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Title: Methods and apparatuses for deoxygenating pyrolysis oil

Abstract

Methods and apparatuses are provided for deoxygenating pyrolysis oil. A method includes contacting a pyrolysis oil with a deoxygenation catalyst in a first reactor at deoxygenation conditions to produce a first reactor effluent. The first reactor effluent has a first oxygen concentration and a first hydrogen concentration, based on hydrocarbons in the first reactor effluent, and the first reactor effluent includes an aromatic compound. The first reactor effluent is contacted with a dehydrogenation catalyst in a second reactor at conditions that deoxygenate the first reactor effluent while preserving the aromatic compound to produce a second reactor effluent. The second reactor effluent has a second oxygen concentration lower than the first oxygen concentration and a second hydrogen concentration that is equal to or lower than the first hydrogen concentration, where the second oxygen concentration and the second hydrogen concentration are based on the hydrocarbons in the second reactor effluent.

Inventors:
; ;
Publication Date:
Research Org.:
UOP LLC. Des Plaines, IL (United States)
Sponsoring Org.:
USDOE
OSTI Identifier:
1390227
Patent Number(s):
9,758,441
Application Number:
14/551,797
Assignee:
UOP LLC DOEEE
DOE Contract Number:  
EE0002879
Resource Type:
Patent
Resource Relation:
Patent File Date: 2014 Nov 24
Country of Publication:
United States
Language:
English
Subject:
37 INORGANIC, ORGANIC, PHYSICAL, AND ANALYTICAL CHEMISTRY; 09 BIOMASS FUELS

Citation Formats

Baird, Lance Awender, Brandvold, Timothy A., and Frey, Stanley Joseph. Methods and apparatuses for deoxygenating pyrolysis oil. United States: N. p., 2017. Web.
Baird, Lance Awender, Brandvold, Timothy A., & Frey, Stanley Joseph. Methods and apparatuses for deoxygenating pyrolysis oil. United States.
Baird, Lance Awender, Brandvold, Timothy A., and Frey, Stanley Joseph. Tue . "Methods and apparatuses for deoxygenating pyrolysis oil". United States. doi:. https://www.osti.gov/servlets/purl/1390227.
@article{osti_1390227,
title = {Methods and apparatuses for deoxygenating pyrolysis oil},
author = {Baird, Lance Awender and Brandvold, Timothy A. and Frey, Stanley Joseph},
abstractNote = {Methods and apparatuses are provided for deoxygenating pyrolysis oil. A method includes contacting a pyrolysis oil with a deoxygenation catalyst in a first reactor at deoxygenation conditions to produce a first reactor effluent. The first reactor effluent has a first oxygen concentration and a first hydrogen concentration, based on hydrocarbons in the first reactor effluent, and the first reactor effluent includes an aromatic compound. The first reactor effluent is contacted with a dehydrogenation catalyst in a second reactor at conditions that deoxygenate the first reactor effluent while preserving the aromatic compound to produce a second reactor effluent. The second reactor effluent has a second oxygen concentration lower than the first oxygen concentration and a second hydrogen concentration that is equal to or lower than the first hydrogen concentration, where the second oxygen concentration and the second hydrogen concentration are based on the hydrocarbons in the second reactor effluent.},
doi = {},
journal = {},
number = ,
volume = ,
place = {United States},
year = {Tue Sep 12 00:00:00 EDT 2017},
month = {Tue Sep 12 00:00:00 EDT 2017}
}

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