for efficient CO2 electroreduction at low overpotentials Zheng, Xueli; Ji, Yongfei; Tang, Jing Nature Catalysis, Vol. 2, Issue 1 https://doi.org/10.1038/s41929-018-0200-8	journal	December 2018
Chelating N-Heterocyclic Carbene Ligands Enable Tuning of Electrocatalytic CO ₂ Reduction to Formate and Carbon Monoxide: Surface Organometallic Chemistry Cao, Zhi; Derrick, Jeffrey S.; Xu, Jun Angewandte Chemie International Edition, Vol. 57, Issue 18 https://doi.org/10.1002/anie.201800367	journal	March 2018
Cyclic two-step electrolysis for stable electrochemical conversion of carbon dioxide to formate Lee, Chan Woo; Cho, Nam Heon; Nam, Ki Tae Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-11903-5	journal	September 2019
Electrochemical CO ₂ Reduction: A Classification Problem Bagger, Alexander; Ju, Wen; Varela, Ana Sofia ChemPhysChem, Vol. 18, Issue 22 https://doi.org/10.1002/cphc.201700736	journal	October 2017
Zn nanosheets coated with a ZnS subnanometer layer for effective and durable CO ₂ reduction Li, Chenglong; Shen, Gurong; Zhang, Rui Journal of Materials Chemistry A, Vol. 7, Issue 4 https://doi.org/10.1039/c8ta10799h	journal	January 2019
Electrocatalytic Reduction of Gaseous CO ₂ to CO on Sn/Cu‐Nanofiber‐Based Gas Diffusion Electrodes Ju, Wenbo; Jiang, Fuze; Ma, Huan Advanced Energy Materials, Vol. 9, Issue 32 https://doi.org/10.1002/aenm.201901514	journal	July 2019
Conversion of Carbon Dioxide Using Lead/Composite/Oxide Electrode into Formate/Formic Acid An, Xiaowei; Yoshida, Akihiro; Abudula, Abuliti Conversion of Carbon Dioxide into Hydrocarbons Vol. 1 Catalysis, p. 25-42 https://doi.org/10.1007/978-3-030-28622-4_2	book	January 2020
Advanced engineering of core/shell nanostructures for electrochemical carbon dioxide reduction Shao, Qi; Wang, Pengtang; Liu, Shangheng Journal of Materials Chemistry A, Vol. 7, Issue 36 https://doi.org/10.1039/c9ta07016h	journal	January 2019
Recent advances in the nanoengineering of electrocatalysts for CO ₂ reduction Li, Fengwang; MacFarlane, Douglas R.; Zhang, Jie Nanoscale, Vol. 10, Issue 14 https://doi.org/10.1039/c7nr09620h	journal	January 2018
Recent Progress in the Theoretical Investigation of Electrocatalytic Reduction of CO ₂ Tian, Ziqi; Priest, Chad; Chen, Liang Advanced Theory and Simulations, Vol. 1, Issue 5 https://doi.org/10.1002/adts.201800004	journal	April 2018
Stepped surface-rich copper fiber felt as an efficient electrocatalyst for the CO ₂ RR to formate Shen, Sibo; He, Jia; Peng, Xianyun Journal of Materials Chemistry A, Vol. 6, Issue 39 https://doi.org/10.1039/c8ta04758h	journal	January 2018
Theory-guided materials design: two-dimensional MXenes in electro- and photocatalysis Handoko, Albertus D.; Steinmann, Stephan N.; Seh, Zhi Wei Nanoscale Horizons, Vol. 4, Issue 4 https://doi.org/10.1039/c9nh00100j	journal	January 2019
Ultrathin Bismuth Nanosheets as a Highly Efficient CO ₂ Reduction Electrocatalyst Su, Panpan; Xu, Wenbin; Qiu, Yanling ChemSusChem, Vol. 11, Issue 5 https://doi.org/10.1002/cssc.201702229	journal	January 2018
Tuning Sn-Cu Catalysis for Electrochemical Reduction of CO2 on Partially Reduced Oxides SnOx-CuOx-Modified Cu Electrodes Li, Qianwen; Li, Mei; Zhang, Shengbo Catalysts, Vol. 9, Issue 5 https://doi.org/10.3390/catal9050476	journal	May 2019
Colloidal silver diphosphide (AgP2) nanocrystals as low overpotential catalysts for CO2 reduction to tunable syngas Li, Hui; Wen, Peng; Itanze, Dominique S. Nature Communications, Vol. 10, Issue 1 https://doi.org/10.1038/s41467-019-13388-8	journal	December 2019
A mechanistic study of B ₃₆ -supported atomic Au promoted CO ₂ electroreduction to formic acid Li, Wen-Ying; Zhao, Xiang; Dang, Jing-Shuang Journal of Materials Chemistry A, Vol. 7, Issue 23 https://doi.org/10.1039/c9ta03983j	journal	January 2019
New aspects of operando Raman spectroscopy applied to electrochemical CO ₂ reduction on Cu foams Jiang, Shan; Klingan, Katharina; Pasquini, Chiara The Journal of Chemical Physics, Vol. 150, Issue 4 https://doi.org/10.1063/1.5054109	journal	January 2019
Electrochemical Conversion of CO ₂ to Syngas with Controllable CO/H ₂ Ratios over Co and Ni Single-Atom Catalysts He, Qun; Liu, Daobin; Lee, Ji Hoon Angewandte Chemie International Edition, Vol. 59, Issue 8 https://doi.org/10.1002/anie.201912719	journal	January 2020
Lateral Adsorbate Interactions Inhibit HCOO ⁻ while Promoting CO Selectivity for CO ₂ Electrocatalysis on Silver Bohra, Divya; Ledezma-Yanez, Isis; Li, Guanna Angewandte Chemie, Vol. 131, Issue 5 https://doi.org/10.1002/ange.201811667	journal	December 2018
Promises of Main Group Metal–Based Nanostructured Materials for Electrochemical CO ₂ Reduction to Formate Han, Na; Ding, Pan; He, Le Advanced Energy Materials, Vol. 10, Issue 11 https://doi.org/10.1002/aenm.201902338	journal	November 2019
Electrochemical CO ₂ Reduction on Bimetallic Surface Alloys: Enhanced Selectivity to CO for Co/Au(110) and to H ₂ for Sn/Au(110) Todoroki, Naoto; Tei, Hiroki; Miyakawa, Taku ChemElectroChem, Vol. 6, Issue 12 https://doi.org/10.1002/celc.201900725	journal	May 2019
Tuning Gold Nanoparticles with Chelating Ligands for Highly Efficient Electrocatalytic CO 2 Reduction Cao, Zhi; Zacate, Samson B.; Sun, Xiaodong Angewandte Chemie International Edition, Vol. 57, Issue 39 https://doi.org/10.1002/anie.201805696	journal	August 2018
Lateral Adsorbate Interactions Inhibit HCOO ⁻ while Promoting CO Selectivity for CO ₂ Electrocatalysis on Silver Bohra, Divya; Ledezma‐Yanez, Isis; Li, Guanna Angewandte Chemie International Edition, Vol. 58, Issue 5 https://doi.org/10.1002/anie.201811667	journal	January 2019
Inside Cover: Electrochemical Conversion of CO ₂ to Syngas with Controllable CO/H ₂ Ratios over Co and Ni Single‐Atom Catalysts (Angew. Chem. Int. Ed. 8/2020) He, Qun; Liu, Daobin; Lee, Ji Hoon Angewandte Chemie International Edition, Vol. 59, Issue 8 https://doi.org/10.1002/anie.202000296	journal	February 2020
High Pressure Electrochemical Reduction of CO ₂ to Formic Acid/Formate: A Comparison between Bipolar Membranes and Cation Exchange Membranes Ramdin, Mahinder; Morrison, Andrew R. T.; de Groen, Mariette Industrial & Engineering Chemistry Research, Vol. 58, Issue 5 https://doi.org/10.1021/acs.iecr.8b04944	journal	January 2019
Theoretical insights into selective electrochemical conversion of carbon dioxide Lee, Chan Woo; Kim, Chanyeon; Min, Byoung Koun Nano Convergence, Vol. 6, Issue 1 https://doi.org/10.1186/s40580-019-0177-2	journal	March 2019
On-Surface Modification of Copper Cathodes by Copper(I)-Catalyzed Azide Alkyne Cycloaddition and CO2 Reduction in Organic Environments Igarashi, Ryota; Takeuchi, Ryuji; Kubo, Kazuyuki Frontiers in Chemistry, Vol. 7 https://doi.org/10.3389/fchem.2019.00860	journal	December 2019

Similar Records

Promotional effect of surface hydroxyls on electrochemical reduction of CO2 over SnOx/Sn electrode

Journal Article · Tue Nov 01 00:00:00 EDT 2016 · Journal of Catalysis · OSTI ID:1390311

Cui, Chaonan; Han, Jinyu; Zhu, Xinli; +4 more

Promotional effect of surface hydroxyls on electrochemical reduction of CO₂ over SnO_x/Sn electrode

Journal Article · Sat Jan 16 00:00:00 EST 2016 · Journal of Catalysis · OSTI ID:1390311

Cui, Chaonan; Han, Jinyu; Zhu, Xinli; +4 more

Investigating the Nature of the Active Sites for the CO₂ Reduction Reaction on Carbon-Based Electrocatalysts

Journal Article · Mon Jul 08 00:00:00 EDT 2019 · ACS Catalysis · OSTI ID:1390311

Asset, Tristan; Garcia, Samuel T.; Herrera, Sergio; +12 more

Related Subjects

37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY
carbon monoxide
CO2 reduction
electrocatalysis
formate
Sn
tin

Title: Understanding Selectivity for the Electrochemical Reduction of Carbon Dioxide to Formic Acid and Carbon Monoxide on Metal Electrodes

Citation Formats

References (37)

Cited By (57)

Similar Records

Related Subjects