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Title: Synthesis of cryptomelane type α-MnO 2 (K x Mn 8 O 16 ) cathode materials with tunable K + content: the role of tunnel cation concentration on electrochemistry

Abstract

Here, we synthesized a series of α-MnO 2samples with differing K +content but similar physical properties allowing direct study of the role of tunnel K +on the electrochemistry of α-MnO 2cathodes.

Authors:
 [1]; ORCiD logo [2];  [1];  [1];  [3];  [1];  [1]; ORCiD logo [4];  [4]; ORCiD logo [5]
  1. Energy Sciences Directorate; Brookhaven National Laboratory; Upton; USA
  2. Department of Chemistry; Stony Brook University; Stony Brook; USA
  3. Energy Sciences Directorate; Brookhaven National Laboratory; Upton; USA; Department of Materials Science and Engineering
  4. Department of Chemistry; Stony Brook University; Stony Brook; USA; Department of Materials Science and Engineering
  5. Energy Sciences Directorate; Brookhaven National Laboratory; Upton; USA; Department of Chemistry
Publication Date:
Research Org.:
Energy Frontier Research Centers (EFRC) (United States). Center for Mesoscale Transport Properties (m2M)
Sponsoring Org.:
USDOE Office of Science (SC), Basic Energy Sciences (BES)
OSTI Identifier:
1389027
DOE Contract Number:  
SC0012673
Resource Type:
Journal Article
Journal Name:
Journal of Materials Chemistry. A
Additional Journal Information:
Journal Volume: 5; Journal Issue: 32; Related Information: m2M partners with Stony Brook University (lead); Brookhaven National Laboratory; Columbia University; Georgia Institute of Technology; Oak Ridge National Laboratory; Rensselaer Polytechnic Institute; University of California, Berkeley; University of North Carolina at Chapel Hill; Journal ID: ISSN 2050-7488
Publisher:
Royal Society of Chemistry
Country of Publication:
United States
Language:
English
Subject:
energy storage (including batteries and capacitors), charge transport, mesostructured materials

Citation Formats

Poyraz, Altug S., Huang, Jianping, Pelliccione, Christopher J., Tong, Xiao, Cheng, Shaobo, Wu, Lijun, Zhu, Yimei, Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Synthesis of cryptomelane type α-MnO 2 (K x Mn 8 O 16 ) cathode materials with tunable K + content: the role of tunnel cation concentration on electrochemistry. United States: N. p., 2017. Web. doi:10.1039/C7TA03476H.
Poyraz, Altug S., Huang, Jianping, Pelliccione, Christopher J., Tong, Xiao, Cheng, Shaobo, Wu, Lijun, Zhu, Yimei, Marschilok, Amy C., Takeuchi, Kenneth J., & Takeuchi, Esther S. Synthesis of cryptomelane type α-MnO 2 (K x Mn 8 O 16 ) cathode materials with tunable K + content: the role of tunnel cation concentration on electrochemistry. United States. https://doi.org/10.1039/C7TA03476H
Poyraz, Altug S., Huang, Jianping, Pelliccione, Christopher J., Tong, Xiao, Cheng, Shaobo, Wu, Lijun, Zhu, Yimei, Marschilok, Amy C., Takeuchi, Kenneth J., and Takeuchi, Esther S. Sun . "Synthesis of cryptomelane type α-MnO 2 (K x Mn 8 O 16 ) cathode materials with tunable K + content: the role of tunnel cation concentration on electrochemistry". United States. https://doi.org/10.1039/C7TA03476H.
@article{osti_1389027,
title = {Synthesis of cryptomelane type α-MnO 2 (K x Mn 8 O 16 ) cathode materials with tunable K + content: the role of tunnel cation concentration on electrochemistry},
author = {Poyraz, Altug S. and Huang, Jianping and Pelliccione, Christopher J. and Tong, Xiao and Cheng, Shaobo and Wu, Lijun and Zhu, Yimei and Marschilok, Amy C. and Takeuchi, Kenneth J. and Takeuchi, Esther S.},
abstractNote = {Here, we synthesized a series of α-MnO2samples with differing K+content but similar physical properties allowing direct study of the role of tunnel K+on the electrochemistry of α-MnO2cathodes.},
doi = {10.1039/C7TA03476H},
url = {https://www.osti.gov/biblio/1389027}, journal = {Journal of Materials Chemistry. A},
issn = {2050-7488},
number = 32,
volume = 5,
place = {United States},
year = {2017},
month = {1}
}

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    Works referencing / citing this record:

    A Double‐Buffering Strategy to Boost the Lithium Storage of Botryoid MnO x /C Anodes
    journal, March 2019


    Cryptomelane K 1.33 Mn 8 O 16 as a cathode for rechargeable aqueous zinc-ion batteries
    journal, January 2019


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