Partial breaking of the Coulombic ordering of ionic liquids confined in carbon nanopores

Futamura, Ryusuke; Iiyama, Taku; Takasaki, Yuma; Gogotsi, Yury; Biggs, Mark J.; Salanne, Mathieu; Ségalini, Julie; Simon, Patrice; Kaneko, Katsumi

doi:10.1038/NMAT4974

Title: Partial breaking of the Coulombic ordering of ionic liquids confined in carbon nanopores

Journal Article · Mon Sep 18 00:00:00 EDT 2017 · Nature Materials

DOI:https://doi.org/10.1038/NMAT4974· OSTI ID:1389046

Futamura, Ryusuke; Iiyama, Taku; Takasaki, Yuma; Gogotsi, Yury; Biggs, Mark J.;

; Ségalini, Julie; Simon, Patrice; Kaneko, Katsumi

Cite

Export

Save

Research Organization:: Energy Frontier Research Centers (EFRC) (United States). Fluid Interface Reactions, Structures and Transport Center (FIRST)

Sponsoring Organization:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

DOE Contract Number:: ERKCC61

OSTI ID:: 1389046

Journal Information:: Nature Materials, Vol. 16, Issue 12; Related Information: FIRST partners with Oak Ridge National Laboratory (lead); Argonne National Laboratory; Drexel University; Georgia State University; Northwestern University; Pennsylvania State University; Suffolk University; Vanderbilt University; University of Virginia; ISSN 1476-1122

Publisher:: Nature Publishing Group

Country of Publication:: United States

Language:: English

References (57)

A superionic state in nano-porous double-layer capacitors: insights from Monte Carlo simulations Kondrat, S.; Georgi, N.; Fedorov, M. V. Physical Chemistry Chemical Physics, Vol. 13, Issue 23 https://doi.org/10.1039/c1cp20798a	journal	January 2011
Molecular Layering of Fluorinated Ionic Liquids at a Charged Sapphire (0001) Surface Mezger, M.; Schroder, H.; Reichert, H. Science, Vol. 322, Issue 5900 https://doi.org/10.1126/science.1164502	journal	October 2008
Hydration and mobility of ions in solution Impey, R. W.; Madden, P. A.; McDonald, I. R. The Journal of Physical Chemistry, Vol. 87, Issue 25 https://doi.org/10.1021/j150643a008	journal	December 1983
Ionic-liquid materials for the electrochemical challenges of the future Armand, Michel; Endres, Frank; MacFarlane, Douglas R. Nature Materials, Vol. 8, Issue 8, p. 621-629 https://doi.org/10.1038/nmat2448	journal	July 2009
Anomalous Increase in Carbon Capacitance at Pore Sizes Less Than 1 Nanometer Chmiola, J. Science, Vol. 313, Issue 5794 https://doi.org/10.1126/science.1132195	journal	September 2006
Accelerating charging dynamics in subnanometre pores Kondrat, Svyatoslav; Wu, Peng; Qiao, Rui Nature Materials, Vol. 13, Issue 4 https://doi.org/10.1038/nmat3916	journal	March 2014
Specific Ion Effects at the Air/Water Interface Jungwirth, Pavel; Tobias, Douglas J. Chemical Reviews, Vol. 106, Issue 4 https://doi.org/10.1021/cr0403741	journal	April 2006
Ion Dynamics in Porous Carbon Electrodes in Supercapacitors Using in Situ Infrared Spectroelectrochemistry Richey, Francis W.; Dyatkin, Boris; Gogotsi, Yury Journal of the American Chemical Society, Vol. 135, Issue 34 https://doi.org/10.1021/ja406120e	journal	August 2013
Molecular Assembly Structure of CCl ₄ in Graphitic Nanospaces Iiyama, T.; Nishikawa, K.; Suzuki, T. The Journal of Physical Chemistry B, Vol. 101, Issue 16 https://doi.org/10.1021/jp962408h	journal	April 1997
Densification of Ionic Liquid Molecules within a Hierarchical Nanoporous Carbon Structure Revealed by Small-Angle Scattering and Molecular Dynamics Simulation Bañuelos, José Leobardo; Feng, Guang; Fulvio, Pasquale F. Chemistry of Materials, Vol. 26, Issue 2 https://doi.org/10.1021/cm4035159	journal	December 2013
Electrochemical Quartz Crystal Microbalance (EQCM) Study of Ion Dynamics in Nanoporous Carbons Tsai, Wan-Yu; Taberna, Pierre-Louis; Simon, Patrice Journal of the American Chemical Society, Vol. 136, Issue 24 https://doi.org/10.1021/ja503449w	journal	June 2014
Extracting Renewable Energy from a Salinity Difference Using a Capacitor Brogioli, Doriano Physical Review Letters, Vol. 103, Issue 5 https://doi.org/10.1103/PhysRevLett.103.058501	journal	July 2009
CL&P: A generic and systematic force field for ionic liquids modeling Canongia Lopes, José N.; Pádua, Agílio A. H. Theoretical Chemistry Accounts, Vol. 131, Issue 3 https://doi.org/10.1007/s00214-012-1129-7	journal	February 2012
Carbide-Derived Carbons - From Porous Networks to Nanotubes and Graphene Presser, Volker; Heon, Min; Gogotsi, Yury Advanced Functional Materials, Vol. 21, Issue 5 https://doi.org/10.1002/adfm.201002094	journal	February 2011
Vertically Oriented Propylene Carbonate Molecules and Tetraethyl Ammonium Ions in Carbon Slit Pores Fukano, Masafumi; Fujimori, Toshihiko; Ségalini, Julie The Journal of Physical Chemistry C, Vol. 117, Issue 11 https://doi.org/10.1021/jp311896q	journal	March 2013
Ionic Liquids at Electrified Interfaces Fedorov, Maxim V.; Kornyshev, Alexei A. Chemical Reviews, Vol. 114, Issue 5 https://doi.org/10.1021/cr400374x	journal	March 2014
Transition Metal Carbides and Nitrides in Energy Storage and Conversion Zhong, Yu; Xia, Xinhui; Shi, Fan Advanced Science, Vol. 3, Issue 5 https://doi.org/10.1002/advs.201500286	journal	February 2016
Effect of a Quaternary Ammonium Salt on Propylene Carbonate Structure in Slit-Shape Carbon Nanopores Tanaka, Akimi; Iiyama, Taku; Ohba, Tomonori Journal of the American Chemical Society, Vol. 132, Issue 7 https://doi.org/10.1021/ja9087874	journal	February 2010
Materials for electrochemical capacitors Simon, Patrice; Gogotsi, Yury Nature Materials, Vol. 7, Issue 11 https://doi.org/10.1038/nmat2297	journal	November 2008
Ordering layers of [bmim][PF6] ionic liquid on graphite surfaces: Molecular dynamics simulation Maolin, Sha; Fuchun, Zhang; Guozhong, Wu The Journal of Chemical Physics, Vol. 128, Issue 13 https://doi.org/10.1063/1.2898497	journal	April 2008
In situ crystallization of ionic liquids with melting points below −25 °C Choudhury, Angshuman R.; Winterton, Neil; Steiner, Alexander CrystEngComm, Vol. 8, Issue 10 https://doi.org/10.1039/B609598D	journal	January 2006
Structural analysis of carbonaceous solids using an adapted reverse Monte Carlo algorithm Petersen, Tim; Yarovsky, Irene; Snook, Ian Carbon, Vol. 41, Issue 12 https://doi.org/10.1016/S0008-6223(03)00296-3	journal	January 2003
On the molecular origin of supercapacitance in nanoporous carbon electrodes Merlet, Céline; Rotenberg, Benjamin; Madden, Paul A. Nature Materials, Vol. 11, Issue 4 https://doi.org/10.1038/nmat3260	journal	March 2012
Exploring electrolyte organization in supercapacitor electrodes with solid-state NMR Deschamps, Michaël; Gilbert, Edouard; Azais, Philippe Nature Materials, Vol. 12, Issue 4 https://doi.org/10.1038/nmat3567	journal	February 2013
In Situ Electrochemical Quartz Crystal Admittance Methodology for Tracking Compositional and Mechanical Changes in Porous Carbon Electrodes Levi, Mikhael D.; Sigalov, Sergey; Aurbach, Doron The Journal of Physical Chemistry C, Vol. 117, Issue 29 https://doi.org/10.1021/jp403065y	journal	June 2013
Solvent effect on the ion adsorption from ionic liquid electrolyte into sub-nanometer carbon pores Lin, R.; Huang, P.; Ségalini, J. Electrochimica Acta, Vol. 54, Issue 27 https://doi.org/10.1016/j.electacta.2009.07.015	journal	November 2009
Nuclear magnetic resonance study of ion adsorption on microporous carbide-derived carbon Forse, Alexander C.; Griffin, John M.; Wang, Hao Physical Chemistry Chemical Physics, Vol. 15, Issue 20 https://doi.org/10.1039/c3cp51210j	journal	January 2013
Modeling the structural evolution of carbide-derived carbons using quenched molecular dynamics Palmer, J. C.; Llobet, A.; Yeon, S. -H. Carbon, Vol. 48, Issue 4 https://doi.org/10.1016/j.carbon.2009.11.033	journal	April 2010
Quantification of ion confinement and desolvation in nanoporous carbon supercapacitors with modelling and in situ X-ray scattering Prehal, C.; Koczwara, C.; Jäckel, N. Nature Energy, Vol. 2, Issue 3 https://doi.org/10.1038/nenergy.2016.215	journal	January 2017
Superionic state in double-layer capacitors with nanoporous electrodes Kondrat, S.; Kornyshev, A. Journal of Physics: Condensed Matter, Vol. 23, Issue 2 https://doi.org/10.1088/0953-8984/23/2/022201	journal	December 2010
Liquid Structure of Room-Temperature Ionic Liquid, 1-Ethyl-3-methylimidazolium Bis-(trifluoromethanesulfonyl) Imide Fujii, Kenta; Soejima, Yasufumi; Kyoshoin, Yasuhiro The Journal of Physical Chemistry B, Vol. 112, Issue 14 https://doi.org/10.1021/jp7105499	journal	April 2008
Highly confined ions store charge more efficiently in supercapacitors Merlet, C.; Péan, C.; Rotenberg, B. Nature Communications, Vol. 4, Issue 1 https://doi.org/10.1038/ncomms3701	journal	October 2013
The physical interaction of gases with crystalline solids Steele, William A. Surface Science, Vol. 36, Issue 1 https://doi.org/10.1016/0039-6028(73)90264-1	journal	April 1973
Ionic liquids in confined geometries Perkin, Susan Physical Chemistry Chemical Physics, Vol. 14, Issue 15 https://doi.org/10.1039/c2cp23814d	journal	January 2012
Supercapacitor Capacitance Exhibits Oscillatory Behavior as a Function of Nanopore Size Feng, Guang; Cummings, Peter T. The Journal of Physical Chemistry Letters, Vol. 2, Issue 22 https://doi.org/10.1021/jz201312e	journal	October 2011
Restricted Hydration Structures of Rb and Br Ions Confined in Slit-Shaped Carbon Nanospace Ohkubo, Takahiro; Konishi, Takehisa; Hattori, Yoshiyuki Journal of the American Chemical Society, Vol. 124, Issue 40 https://doi.org/10.1021/ja027144t	journal	October 2002
NMR Study of Ion Dynamics and Charge Storage in Ionic Liquid Supercapacitors Forse, Alexander C.; Griffin, John M.; Merlet, Céline Journal of the American Chemical Society, Vol. 137, Issue 22 https://doi.org/10.1021/jacs.5b03958	journal	May 2015
On the Dynamics of Charging in Nanoporous Carbon-Based Supercapacitors Péan, Clarisse; Merlet, Céline; Rotenberg, Benjamin ACS Nano, Vol. 8, Issue 2 https://doi.org/10.1021/nn4058243	journal	January 2014
Structure and Nanostructure in Ionic Liquids Hayes, Robert; Warr, Gregory G.; Atkin, Rob Chemical Reviews, Vol. 115, Issue 13 https://doi.org/10.1021/cr500411q	journal	June 2015
Nanostructural Organization in Ionic Liquids Canongia Lopes, José N. A.; Pádua, Agílio A. H. The Journal of Physical Chemistry B, Vol. 110, Issue 7 https://doi.org/10.1021/jp056006y	journal	February 2006
Double Layer in Ionic Liquids: Overscreening versus Crowding Bazant, Martin Z.; Storey, Brian D.; Kornyshev, Alexei A. Physical Review Letters, Vol. 106, Issue 4 https://doi.org/10.1103/PhysRevLett.106.046102	journal	January 2011
Anions, the Reporters of Structure in Ionic Liquids Hettige, Jeevapani J.; Kashyap, Hemant K.; Annapureddy, Harsha V. R. The Journal of Physical Chemistry Letters, Vol. 4, Issue 1 https://doi.org/10.1021/jz301866f	journal	December 2012
Interionic Interactions in Conducting Nanoconfinement Rochester, Christopher C.; Lee , Alpha A.; Pruessner, Gunnar ChemPhysChem, Vol. 14, Issue 18 https://doi.org/10.1002/cphc.201300834	journal	December 2013
Small-Angle Neutron Scattering for In Situ Probing of Ion Adsorption Inside Micropores Boukhalfa, S.; He, L.; Melnichenko, Y. B. Angewandte Chemie International Edition, Vol. 52, Issue 17 https://doi.org/10.1002/anie.201209141	journal	January 2013
Suppression and enhancement of van der Waals interactions Cho, Minhaeng; Silbey, Robert J. The Journal of Chemical Physics, Vol. 104, Issue 21 https://doi.org/10.1063/1.471562	journal	June 1996
Theoretical Model for Nanoporous Carbon Supercapacitors Huang, Jingsong; Sumpter, Bobby G.; Meunier, Vincent Angewandte Chemie International Edition, Vol. 47, Issue 3 https://doi.org/10.1002/anie.200703864	journal	January 2008
Double-Layer in Ionic Liquids: Paradigm Change? Kornyshev, Alexei A. The Journal of Physical Chemistry B, Vol. 111, Issue 20 https://doi.org/10.1021/jp067857o	journal	May 2007
Review on the science and technology of water desalination by capacitive deionization Porada, S.; Zhao, R.; van der Wal, A. Progress in Materials Science, Vol. 58, Issue 8 https://doi.org/10.1016/j.pmatsci.2013.03.005	journal	October 2013
Small-Angle Neutron Scattering for In Situ Probing of Ion Adsorption Inside Micropores Boukhalfa, S.; He, L.; Melnichenko, Y. B. Angewandte Chemie, Vol. 125, Issue 17 https://doi.org/10.1002/ange.201209141	journal	February 2013
The physical interaction of gases with crystalline solids Steele, William A. Surface Science, Vol. 39, Issue 1 https://doi.org/10.1016/0039-6028(73)90102-7	journal	August 1973
Coal-based 3D hierarchical porous carbon aerogels for high performance and super-long life supercapacitors Lv, Yan; Ding, Lili; Wu, Xueyan Scientific Reports, Vol. 10, Issue 1 https://doi.org/10.1038/s41598-020-64020-5	journal	April 2020
Quantification of ion confinement and desolvation in nanoporous carbon supercapacitors with modelling and in situ X-ray scattering Prehal, Christian; Koczwara, Christian; Jäckel, Nicolas Universität des Saarlandes https://doi.org/10.22028/d291-29122	collection	January 2017
Transition Metal Carbides and Nitrides in Energy Storage and Conversion Zhong, Yu; Xia, Xinhui; Shi, Fan Advanced Science, Vol. 4, Issue 3 https://doi.org/10.1002/advs.201700047	journal	February 2017
Theoretical Model for Nanoporous Carbon Supercapacitors Huang, Jingsong; Sumpter, Bobby G.; Meunier, Vincent Angewandte Chemie, Vol. 120, Issue 3 https://doi.org/10.1002/ange.200703864	journal	January 2008
Review on the science and technology of water desalination by capacitive deionization Presser, Volker; Porada, S.; Zhao, R. Amsterdam : Elsevier https://doi.org/10.34657/4972	other	January 2013
Superionic state in double-layer capacitors with nanoporous electrodes Kondrat, S.; Kornyshev, A. arXiv https://doi.org/10.48550/arxiv.1010.0921	text	January 2010
Double layer in ionic liquids: Overscreening vs. crowding Bazant, Martin Z.; Storey, Brian D.; Kornyshev, Alexei A. arXiv https://doi.org/10.48550/arxiv.1010.3490	text	January 2010

Cited By (30)

Breaking the Limits of Ionic Liquid-Based Supercapacitors: Mesoporous Carbon Electrodes Functionalized with Manganese Oxide Nanosplotches for Dense, Stable, and Wide-Temperature Energy Storage Lai, Feili; Feng, Jianrui; Yan, Runyu Advanced Functional Materials, Vol. 28, Issue 36 https://doi.org/10.1002/adfm.201801298	journal	July 2018
Ionic-Liquid Gating of InAs Nanowire-Based Field-Effect Transistors Lieb, Johanna; Demontis, Valeria; Prete, Domenic Advanced Functional Materials, Vol. 29, Issue 3 https://doi.org/10.1002/adfm.201804378	journal	November 2018
Supramolecular Self‐Assembly of Nanoconfined Ionic Liquids for Fast Anisotropic Ion Transport Cherian, Tomy; Nunes, Danilo Rosa; Dane, Thomas G. Advanced Functional Materials, Vol. 29, Issue 49 https://doi.org/10.1002/adfm.201905054	journal	October 2019
Wettability and Applications of Nanochannels Zhang, Xiqi; Liu, Hongliang; Jiang, Lei Advanced Materials, Vol. 31, Issue 5 https://doi.org/10.1002/adma.201804508	journal	October 2018
Toward the Experimental Understanding of the Energy Storage Mechanism and Ion Dynamics in Ionic Liquid Based Supercapacitors Yan, Runyu; Antonietti, Markus; Oschatz, Martin Advanced Energy Materials, Vol. 8, Issue 18 https://doi.org/10.1002/aenm.201800026	journal	March 2018
Magnetic Field–Suppressed Lithium Dendrite Growth for Stable Lithium‐Metal Batteries Shen, Kang; Wang, Zeng; Bi, Xuanxuan Advanced Energy Materials, Vol. 9, Issue 20 https://doi.org/10.1002/aenm.201900260	journal	April 2019
Boron Nitride Membranes with a Distinct Nanoconfinement Effect for Efficient Ethylene/Ethane Separation Dou, Haozhen; Jiang, Bin; Xu, Mi Angewandte Chemie International Edition, Vol. 58, Issue 39 https://doi.org/10.1002/anie.201907773	journal	September 2019
Water‐Induced Breaking of the Coulombic Ordering in a Room‐Temperature Ionic Liquid Metal Complex Hiraoka, Tomoaki; Ohtani, Ryo; Nakamura, Masaaki Chemistry – A European Journal, Vol. 25, Issue 31 https://doi.org/10.1002/chem.201900069	journal	May 2019
Molecular Insights into the Regulatable Interfacial Property and Flow Behavior of Confined Ionic Liquids in Graphene Nanochannels Wang, Yanlei; Wang, Chenlu; Zhang, Yaqin Small, Vol. 15, Issue 29 https://doi.org/10.1002/smll.201804508	journal	January 2019
Influences from solvents on charge storage in titanium carbide MXenes Wang, Xuehang; Mathis, Tyler S.; Li, Ke Nature Energy, Vol. 4, Issue 3 https://doi.org/10.1038/s41560-019-0339-9	journal	March 2019
Self-assembled nanostructures in ionic liquids facilitate charge storage at electrified interfaces Mao, Xianwen; Brown, Paul; Červinka, Ctirad Nature Materials, Vol. 18, Issue 12 https://doi.org/10.1038/s41563-019-0449-6	journal	August 2019
Molecular understanding of charge storage and charging dynamics in supercapacitors with MOF electrodes and ionic liquid electrolytes Bi, Sheng; Banda, Harish; Chen, Ming Nature Materials, Vol. 19, Issue 5 https://doi.org/10.1038/s41563-019-0598-7	journal	February 2020
Moving ions confined between graphene sheets Gogotsi, Yury Nature Nanotechnology, Vol. 13, Issue 8 https://doi.org/10.1038/s41565-018-0237-5	journal	August 2018
Molecular streaming and its voltage control in ångström-scale channels Mouterde, T.; Keerthi, A.; Poggioli, A. R. Nature, Vol. 567, Issue 7746 https://doi.org/10.1038/s41586-019-0961-5	journal	March 2019
The confined [Bmim][BF ₄ ] ionic liquid flow through graphene oxide nanochannels: a molecular dynamics study Wang, Yanlei; Huo, Feng; He, Hongyan Physical Chemistry Chemical Physics, Vol. 20, Issue 26 https://doi.org/10.1039/c8cp02408a	journal	January 2018
Confinement of aqueous mixtures of ionic liquids between amorphous TiO ₂ slit nanopores: electrostatic field induction Mohammadpour, Fatemeh; Heydari Dokoohaki, Maryam; Zolghadr, Amin Reza Physical Chemistry Chemical Physics, Vol. 20, Issue 46 https://doi.org/10.1039/c8cp04500c	journal	January 2018
Storing electricity as chemical energy: beyond traditional electrochemistry and double-layer compression Antonietti, Markus; Chen, Xiaodong; Yan, Runyu Energy & Environmental Science, Vol. 11, Issue 11 https://doi.org/10.1039/c8ee01723a	journal	January 2018
Challenges and prospects of 3D micro-supercapacitors for powering the internet of things Lethien, Christophe; Le Bideau, Jean; Brousse, Thierry Energy & Environmental Science, Vol. 12, Issue 1 https://doi.org/10.1039/c8ee02029a	journal	January 2019
A long-chain protic ionic liquid inside silica nanopores: enhanced proton mobility due to efficient self-assembly and decoupled proton transport Garaga, Mounesha N.; Dracopoulos, Vassilios; Werner-Zwanziger, Ulrike Nanoscale, Vol. 10, Issue 26 https://doi.org/10.1039/c8nr02031k	journal	January 2018
Organosilica-based ionogel derived nitrogen-doped microporous carbons for high performance supercapacitor electrodes Wang, Peng; Tao, Lumi; Luo, Huan Inorganic Chemistry Frontiers, Vol. 5, Issue 12 https://doi.org/10.1039/c8qi01034j	journal	January 2018
Height-driven structure and thermodynamic properties of confined ionic liquids inside carbon nanochannels from molecular dynamics study Wang, Chenlu; Wang, Yanlei; Lu, Yumiao Physical Chemistry Chemical Physics, Vol. 21, Issue 24 https://doi.org/10.1039/c9cp00732f	journal	January 2019
Ionic liquid thin layer-induced memory effects in organic field-effect transistors Eguchi, Keitaro; Matsushita, Michio M.; Awaga, Kunio Physical Chemistry Chemical Physics, Vol. 21, Issue 35 https://doi.org/10.1039/c9cp01647c	journal	January 2019
A space-confined strategy toward large-area two-dimensional crystals of ionic liquid Lu, Yumiao; Chen, Wei; Wang, Yanlei Physical Chemistry Chemical Physics, Vol. 22, Issue 4 https://doi.org/10.1039/c9cp04467a	journal	January 2020
Microscopic dynamics in room-temperature ionic liquids confined in materials for supercapacitor applications Osti, Naresh C.; Mamontov, Eugene Sustainable Energy & Fuels, Vol. 4, Issue 4 https://doi.org/10.1039/c9se00829b	journal	January 2020
Ion-ion correlations across and between electrified graphene layers Mendez-Morales, Trinidad; Burbano, Mario; Haefele, Matthieu The Journal of Chemical Physics, Vol. 148, Issue 19 https://doi.org/10.1063/1.5012761	journal	May 2018
Tracer diffusion in crowded narrow channels Bénichou, O.; Illien, P.; Oshanin, G. Journal of Physics: Condensed Matter, Vol. 30, Issue 44 https://doi.org/10.1088/1361-648x/aae13a	journal	October 2018
Overscreening and crowding in electrochemical ionic liquid systems Begić, Srđan; Chen, Fangfang; Jónsson, Erlendur Physical Review Materials, Vol. 3, Issue 9 https://doi.org/10.1103/physrevmaterials.3.095801	journal	September 2019
Cation Molecular Structure Affects Mobility and Transport of Electrolytes in Porous Carbons Osti, Naresh C.; Dyatkin, Boris; Gallegos, Alejandro Journal of The Electrochemical Society, Vol. 166, Issue 4 https://doi.org/10.1149/2.0131904jes	journal	January 2019
Effects of Carbon Pore Size on the Contribution of Ionic Liquid Electrolyte Phase Transitions to Energy Storage in Supercapacitors Schutjajew, Konstantin; Yan, Runyu; Antonietti, Markus Frontiers in Materials, Vol. 6 https://doi.org/10.3389/fmats.2019.00065	journal	April 2019
Boron Nitride Membranes with a Distinct Nanoconfinement Effect for Efficient Ethylene/Ethane Separation Dou, Haozhen; Jiang, Bin; Xu, Mi Angewandte Chemie, Vol. 131, Issue 39 https://doi.org/10.1002/ange.201907773	journal	July 2019

Similar Records

Partial breaking of the Coulombic ordering of ionic liquids confined in carbon nanopores

Journal Article · Mon Sep 18 00:00:00 EDT 2017 · Nature Materials · OSTI ID:1389046

Futamura, Ryusuke; Iiyama, Taku; Takasaki, Yuma; +6 more

Densification of Ionic Liquid Molecules within a Hierarchical Nanoporous Carbon Structure Revealed by Small Angle Scattering and Molecular Dynamics Simulation

Journal Article · Tue Jan 28 00:00:00 EST 2014 · Chem. Mater. · OSTI ID:1389046

Banuelos, J. L.; Feng, G.; Fulvio, P. F.; +5 more

Densification of Ionic Liquid Molecules within a Hierarchical Nanoporous Carbon Structure Revealed by Small-Angle Scattering and Molecular Dynamics Simulation

Journal Article · Thu Dec 26 00:00:00 EST 2013 · Chemistry of Materials · OSTI ID:1389046

Bañuelos, José Leobardo; Feng, Guang; Fulvio, Pasquale F.; +5 more

Related Subjects

catalysis (heterogeneous)
solar (fuels)
energy storage (including batteries and capacitors)
hydrogen and fuel cells
electrodes - solar
mechanical behavior
charge transport
materials and chemistry by design
synthesis (novel materials)

Title: Partial breaking of the Coulombic ordering of ionic liquids confined in carbon nanopores

Citation Formats

References (57)

Cited By (30)

Similar Records

Related Subjects