Lithiation of multilayer Ni/NiO electrodes: criticality of nickel layer thicknesses on conversion reaction kinetics

doi:https://doi.org/10.1039/C7CP02448G

Title: Lithiation of multilayer Ni/NiO electrodes: criticality of nickel layer thicknesses on conversion reaction kinetics

Abstract

X-ray reflectivity and transmission electron microscopy (TEM) were used to characterize the morphological changes in thin film electrodes with alternating Ni and NiO layers during lithiation as a function of the Ni buffer layer thickness.

Authors:

Evmenenko, Guennadi ^[1]; Fister, Timothy T. ^[2]; Buchholz, D. Bruce ^[1]; Castro, Fernando C. ^[3]; Li, Qianqian ^[3]; Wu, Jinsong ^[4];

^[1];

^[2];

^[5]

Department of Materials Science and Engineering; Northwestern University; Evanston; USA
Chemical Sciences and Engineering Division; Argonne National Laboratory; Lemont; USA
EPIC; NUANCE Center; Northwestern University; Evanston; USA
Department of Materials Science and Engineering; Northwestern University; Evanston; USA; EPIC
Department of Materials Science and Engineering; Northwestern University; Evanston; USA; Department of Physics and Astronomy

Publication Date:: 2017-01-01

Research Org.:: Energy Frontier Research Centers (EFRC) (United States). Center for Electrical Energy Storage (CEES)

Sponsoring Org.:: USDOE Office of Science (SC), Basic Energy Sciences (BES)

OSTI Identifier:: 1389019

DOE Contract Number:: AC02-06CH11357

Resource Type:: Journal Article

Journal Name:: Physical Chemistry Chemical Physics. PCCP (Print)

Additional Journal Information:: Journal Volume: 19; Journal Issue: 30; Related Information: CEES partners with Argonne National Laboratory (lead); University of Illinois, Urbana-Champaign; Northwest University; Journal ID: ISSN 1463-9076

Publisher:: Royal Society of Chemistry

Country of Publication:: United States

Language:: English

Subject:: energy storage (including batteries and capacitors), charge transport, materials and chemistry by design, synthesis (novel materials)

Citation Formats


                    Evmenenko, Guennadi, Fister, Timothy T., Buchholz, D. Bruce, Castro, Fernando C., Li, Qianqian, Wu, Jinsong, Dravid, Vinayak P., Fenter, Paul, and Bedzyk, Michael J. Lithiation of multilayer Ni/NiO electrodes: criticality of nickel layer thicknesses on conversion reaction kinetics.  United States: N. p., 2017. 
        Web.  doi:10.1039/C7CP02448G.

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                    Evmenenko, Guennadi, Fister, Timothy T., Buchholz, D. Bruce, Castro, Fernando C., Li, Qianqian, Wu, Jinsong, Dravid, Vinayak P., Fenter, Paul, & Bedzyk, Michael J. Lithiation of multilayer Ni/NiO electrodes: criticality of nickel layer thicknesses on conversion reaction kinetics.  United States.  https://doi.org/10.1039/C7CP02448G

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                    Evmenenko, Guennadi, Fister, Timothy T., Buchholz, D. Bruce, Castro, Fernando C., Li, Qianqian, Wu, Jinsong, Dravid, Vinayak P., Fenter, Paul, and Bedzyk, Michael J. Sun .  
        "Lithiation of multilayer Ni/NiO electrodes: criticality of nickel layer thicknesses on conversion reaction kinetics".  United States.  https://doi.org/10.1039/C7CP02448G.

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@article{osti_1389019,

  title        = {Lithiation of multilayer Ni/NiO electrodes: criticality of nickel layer thicknesses on conversion reaction kinetics},

  author       = {Evmenenko, Guennadi and Fister, Timothy T. and Buchholz, D. Bruce and Castro, Fernando C. and Li, Qianqian and Wu, Jinsong and Dravid, Vinayak P. and Fenter, Paul and Bedzyk, Michael J.},

  abstractNote = {X-ray reflectivity and transmission electron microscopy (TEM) were used to characterize the morphological changes in thin film electrodes with alternating Ni and NiO layers during lithiation as a function of the Ni buffer layer thickness.},

  doi          = {10.1039/C7CP02448G},

  url          = {https://www.osti.gov/biblio/1389019},
  journal      = {Physical Chemistry Chemical Physics. PCCP (Print)},

  issn         = {1463-9076},

  number       = 30,

  volume       = 19,

  place        = {United States},

  year         = {2017},

  month        = {1}

}

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Works referenced in this record:

Fe/Si multi-layer thin film anodes for lithium rechargeable thin film batteries
journal, July 2003

Kim, Jae-Bum; Lee, Heon-Young; Lee, Kawn-Soo
Electrochemistry Communications, Vol. 5, Issue 7
https://doi.org/10.1016/S1388-2481(03)00120-6

Kinetic aspects of Li intercalation in mechano-chemically processed cathode materials for lithium ion batteries: Electrochemical characterization of ball-milled LiMn2O4
journal, August 2011

Zheng, J. P.; Crain, D. J.; Roy, D.
Solid State Ionics, Vol. 196, Issue 1
https://doi.org/10.1016/j.ssi.2011.06.004

Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
journal, September 2000

Poizot, P.; Laruelle, S.; Grugeon, S.
Nature, Vol. 407, Issue 6803, p. 496-499
https://doi.org/10.1038/35035045

Si–Y multi-layer thin films as anode materials of high-capacity lithium-ion batteries
journal, November 2012

Li, Haixia; Bai, Hongmei; Tao, Zhanliang
Journal of Power Sources, Vol. 217
https://doi.org/10.1016/j.jpowsour.2012.05.080

NiO thin films grown directly on Cu foils by pulsed laser deposition as anode materials for lithium ion batteries
journal, October 2014

Cao, Ling; Wang, Dongxiao; Wang, Rong
Materials Letters, Vol. 132
https://doi.org/10.1016/j.matlet.2014.06.114

Separation of overlapping core edges in electron energy loss spectra by multiple-least-squares fitting
journal, January 1988

Leapman, R. D.; Swyt, C. R.
Ultramicroscopy, Vol. 26, Issue 4
https://doi.org/10.1016/0304-3991(88)90239-2

Beyond Intercalation-Based Li-Ion Batteries: The State of the Art and Challenges of Electrode Materials Reacting Through Conversion Reactions
journal, August 2010

Cabana, Jordi; Monconduit, Laure; Larcher, Dominique
Advanced Materials, Vol. 22, Issue 35
https://doi.org/10.1002/adma.201000717

Mechanisms of Charge Storage in Nanoparticulate TiO2 and Li4Ti5O12 Anodes: New Insights from Scan rate-dependent Cyclic Voltammetry
journal, June 2015

Opitz, Martin; Yue, Junpei; Wallauer, Jens
Electrochimica Acta, Vol. 168
https://doi.org/10.1016/j.electacta.2015.03.186

Improvement of capacity and cyclability of Fe/Si multilayer thin film anodes for lithium rechargeable batteries
journal, May 2005

Kim, Jae-Bum; Jun, Bong-Suk; Lee, Sung-Man
Electrochimica Acta, Vol. 50, Issue 16-17
https://doi.org/10.1016/j.electacta.2004.12.021

Ultrathin nickel oxide nanosheets for enhanced sodium and lithium storage
journal, January 2015

Sun, Wenping; Rui, Xianhong; Zhu, Jixin
Journal of Power Sources, Vol. 274
https://doi.org/10.1016/j.jpowsour.2014.10.105

Co-refinement of multiple-contrast neutron/X-ray reflectivity data using MOTOFIT
journal, March 2006

Nelson, Andrew
Journal of Applied Crystallography, Vol. 39, Issue 2
https://doi.org/10.1107/S0021889806005073

Electron energy loss analysis of near-trace-element concentrations of calcium
journal, January 1987

Shuman, H.; Somlyo, A. P.
Ultramicroscopy, Vol. 21, Issue 1
https://doi.org/10.1016/0304-3991(87)90004-0

Multifunctional Ni/NiO hybrid nanomembranes as anode materials for high-rate Li-ion batteries
journal, October 2014

Sun, Xiaolei; Si, Wenping; Liu, Xianghong
Nano Energy, Vol. 9
https://doi.org/10.1016/j.nanoen.2014.06.022

Review on recent progress of nanostructured anode materials for Li-ion batteries
journal, July 2014

Goriparti, Subrahmanyam; Miele, Ermanno; De Angelis, Francesco
Journal of Power Sources, Vol. 257
https://doi.org/10.1016/j.jpowsour.2013.11.103

Solubility of Lithium Salts Formed on the Lithium-Ion Battery Negative Electrode Surface in Organic Solvents
journal, January 2009

Tasaki, Ken; Goldberg, Alex; Lian, Jian-Jie
Journal of The Electrochemical Society, Vol. 156, Issue 12
https://doi.org/10.1149/1.3239850

Morphological Evolution of Multilayer Ni/NiO Thin Film Electrodes during Lithiation
journal, July 2016

Evmenenko, Guennadi; Fister, Timothy T.; Buchholz, D. Bruce
ACS Applied Materials & Interfaces, Vol. 8, Issue 31
https://doi.org/10.1021/acsami.6b05040

Amorphous silicon/carbon multilayer thin films as the anode for high rate rechargeable Li-ion batteries
journal, April 2013

Wang, Jun; Tong, Yongfeng; Xu, Zhuang
Materials Letters, Vol. 97
https://doi.org/10.1016/j.matlet.2013.01.027

Silicon as a potential anode material for Li-ion batteries: where size, geometry and structure matter
journal, January 2016

Ashuri, Maziar; He, Qianran; Shaw, Leon L.
Nanoscale, Vol. 8, Issue 1
https://doi.org/10.1039/C5NR05116A

Lithium Intercalation Behavior in Multilayer Silicon Electrodes
journal, January 2014

Fister, Tim T.; Esbenshade, Jennifer; Chen, Xiao
Advanced Energy Materials, Vol. 4, Issue 7
https://doi.org/10.1002/aenm.201301494

Magnetic sputtered amorphous Si/C multilayer thin films as anode materials for lithium ion batteries
journal, February 2014

Tong, Yongfeng; Xu, Zhuang; Liu, Chang
Journal of Power Sources, Vol. 247
https://doi.org/10.1016/j.jpowsour.2013.08.087

Deformation and stress in electrode materials for Li-ion batteries
journal, June 2014

Mukhopadhyay, Amartya; Sheldon, Brian W.
Progress in Materials Science, Vol. 63
https://doi.org/10.1016/j.pmatsci.2014.02.001

Design and performance of the 33-BM beamline at the Advanced Photon Source
journal, September 2011

Karapetrova, Evguenia; Ice, Gene; Tischler, Jonathan
Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectrometers, Detectors and Associated Equipment, Vol. 649, Issue 1
https://doi.org/10.1016/j.nima.2010.12.159

Intercalated SiO2&Si/Carbon Composite for High Capacity Li Ion Battery Anodes
journal, September 2014

Pang, Chunlei; Li, Na; Wang, C. X.
Electrochimica Acta, Vol. 141
https://doi.org/10.1016/j.electacta.2014.06.152

Cycling performance of density modulated multilayer silicon thin film anodes in Li-ion batteries
journal, January 2015

Demirkan, M. T.; Trahey, L.; Karabacak, T.
Journal of Power Sources, Vol. 273
https://doi.org/10.1016/j.jpowsour.2014.09.027

Effect of multilayer structure on cyclic performance of Si/Fe anode electrode in Lithium-ion secondary batteries
journal, January 2013

Kang, Hee-Kook; Lee, Seong-Rae; Cho, Won Il
Phys. Chem. Chem. Phys., Vol. 15, Issue 5
https://doi.org/10.1039/C2CP42824E

High specific capacity retention of graphene/silicon nanosized sandwich structure fabricated by continuous electron beam evaporation as anode for lithium-ion batteries
journal, May 2015

Mori, Tatsuhiro; Chen, Chih-Jung; Hung, Tai-Feng
Electrochimica Acta, Vol. 165
https://doi.org/10.1016/j.electacta.2015.02.219

Surface-enabled superior lithium storage of high-quality ultrathin NiO nanosheets
journal, January 2014

Zhu, Youqi; Guo, Huizi; Wu, Yu
Journal of Materials Chemistry A, Vol. 2, Issue 21
https://doi.org/10.1039/c4ta00257a

A review of conduction phenomena in Li-ion batteries
journal, December 2010

Park, Myounggu; Zhang, Xiangchun; Chung, Myoungdo
Journal of Power Sources, Vol. 195, Issue 24
https://doi.org/10.1016/j.jpowsour.2010.06.060

Determination of the diffusion coefficient of lithium ions in nano-Si
journal, March 2009

Ding, N.; Xu, J.; Yao, Y. X.
Solid State Ionics, Vol. 180, Issue 2-3
https://doi.org/10.1016/j.ssi.2008.12.015

Diffusion of Lithium in Bulk Amorphous Silicon: A Theoretical Study
journal, October 2012

Tritsaris, Georgios A.; Zhao, Kejie; Okeke, Onyekwelu U.
The Journal of Physical Chemistry C, Vol. 116, Issue 42
https://doi.org/10.1021/jp307221q

Three-Dimensionally “Curved” NiO Nanomembranes as Ultrahigh Rate Capability Anodes for Li-Ion Batteries with Long Cycle Lifetimes
journal, October 2013

Sun, Xiaolei; Yan, Chenglin; Chen, Yao
Advanced Energy Materials, Vol. 4, Issue 4
https://doi.org/10.1002/aenm.201300912

Distinguishing the core from the shell in MnOx/MnOy and FeOx/MnOx core/shell nanoparticles through quantitative electron energy loss spectroscopy (EELS) analysis
journal, January 2012

Estradé, S.; Yedra, Ll.; López-Ortega, A.
Micron, Vol. 43, Issue 1
https://doi.org/10.1016/j.micron.2011.04.002

Works referencing / citing this record:

Thin Film RuO ₂ Lithiation: Fast Lithium-Ion Diffusion along the Interface
journal, November 2018

Kim, Sungkyu; Evmenenko, Guennadi; Xu, Yaobin
Advanced Functional Materials, Vol. 28, Issue 52
https://doi.org/10.1002/adfm.201805723

Structural analysis of the initial lithiation of NiO thin film electrodes
journal, January 2019

Evmenenko, Guennadi; Fister, Timothy T.; Castro, Fernando C.
Physical Chemistry Chemical Physics, Vol. 21, Issue 17
https://doi.org/10.1039/c9cp01527b

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Title: Lithiation of multilayer Ni/NiO electrodes: criticality of nickel layer thicknesses on conversion reaction kinetics

Abstract

Citation Formats

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Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries
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Si–Y multi-layer thin films as anode materials of high-capacity lithium-ion batteries
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NiO thin films grown directly on Cu foils by pulsed laser deposition as anode materials for lithium ion batteries
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Separation of overlapping core edges in electron energy loss spectra by multiple-least-squares fitting
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