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Title: Preparation and Characterization of Group 13 Cyanides

Journal Article · · Chemistry - A European Journal

Research Organization:
Energy Frontier Research Centers (EFRC) (United States). Center for Understanding and Control of Acid Gas-induced Evolution of Materials for Energy (UNCAGE-ME)
Sponsoring Organization:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
DOE Contract Number:
SC0012577
OSTI ID:
1389041
Journal Information:
Chemistry - A European Journal, Vol. 23, Issue 38; Related Information: UNCAGE-ME partners with Georgia Institute of Technology (lead); Lehigh University; Oak Ridge National Laboratory; University of Alabama; University of Florida; University of Wisconsin; Washington University in St. Louis; ISSN 0947-6539
Publisher:
ChemPubSoc Europe
Country of Publication:
United States
Language:
English

References (70)

2D NMR exchange spectroscopy with spy nuclei for thallium(III) cyano complexes in aqueous solution journal July 1993
Magnetic Interactions and Magnetic Anisotropy in Exchange Coupled 4f-3d Systems: A Case Study of a Heterodinuclear Ce 3+ -Fe 3+ Cyanide-Bridged Complex journal January 2009
Structure of tribromotris(pyridine)thallium(III), [TlBr3(C5H5N)3] journal November 1984
Directed Assembly of Metal−Cyanide Cluster Magnets journal April 2005
Preparation and Characterization of the Binary Group 13 Azides M(N3)3 and M(N3)3⋅CH3CN (M=Ga, In, Tl), [Ga(N3)5]2−, and [M(N3)6]3− (M=In, Tl) journal July 2011
AB initio and Dft investigations of Al, Ga, and In tricyanides and triisocyanides journal July 2000
Tricyanometalate molecular chemistry: A type of versatile building blocks for the construction of cyano-bridged molecular architectures journal August 2011
Theoretical models incorporating electron correlation journal January 1976
COSMO: a new approach to dielectric screening in solvents with explicit expressions for the screening energy and its gradient journal January 1993
Crystal structure of cyanometallates Me 3 [ Co ( CN ) 6 ] 2 and KMe [ Fe ( CN ) 6 ] with Me = Mn 2+ , Ni 2+ , Cu 2+ journal March 1999
Electron affinities of the first‐row atoms revisited. Systematic basis sets and wave functions journal May 1992
Structure of Thallium(III) Chloride, Bromide, and Cyanide Complexes in Aqueous Solution journal May 1995
Schwingungsspektren der Cyanodimethylmetall-Komplexe von Magnesium, Aluminium, Gallium und Indium journal February 1975
Preparation and structures of two mixed-ligand 4-methylpyridine indium bromide complexes journal February 2016
Solubility, Complex Formation, and Redox Reactions in the Tl 2 O 3 −HCN/CN - −H 2 O System. Crystal Structures of the Cyano Compounds Tl(CN) 3 ·H 2 O, Na[Tl(CN) 4 ]·3H 2 O, K[Tl(CN) 4 ], and Tl I [Tl III (CN) 4 ] and of Tl I 2 C 2 O 4 journal April 2005
Molecules to build solids: high TC molecule-based magnets by design and recent revival of cyano complexes chemistry journal September 1999
Copper, Indium, Tin, and Lead Complexes with Fluorinated Selenolate Ligands: Precursors to MSe x journal August 2015
Magnetism of metal cyanide networks assembled at interfaces journal December 2005
Metal-organic frameworks journal January 2003
Structure of tribromobis(pyridine)thallium(III), TlBr3(C5H5N)2 journal January 1984
Molecular core-valence correlation effects involving the post-d elements Ga–Rn: Benchmarks and new pseudopotential-based correlation consistent basis sets journal November 2010
Cyanometallates as Halogen Bond Acceptors journal December 2011
Inorganic−Organic Hybrid Molecular Architectures of Cyanometalate Host and Organic Guest Systems:  Specific Behavior of the Guests journal April 2005
Synthetic Routes to Ga(CN) 3 and MGa(CN) 4 (M = Li, Cu) Framework Structures journal July 1997
Formation and structure of novel ternary complexes of thallium(III)-cyanide–amine (ethylenediamine and triethylenetetramine) in solution and in solid journal February 2003
Designer Magnets Containing Cyanides and Nitriles journal July 2001
Cyano-Bridged Re 6 Q 8 (Q = S, Se) Cluster-Metal Framework Solids:  A New Class of Porous Materials journal December 1998
Quantum Mechanical Continuum Solvation Models journal August 2005
Organoindium azides: new precursors to indium nitride journal December 1997
Synthesis and magnetism of multi-dimensional cyanide-bridged bimetallic assemblies journal March 2000
Studies on two interesting microporous polymeric clusters {[Et4N]2[MS4Cu4(CN)4]}n (M = Mo or W) with three-dimensional open frameworks: synthesis, structural characterization, strong optical non-linearities and large optical limiting properties journal January 2000
Indium tricyanide and indium trithiocyanate journal January 1966
Density‐functional thermochemistry. III. The role of exact exchange journal April 1993
Equilibrium Dynamics in the Thallium(III)−Cyanide System in Aqueous Solution journal December 1997
Systematically convergent basis sets with relativistic pseudopotentials. I. Correlation consistent basis sets for the post- d group 13–15 elements journal December 2003
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density journal January 1988
The Disordered Crystal Structures of Zn(CN)2and Ga(CN)3 journal November 1997
Die Kristallstruktur von [(CH3)2InCN]∞ journal February 1993
Synthesis of Nanoporous Cubic In(CN) 3 and In 1 - x Ga x (CN) 3 and Corresponding Inclusion Compounds journal September 1998
Design of single chain magnets through cyanide-bearing six-coordinate complexes journal December 2005
Synthesis of Molecular Adducts of Beryllium, Boron, and Gallium Cyanides: Theoretical and Experimental Correlations between Solid-State and Molecular Analogues journal November 2007
Preparation and Characterization of the Binary Group 13 Azides M(N3)3 and M(N3)3⋅CH3CN (M=Ga, In, Tl), [Ga(N3)5]2−, and [M(N3)6]3− (M=In, Tl) journal July 2011
Structures and Stability of Molecular InBr 3 Py x ( x = 1–3) Complexes: Unexpected Solid State Stabilization of Dimeric In 2 Br 6 Py 4 As Compared to Valence-Isoelectronic Group 15 and 17 Halogen Bridging Dimers journal November 2013
Accurate correlation consistent basis sets for molecular core–valence correlation effects: The second row atoms Al–Ar, and the first row atoms B–Ne revisited journal December 2002
Preparation and Characterization of Antimony and Arsenic Tricyanide and Their 2,2′-Bipyridine Adducts journal August 2016
Cyanide Exchange on Tl(CN)4− in Aqueous Solution Studied by205Tl and13C NMR Spectroscopy journal July 2001
The Hexacyanotitanate Ion:  Synthesis and Crystal Structure of [NEt 4 ] 3 [Ti III (CN) 6 ]·4MeCN journal July 1997
Emission, Raman Spectroscopy, and Structural Characterization of Actinide Tetracyanometallates journal April 2013
A Decade of Octacyanides in Polynuclear Molecular Materials journal December 2010
Synthesis and characterization of halogeno- and pseudo-halogeno-thallium(III) porphyrin complexes. Variation of the co-ordination geometry as a function of the axial ligand journal January 1993
Thallium(III) coordination compounds: chemical information from 205 Tl NMR longitudinal relaxation times journal September 2002
Structure of the 4:1 complexes formed by pyridine and the Group III halides InCl3 and TlCl3: mer-trichlorotris(pyridine)indium(III)–pyridine (1/1), [InCl3(C5H5N)3].C5H5N, and mer-trichlorotris(pyridine)thallium(III)–pyridine (1/1), [TlCl3(C5H5N)3].C5H5N journal August 1984
Cyanide complexes of the early transition metals (groups IVa-VIIa) journal November 1975
Chemistry and magnetism of cyanido-bridged d–f assemblies journal October 2006
Molecular spin crossover phenomenon: recent achievements and prospects journal January 2011
Cyanide-Bridged Molecular Squares - The Building Units of Prussian Blue journal June 2011
Tailored Design of Multiple Nanoarchitectures in Metal-Cyanide Hybrid Coordination Polymers journal December 2012
Molecular structure of an indium(III) iodide-tris(4-methylpyridine) adduct journal June 1996
Note on an Approximation Treatment for Many-Electron Systems journal October 1934
Photomagnetism in Cyano-Bridged Bimetal Assemblies journal August 2012
Organo-Tricyanoborates as Tectons:  Illustrative Coordination Polymers Based on Copper(I) Derivatives journal September 2005
Topological Motifs in Cyanometallates: From Building Units to Three-Periodic Frameworks journal October 2015
Inorganic—Organic Hybrid Molecular Architectures of Cyanometalate Host and Organic Guest Systems: Specific Behavior of the Guests journal July 2005
Directed Assembly of Metal—Cyanide Cluster Magnets journal July 2005
Quantum Mechanical Continuum Solvation Models journal October 2005
Taking a snapshot of the triplet excited state of an OLED organometallic luminophore using X-rays journal May 2020
Metal-Organic Frameworks journal September 2006
Equilibrium Dynamics in the Thallium(III)-Cyanide System in Aqueous Solution. journal February 1998
Development of the Colle-Salvetti correlation-energy formula into a functional of the electron density text January 1988
Metal-Organic Frameworks journal December 2003

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